chemical thermodynamics of neptunium and plutonium - U.S. ...

More documents

Recommendations

Info

19.1 Plutonium sulphur compounds and complexes 393Table 19.2: (continued)Reference log 10 β (a) I (M) t ( ◦ C) MethodPu 4+ + 2HSO − 4Å Pu(SO 4 ) 2 (aq) + 2H +[54SUL/AME] 4.65 2.3 Medium spuncertain[61MAR/CHM] 1.30 0.5 ix HClO 4[64LAX/PAT] 4.71 1 HNO 3 25 dis4.76 2 (Na,H) 25 dis(NO 3 ,ClO 4 )4.66 2 (Na,H) 25 dis(NO 3 ,ClO 4 )4.37 2.2 (Na,H) 25 dis(NO 3 ,ClO 4 )[73PAT/RAM] 4.36 2 10 dis4.37 2 25 dis4.41 2 40 dis[73PAT/RAM2] (4.34±0.05) 2HClO 4 25 dis4.50 2 HClO 4 25 dis[76BAG/RAM] (4.64±0.02) 2HClO 4 25 dis(4.53±0.01) 2HClO 4 25 disPu 4+ + 2HSO − 4Å Pu(SO 4 ) 2 (aq) + 2H +[76BAG/RAM2] (4.66±0.01) 2 25 dis HClO 4(4.69±0.01) 2 25 dis HClO 4(4.51±0.01) 2 25 dis HClO 44.70 2 25 dis HClO 4[77BAG/RAM] (4.60±0.01) 2 10 dis HClO 4(4.43±0.01) 2 10 dis HClO 4PuSO 2+4 + HSO − 4Å Pu(SO 4 ) 2 (aq) + H +[64LUC] (0.58±0.16) 1 (23± 0.5) dis (H,Na) HNO 3Pu 4+ + 3HSO − 4Å Pu(SO 4 ) 2−3 + 3H +[54SUL/AME] 5.35 2.3 Medium spuncertain[61MAR/CHM] 2.10 0.5 ix HClO 4(Continued on next page)
394 19. Plutonium group 16 compounds and complexesTable 19.2: (continued)Reference log 10 β (a) I (M) t ( ◦ C) MethodPu 4+ + 2HSO − 4Å Pu(SO 4 )(HSO 4 ) + + H +[83NAS/CLE] (4.10±0.09) 2 0 dis (H,Na) ClO 4(4.06±0.07) 2 10 dis (H,Na) ClO 4(4.13±0.07) 2 25 dis (H,Na) ClO 4(4.11±0.08) 2 35 dis (H,Na) ClO 4Pu 4+ + NO − 3 + HSO− 4Å PuNO 3 (SO 4 ) + + H +[76BAG/RAM2] 3.03 2 25 dis HClO 4(a) Here “β” refers to either β or ∗ β as appropriate for each reaction as written.The most reliable value of log10 ∗β1(I)(19.4) atI = 2.2 m is the weighted averageof the results at 25 ◦ C reported in Table 19.3: (2.75 ± 0.01). Based on theionic interaction parameters determined for the analogous U(IV) complex (ε(19.4) =−(0.31 ± 0.12) kg·mol −1 [92GRE/FUG]), this value can be extrapolated to standardconditions: log10 ∗β◦1(19.4) = (4.91 ± 0.22).
Page 1 and 2:
4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
Page 3 and 4:
CHEMICAL THERMODYNAMICSVol. 1. Chem
Page 5 and 6:
Published under the imprint NORTH-H
Page 7 and 8:
viPREFACEviewed several of the othe
Page 9 and 10:
viiiACKNOWLEDGEMENTSand Whiteshell
Page 11 and 12:
xFOREWORDsending comments on the TD
Page 13 and 14:
xiiCONTENTSIII Discussion of neptun
Page 15:
xivCONTENTS11.1.4.2 Solid neptunium
Page 18 and 19:
CONTENTSxvii20.5.1 PuSb(cr) . . . .
Page 20 and 21:
List of Tables2.1 Symbols and termi
Page 22 and 23:
LIST OF TABLESxxi20.2 Experimental
Page 24 and 25:
List of Figures2.1 Standard order o
Page 26:
Part IIntroductory material1
Page 29 and 30:
4 1. IntroductionInorganic Complexe
Page 31 and 32:
6 1. Introductionlected, but form a
Page 34 and 35:
Chapter 2Standards, Conventions, an
Page 36 and 37:
2.1 Symbols, terminology and nomenc
Page 38 and 39:
Page 40 and 41:
Page 42 and 43:
Page 44 and 45:
Page 46 and 47:
Page 48 and 49:
2.2 Units and conversion factors 23
Page 50 and 51:
2.2 Units and conversion factors 25
Page 52 and 53:
2.3 Standard and reference conditio
Page 54 and 55:
2.3 Standard and reference conditio
Page 56 and 57:
2.5 Uncertainty estimates 31Table 2
Page 58 and 59:
2.7 Presentation of the selected da
Page 60:
2.7 Presentation of the selected da
Page 64 and 65:
Chapter 3Selected neptunium dataThi
Page 66 and 67:
41Table 3.1: Selected thermodynamic
Page 68 and 69:
43Table 3.1: (continued)Compound f
Page 70 and 71:
Page 72 and 73:
Page 74 and 75:
49Table 3.2: (continued)SpeciesReac
Page 76 and 77:
Page 78 and 79:
Chapter 4Selected plutonium dataThi
Page 80 and 81:
Page 82 and 83:
Page 84 and 85:
Page 86 and 87:
61SpeciesPu(OH) 3 (cr)ReactionTable
Page 88 and 89:
Page 90 and 91:
Chapter 5Selected auxiliary dataThi
Page 92 and 93:
Page 94 and 95:
Page 96 and 97:
Page 98 and 99:
Page 100 and 101:
Page 102 and 103:
(footnotes continued)(p) Data from
Page 104 and 105:
79Table 5.2: (continued)Species Rea
Page 106:
81Table 5.2: (continued)Species Rea
Page 110 and 111:
Chapter 6Elemental neptunium6.1 Nep
Page 112 and 113:
6.1 Neptunium crystal and liquid 87
Page 114:
6.2 Neptunium ideal monatomic gas 8
Page 117 and 118:
92 7. Neptunium aqua ionsE ◦′ (
Page 119 and 120:
94 7. Neptunium aqua ionsto the sta
Page 121 and 122:
96 7. Neptunium aqua ions(∂ E ◦
Page 123 and 124:
98 7. Neptunium aqua ionsnon-system
Page 125 and 126:
100 7. Neptunium aqua ionsto the re
Page 127 and 128:
102 7. Neptunium aqua ionsTable 7.4
Page 130 and 131:
Chapter 8Neptunium oxygen andhydrog
Page 132 and 133:
8.1 Aqueous neptunium hydroxide com
Page 134 and 135:
Page 136 and 137:
Page 138 and 139:
Page 140 and 141:
Page 142 and 143:
8.2 Crystalline and amorphous neptu
Page 144 and 145:
Page 146 and 147:
Page 148 and 149:
Page 150 and 151:
Page 152 and 153:
Page 154:
Page 157 and 158:
132 9. Neptunium group 17 (halogen)
Page 159 and 160:
Page 161 and 162:
Page 163 and 164:
Page 165 and 166:
Page 167 and 168:
Page 169 and 170:
Page 171 and 172:
Page 173 and 174:
Page 175 and 176:
Page 177 and 178:
Page 179 and 180:
Page 181 and 182:
Page 183 and 184:
Page 185 and 186:
Page 187 and 188:
Page 189 and 190:
Page 191 and 192:
Page 193 and 194:
Page 195 and 196:
Page 197 and 198:
Page 199 and 200:
Page 201 and 202:
Page 203 and 204:
178 10. Neptunium group 16 compound
Page 205 and 206:
Page 207 and 208:
Page 209 and 210:
Page 212 and 213:
Chapter 11Neptunium group 15compoun
Page 214 and 215:
11.1 Neptunium nitrogen compounds a
Page 216 and 217:
Page 218 and 219:
Page 220 and 221:
Page 222 and 223:
11.2 Neptunium phosphorus compounds
Page 224 and 225:
11.2 Neptunium phosphorus compounds
Page 226 and 227:
Chapter 12Neptunium group 14compoun
Page 228 and 229:
12.1 Neptunium carbon compounds and
Page 230 and 231:
cal 0.3-1.6 M Na 2 SO 4 25 r H m =
Page 232 and 233:
vlt 0 25 (0.340±0.002) (k) [95OFF/
Page 234 and 235:
sol K + ,CO 2−3 , 20 −(2.31±0.
Page 236 and 237:
Page 238 and 239:
Page 240 and 241:
Page 242 and 243:
Page 244 and 245:
Page 246 and 247:
Page 248 and 249:
Page 250 and 251:
Page 252 and 253:
sp 0.1 M NaCl 23 (4.68±0.03) [96RU
Page 254 and 255:
dis 0.2 M NaClO 25 2.93 (3.42±1.0)
Page 256 and 257:
sol 1 M NaCl 23 (2.06±0.13) [96RUN
Page 258 and 259:
sol 0.15 M Na 2 CO 3 −(2.58±0.64
Page 260 and 261:
sol 1 M NaClO 30 −(4.0±0.2) [93L
Page 262 and 263:
sol 3 M NaClO 25 −(2.14±0.18)
Page 264 and 265:
(f) Values selected in this review
Page 266 and 267:
Page 268 and 269:
Page 270 and 271:
Page 272 and 273:
Page 274 and 275:
Page 276 and 277:
Page 278 and 279:
Page 280 and 281:
Page 282 and 283:
(V vs. SHE) (V vs. SHE) (V · K −
Page 284 and 285:
(h) 1MK 2 CO 3 is written in Table
Page 286 and 287:
Page 288 and 289:
Page 290 and 291:
Page 292 and 293:
2 3 r H m (5.0±2.0)log 10 β 2 MO
Page 294 and 295:
Page 296 and 297:
Page 298 and 299:
Page 300 and 301:
Page 302 and 303:
Page 304 and 305:
Page 306 and 307:
Page 308 and 309:
Page 310 and 311:
Page 312:
Page 315 and 316:
290 13. Neptunium group 2 (alkaline
Page 317 and 318:
292 14. Neptunium group 1 (alkali)
Page 320:
Part IVDiscussion of plutonium data
Page 323 and 324:
298 15. Elemental plutoniumTable 15
Page 325 and 326:
300 15. Elemental plutoniumfrom 298
Page 327 and 328:
302 16. Plutonium aqua ionsthe prop
Page 329 and 330:
304 16. Plutonium aqua ions298.15 K
Page 331 and 332:
306 16. Plutonium aqua ionsE ◦ =
Page 333 and 334:
308 16. Plutonium aqua ionsSm ◦ (
Page 335 and 336:
310 16. Plutonium aqua ionsstandard
Page 337 and 338:
312 16. Plutonium aqua ions r H ◦
Page 339 and 340:
314 16. Plutonium aqua ionsE ◦′
Page 341 and 342:
316 16. Plutonium aqua ionsFigure 1
Page 343 and 344:
318 17. Plutonium oxygen and hydrog
Page 345 and 346:
Page 347 and 348:
Page 349 and 350:
Page 351 and 352:
1:1 pot RT 1 M NaClO 4 −5.71 [49K
Page 353 and 354:
Page 355 and 356:
Page 357 and 358:
Page 359 and 360:
Page 361 and 362:
Page 363 and 364:
Page 365 and 366:
Page 367 and 368: 342 17. Plutonium oxygen and hydrog
Page 370 and 371: Chapter 18Plutonium group 17 (halog
Page 372 and 373: 18.1 Plutonium halide compounds 347
Page 396 and 397: 18.2 Aqueous plutonium group 17 (ha
Page 402 and 403: PuO 2+2+ 3F − Å PuO 2 F − (b)3
Page 412: 18.2 Aqueous plutonium group 17 (ha
Page 415 and 416: 390 19. Plutonium group 16 compound
Page 417: 392 19. Plutonium group 16 compound
Page 426 and 427: Chapter 20Plutonium group 15 compou
Page 428 and 429: 20.1 Plutonium nitrogen compounds a
Page 432 and 433: Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
Page 434 and 435: 3 3 3dis, TTA 6 M (? HCl or HClO 4
Page 440 and 441: 20.2 Plutonium phosphorus compounds
Page 442 and 443: 20.2 Plutonium phosphorus compounds
Page 444 and 445: 20.3 Solid plutonium phosphorus com
Page 446 and 447: 20.4 Plutonium arsenic compounds 42
Page 448 and 449: 20.6 The plutonium-bismuth system 4
Page 450: 20.6 The plutonium-bismuth system 4
Page 469 and 470:
444 21. Plutonium group 14 compound
Page 471 and 472:
446 22. Plutonium group 2 (alkaline
Page 474:
Chapter 23Plutonium group 1 (alkali
Page 477 and 478:
452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
Page 479 and 480:
454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
Page 481 and 482:
456 BIBLIOGRAPHY[51WES/EYR][51WES/W
Page 483 and 484:
458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
Page 485 and 486:
460 BIBLIOGRAPHYmetals in connectio
Page 487 and 488:
462 BIBLIOGRAPHY[59SHE/TIM][59STU][
Page 489 and 490:
464 BIBLIOGRAPHY[61SCH][61STO/FRY][
Page 491 and 492:
466 BIBLIOGRAPHY[63ROB/WAL] Roberts
Page 493 and 494:
468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
Page 495 and 496:
470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
Page 497 and 498:
472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
Page 499 and 500:
474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
Page 501 and 502:
476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
Page 503 and 504:
478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
Page 505 and 506:
480 BIBLIOGRAPHY[71MOS][71MOS2][71M
Page 507 and 508:
482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
Page 509 and 510:
484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
Page 511 and 512:
486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
Page 513 and 514:
488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
Page 515 and 516:
490 BIBLIOGRAPHY298.15 K”, J. Che
Page 517 and 518:
492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
Page 519 and 520:
494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
Page 521 and 522:
496 BIBLIOGRAPHYof plutonium(IV)”
Page 523 and 524:
498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
Page 525 and 526:
500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
Page 527 and 528:
502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
Page 529 and 530:
504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532:
506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
Page 533 and 534:
508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
Page 535 and 536:
510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538:
512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
Page 539 and 540:
514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
Page 541 and 542:
516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
Page 543 and 544:
518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
Page 545 and 546:
520 BIBLIOGRAPHYGeochim. Cosmochim.
Page 547 and 548:
522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
Page 549 and 550:
524 BIBLIOGRAPHY254, 258, 258, 264,
Page 551 and 552:
526 BIBLIOGRAPHY[91MEI][91NIT][91OK
Page 553 and 554:
528 BIBLIOGRAPHYment”, Waste Mana
Page 555 and 556:
530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
Page 557 and 558:
532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
Page 559 and 560:
534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562:
536 BIBLIOGRAPHYK, gas-phase infrar
Page 563 and 564:
538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
Page 565 and 566:
540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
Page 567 and 568:
542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
Page 569 and 570:
544 LIST OF CITED AUTHORSTable 23.1
Page 571 and 572:
Page 573 and 574:
Page 575 and 576:
Page 577 and 578:
Page 579 and 580:
Page 581 and 582:
Page 583 and 584:
Page 585 and 586:
Page 587 and 588:
Page 589 and 590:
Page 591 and 592:
Page 593 and 594:
Page 596 and 597:
Appendix ADiscussion of selected re
Page 598 and 599:
A. Discussion of selected reference
Page 600 and 601:
Page 602 and 603:
Page 604 and 605:
Page 606 and 607:
Page 608 and 609:
Page 610 and 611:
Page 612 and 613:
Page 614 and 615:
Page 616 and 617:
Page 618 and 619:
Page 620 and 621:
Page 622 and 623:
Page 624 and 625:
Page 626 and 627:
Page 628 and 629:
Page 630 and 631:
Page 632 and 633:
Page 634 and 635:
Page 636 and 637:
Page 638 and 639:
Page 640 and 641:
Page 642 and 643:
Page 644 and 645:
Page 646 and 647:
Page 648 and 649:
Page 650 and 651:
Page 652 and 653:
Page 654 and 655:
Page 656 and 657:
Page 658 and 659:
Page 660 and 661:
Page 662 and 663:
Page 664 and 665:
Page 666 and 667:
Page 668 and 669:
Page 670 and 671:
Page 672 and 673:
Page 674 and 675:
Page 676 and 677:
Page 678 and 679:
Page 680 and 681:
Page 682 and 683:
Page 684 and 685:
Page 686 and 687:
Page 688 and 689:
Page 690 and 691:
Page 692 and 693:
Page 694 and 695:
Page 696 and 697:
Page 698 and 699:
Page 700 and 701:
Page 702 and 703:
Page 704 and 705:
Page 706 and 707:
Page 708 and 709:
Page 710 and 711:
Page 712 and 713:
Page 714 and 715:
Page 716 and 717:
Page 718 and 719:
Page 720 and 721:
Page 722 and 723:
Page 724 and 725:
Page 726 and 727:
Page 728 and 729:
Page 730 and 731:
Page 732 and 733:
Page 734 and 735:
Page 736 and 737:
Page 738 and 739:
Page 740 and 741:
Page 742 and 743:
Page 744 and 745:
Page 746 and 747:
Page 748 and 749:
Page 750 and 751:
Page 752 and 753:
Page 754 and 755:
Page 756 and 757:
Page 758 and 759:
Page 760 and 761:
Page 762 and 763:
Page 764 and 765:
Page 766 and 767:
Page 768 and 769:
Page 770 and 771:
Page 772 and 773:
Page 774 and 775:
Page 776 and 777:
Page 778 and 779:
5 −10.63±0.11 (g) −12.48±0.23
Page 780 and 781:
Page 782 and 783:
Page 784 and 785:
Page 786 and 787:
Page 788 and 789:
dataarein1MNa + media, except as no
Page 790 and 791:
Page 792 and 793:
Page 794 and 795:
Page 796 and 797:
Page 798 and 799:
Page 800 and 801:
Page 802 and 803:
Page 804 and 805:
Page 806 and 807:
Page 808 and 809:
Page 810 and 811:
Page 812 and 813:
Page 814 and 815:
Page 816 and 817:
Page 818 and 819:
Page 820 and 821:
Page 822 and 823:
Page 824 and 825:
Appendix BIonic strength correction
Page 826 and 827:
B.1 The specific ion interaction eq
Page 828 and 829:
Page 830 and 831:
Page 832 and 833:
Page 834 and 835:
Page 836 and 837:
B.2 Ion interaction coefficients ve
Page 838 and 839:
B.3 Tables of ion interaction coeff
Page 840 and 841:
Page 842 and 843:
Page 844 and 845:
Page 846 and 847:
Page 848 and 849:
Appendix CAssigned uncertainties
Page 850 and 851:
C.2 Two or more independent source
Page 852 and 853:
C.2 Two or more independent source
Page 854 and 855:
C.3 Several data at different ionic
Page 856 and 857:
C.3 Several data at different ionic
Page 858 and 859:
C.4 Procedures for data handling 83
Page 860 and 861:
C.4 Procedures for data handling 83
Page 862 and 863:
Index837
Page 864 and 865:
INDEX - GENERAL 839standard state p
Page 866 and 867:
INDEX - NEPTUNIUM 841elemental nept
Page 868 and 869:
INDEX - PLUTONIUM 843Index - pluton
Page 870:
INDEX - PLUTONIUM 845monobismuthide
show all

chemical thermodynamics of neptunium and plutonium - U.S. ...

Create successful ePaper yourself

Delete template?

Save as template?