chemical thermodynamics of neptunium and plutonium - U.S. ...

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45Table 3.1: (continued)Compound f G ◦ m f Hm ◦ Sm ◦ Cp,m◦(kJ · mol −1 ) (kJ · mol −1 ) (J · K −1 · mol −1 ) (J · K −1 · mol −1 )(NH 4 ) 4 NpO 2 (CO 3 ) 3 (s) −2850.284 (b)±6.106Np(SCN) 3+ −416.198 (b) −486.622 (b) −248.165 (b)±7.081 ±6.520 ±25.449Np(SCN) 2+2 −329.777 (b) −412.222 (b) −89.545 (b)±10.166 ±12.748 ±50.953Np(SCN) + 3 −241.072 (b) −339.822 (b) 54.707 (b)±13.541 ±15.573 ±66.304(UO 2 ) 2 NpO 2 (CO 3 ) 6−6 −6174.307 (b)±16.981Sr 3 NpO 6 (cr) −3125.800±5.900Ba 3 NpO 6 (cr) −3085.600±9.600Ba 2 MgNpO 6 (cr) −3096.900±8.200Ba 2 CaNpO 6 (cr) −3159.300±7.900Ba 2 SrNpO 6 (cr) −3122.500±7.800Li 2 NpO 4 (cr) −1828.200±5.800α − Na 2 NpO 4 −1763.800±5.700β − Na 2 NpO 4 −1748.500±6.100β − Na 4 NpO 5 −2315.400±5.700Na 2 Np 2 O 7 (cr) −2894.000±11.000Na 3 NpF 8 (cr) −3521.239 (a) −3714.000 369.000 272.250 (c)±21.305 ±21.000 ±12.000 ±12.000NaNpO 2 CO 3 (s, aged)−1764.157 (b)±6.326Na 3 NpO 2 (CO 3 ) 2 (s)−2833.333 (b)±6.839NaNpO 2 CO 3·3.5H 2 O(s, fresh) −2591.287 (b)±5.991K 2 NpO 4 (cr) −1784.300±6.400K 2 Np 2 O 7 (cr) −2932.000±11.000K 4 NpO 2 (CO 3 ) 3 (s)−3660.395 (b)±7.641(Continued on next page)
46 3. Selected <strong>neptunium</strong> dataTable 3.1: (continued)Compound f G ◦ m f Hm ◦ Sm ◦ Cp,m◦(kJ · mol −1 ) (kJ · mol −1 ) (J · K −1 · mol −1 ) (J · K −1 · mol −1 )Rb 2 Np 2 O 7 (cr) −2914.000±12.000Cs 2 NpO 4 (cr) −1788.100±5.700Cs 2 NpCl 6 (cr) −1833.039 (a) −1976.200 410.000±4.871 ±1.900 ±15.000Cs 2 NpO 2 Cl 4 (cr) −2056.100±5.400Cs 3 NpO 2 Cl 4 (cr) −2449.100±4.800Cs 2 NpBr 6 (cr) −1620.121 (a) −1682.300 469.000±3.616 ±2.000 ±10.000Cs 2 NaNpCl 6 (cr) −2217.200±3.100(a) Value calculated internally with the Gibbs-Helmholtz equation, f G ◦ m = f H ◦ m −T ∑ i S◦ m,i .(b) Value calculated internally from reaction data (see Table 3.2).(c) Temperature coefficients <strong>of</strong> this function are listed in Table 3.3.(d) A temperature function for the heat capacity is given in Table 3.3.
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
Page 20 and 21: List of Tables2.1 Symbols and termi
Page 22 and 23: LIST OF TABLESxxi20.2 Experimental
Page 24 and 25: List of Figures2.1 Standard order o
Page 26: Part IIntroductory material1
Page 29 and 30: 4 1. IntroductionInorganic Complexe
Page 31 and 32: 6 1. Introductionlected, but form a
Page 34 and 35: Chapter 2Standards, Conventions, an
Page 36 and 37: 2.1 Symbols, terminology and nomenc
Page 48 and 49: 2.2 Units and conversion factors 23
Page 50 and 51: 2.2 Units and conversion factors 25
Page 52 and 53: 2.3 Standard and reference conditio
Page 54 and 55: 2.3 Standard and reference conditio
Page 56 and 57: 2.5 Uncertainty estimates 31Table 2
Page 58 and 59: 2.7 Presentation of the selected da
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Page 64 and 65: Chapter 3Selected neptunium dataThi
Page 66 and 67: 41Table 3.1: Selected thermodynamic
Page 68 and 69: 43Table 3.1: (continued)Compound f
Page 74 and 75: 49Table 3.2: (continued)SpeciesReac
Page 78 and 79: Chapter 4Selected plutonium dataThi
Page 86 and 87: 61SpeciesPu(OH) 3 (cr)ReactionTable
Page 90 and 91: Chapter 5Selected auxiliary dataThi
Page 102 and 103: (footnotes continued)(p) Data from
Page 104 and 105: 79Table 5.2: (continued)Species Rea
Page 106: 81Table 5.2: (continued)Species Rea
Page 110 and 111: Chapter 6Elemental neptunium6.1 Nep
Page 112 and 113: 6.1 Neptunium crystal and liquid 87
Page 114: 6.2 Neptunium ideal monatomic gas 8
Page 117 and 118: 92 7. Neptunium aqua ionsE ◦′ (
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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