chemical thermodynamics of neptunium and plutonium - U.S. ...

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(V vs. SHE) (V vs. SHE) (V · K −1 )Np(V) + e − Å Np(IV)(12.18) and NpO 2 (CO 3 ) 5−3+ e − + 2CO 2 (g) Å Np(CO 3 ) 6−5 (12.19)(g)pot 1 M Na 2 CO (h) 3 room t (0.1 ±0.2) (i) 0.514 (j) [79FED/PER]pot 0.3 M Na 2 CO 3 25 0.267 (k) 0.641 (j) [96DEL/VIT]pot 0.6 M Na 2 CO 3 25 0.188 (k) 0.694 (j) −0.00206 (m)pot 1 M Na 2 CO 3 25 0.226 (k) 0.641 (j) −0.00217 (m)pH=10.27 0.535pot 1.5 M Na 2 CO 3 25 0.207 (k) 0.620 (j) −0.00224 (m)pot I = 0 25 0.124 (0.436 ±0.116)Redox equilibriaMethod Ionic medium (mol · dm −3 ) t ( ◦ C) E ◦′ (V vs. SHE) ReferenceNp(CO 3 ) 6−5 + e − Å Np(CO 3 ) 3−3 + 2CO3 2−(n)vlt 1 M Na 2 CO 3 room t −(1.32 ± 0.1) [79FED/PER]vlt 1 M K 2 CO 3 room t −(1.3 ± 0.1) [84VAR/HOB]vlt 2 M Na 2 CO 3 room t −(1.2 ± 0.1)(Continued on next page)12.1 Neptunium carbon compounds and complexes 257
Np 4+ + 3CO 2−3Å Np(CO 3 ) 2−3sol NaHCO 3 , in air room t (37.0 ± 1.2) < 33 [89MOR/PRA]Np 4+ + 2CO 2−3+ 2OH − Å Np(CO 3 ) 2 (OH) 2−2sol 0.01 M (CO 2−3+HCO − 3 ), Na+ room t (45.69 ± 0.44) < 42 (l) [90PRA/MOR]sol I = 0 (23 ± 2) 43.17 < 42 [99RAI/HES]Np 4+ + CO 2−3 + 4OH − Å Np(CO 3 )(OH) 2−4sol 0.1 to 2.2 M (NH 4 ) 2 CO 3 room t (53.05 ± 0.02) < 47 (l) [71MOS2]sol 0.5 M NaClO 4 20 (49.2 ± 0.5) [93ERI/NDA]Np 4+ + 2CO 2−3 + 4OH − Å Np(CO 3 ) 2 (OH) 4−4sol0.01 M (CO 2−3 +HCO − 3 ), Na+ room t (53.07 ± 0.44) < 48 (l) [90PRA/MOR]Np 4+ + CO 2−3 + 3OH − Å NpCO 3 (OH) − 312. Neptunium group 14 compounds and complexessol 0.5 M NaClO 4 20 (45.8 ± 0.5) [93ERI/NDA](a) Estimated in the present review from data of this study (not interpreted by the original authors).(b) log 10 K determined in chemical conditions where log 10 [CO 2−3 ]=−log 10 K .(c) Data tabulated on pages 57 and 58 of [96DEL/VIT].(d) Molal units.(continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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Page 234 and 235: sol K + ,CO 2−3 , 20 −(2.31±0.
Page 236 and 237: 12.1 Neptunium carbon compounds and
Page 252 and 253: sp 0.1 M NaCl 23 (4.68±0.03) [96RU
Page 254 and 255: dis 0.2 M NaClO 25 2.93 (3.42±1.0)
Page 256 and 257: sol 1 M NaCl 23 (2.06±0.13) [96RUN
Page 258 and 259: sol 0.15 M Na 2 CO 3 −(2.58±0.64
Page 260 and 261: sol 1 M NaClO 30 −(4.0±0.2) [93L
Page 262 and 263: sol 3 M NaClO 25 −(2.14±0.18)
Page 264 and 265: (f) Values selected in this review
Page 284 and 285: (h) 1MK 2 CO 3 is written in Table
Page 292 and 293: 2 3 r H m (5.0±2.0)log 10 β 2 MO
Page 312: 12.1 Neptunium carbon compounds and
Page 315 and 316: 290 13. Neptunium group 2 (alkaline
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Page 320: Part IVDiscussion of plutonium data
Page 323 and 324: 298 15. Elemental plutoniumTable 15
Page 325 and 326: 300 15. Elemental plutoniumfrom 298
Page 327 and 328: 302 16. Plutonium aqua ionsthe prop
Page 329 and 330: 304 16. Plutonium aqua ions298.15 K
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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