chemical thermodynamics of neptunium and plutonium - U.S. ...

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12.1 Neptunium carbon compounds and complexes 287Table 12.9: Experimental equilibrium data for the neptunium(V) thiocyanate system.Method Ionic medium t ( ◦ C) log 10 β q(a) ReferenceNpO + 2 + SCN− Å NpO 2 SCN(aq)sp 5 M (NaClO 4 ) 25 0.86 [77CUI/MUS]pot 9 M (NaClO 4 ) 25 1.03 [77MUS/MAR]sp 9 M (NaClO 4 ) 25 1.23dis 2 M (H, Na)ClO 4 25 (0.32 ± 0.02) [79RAO/GUD]dis 8.5 M(H, Na)ClO 4 25 0.91 [81PAT/RAM]NpO + 2 + 2SCN− Å NpO 2 (SCN) − 2sp 5 M (NaClO 4 ) 25 1.05 [77CUI/MUS]pot 9 M (NaClO 4 ) 25 1.56 [77MUS/MAR]sp 9 M (NaClO 4 ) 25 1.91dis 8.5 M(H, Na)ClO 4 25 1.07 [81PAT/RAM]NpO + 2 + 3SCN− Å NpO 2 (SCN) 2−3sp 5 M (NaClO 4 ) 25 0.89 [77CUI/MUS]pot 9 M (NaClO 4 ) 25 1.60 [77MUS/MAR]sp 9 M (NaClO 4 ) 25 2.04NpO + 2 + 4SCN− Å NpO 2 (SCN) 3−4sp 5 M (NaClO 4 ) 25 −0.11 [77CUI/MUS]pot 9 M (NaClO 4 ) 25 1.56 [77MUS/MAR]sp 9 M (NaClO 4 ) 25 1.72NpO + 2 + 5SCN− Å NpO 2 (SCN) 4−5sp 9 M (NaClO 4 ) 25 0.46 [77MUS/MAR](a) log 10 β q refers to the equilibrium and the ionic strength given in the table.
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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Page 264 and 265: (f) Values selected in this review
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Page 314 and 315: Chapter 13Neptunium group 2(alkalin
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Page 322 and 323: Chapter 15Elemental plutonium15.1 P
Page 324 and 325: 15.2 Plutonium ideal monatomic gas
Page 326 and 327: Chapter 16Plutonium aqua ionsPluton
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17.2 Solid plutonium oxides and hyd
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346 18. Plutonium group 17 (halogen
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PuO 2+2+ F − Å PuO 2 F + (b)cix
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Chapter 19Plutonium group 16 compou
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19.1 Plutonium sulphur compounds an
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402 20. Plutonium group 15 compound
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dis, TTA 2 M HClO 4 10 (0.57 ± 0.0
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ut does not exist as cited (there i
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Chapter 21Plutonium group 14 compou
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21.1 Plutonium carbon compounds and
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Chapter 22Plutonium group 2(alkalin
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22.2 Plutonium barium compounds 447
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Bibliography[22BRØ][22BRØ2][35GUG
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BIBLIOGRAPHY 453[49HIN/AME][49HIN/M
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BIBLIOGRAPHY 455[50BUS/COW][50EYR/W
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BIBLIOGRAPHY 457[53JON][53RAB][53WE
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BIBLIOGRAPHY 459[56RAB]Rabideau, S.
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BIBLIOGRAPHY 461[59AXE/IHL][59BJO/R
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BIBLIOGRAPHY 463[60RAB/KLI][61BEN/D
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BIBLIOGRAPHY 465[62SCH/NEB] Schwabe
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BIBLIOGRAPHY 467[64GEL/ZAI][64KAY/L
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BIBLIOGRAPHY 469[65MUL/ELL][65PAR][
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BIBLIOGRAPHY 471[66RAN][66RYK/YAK][
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BIBLIOGRAPHY 473[67SOL/TSV][68AHR/B
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BIBLIOGRAPHY 475[68TRE/GER][68ZAI/A
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BIBLIOGRAPHY 477[69SUL/ZIE][70AL-/W
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BIBLIOGRAPHY 479hexammine cobalt(II
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BIBLIOGRAPHY 481[72BLO/BUK][72BLO/B
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BIBLIOGRAPHY 483radioactif., CEN, F
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BIBLIOGRAPHY 485169, 169, 169, 170,
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BIBLIOGRAPHY 487[75ACK/RAU][75ALE/O
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BIBLIOGRAPHY 489other Actinides, he
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BIBLIOGRAPHY 491[76OET/RAN][76PAR][
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BIBLIOGRAPHY 493[77MUS/MAR] Musikas
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BIBLIOGRAPHY 495[78RAO/BAG][78RAO/B
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BIBLIOGRAPHY 497[79MUE/LAN][79PIT][
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BIBLIOGRAPHY 499and plutonium sesqu
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BIBLIOGRAPHY 501[81RAI/SWA][81ROL/G
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BIBLIOGRAPHY 503[82MOR/FUG][82NAI/C
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BIBLIOGRAPHY 505[83KIM/LIE][83MAR/H
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BIBLIOGRAPHY 507[84BUS/PLU][84CHO/R
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BIBLIOGRAPHY 509[84REE/DAN][84VAR/B
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BIBLIOGRAPHY 511The gaseous actinid
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BIBLIOGRAPHY 513[86BLA/FRE][86BRO/F
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BIBLIOGRAPHY 515and Radiation Chemi
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BIBLIOGRAPHY 517[87RAI/SWA][87RIC/S
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BIBLIOGRAPHY 519Can. J. Chem., 66 (
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BIBLIOGRAPHY 521[89RÖS/DIT][89SAW/
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BIBLIOGRAPHY 523[90KRI/HAG][90LEI][
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BIBLIOGRAPHY 525[91AND/CAS][91BYR/L
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BIBLIOGRAPHY 527[91WAN][91YAM/PRA][
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BIBLIOGRAPHY 529diochim. Acta, 58/5
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BIBLIOGRAPHY 531[93OKA/MAE][93OKA/R
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BIBLIOGRAPHY 533[94GIF/VIT][94GRI/C
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BIBLIOGRAPHY 535[94VEI/SMI][94YAM/S
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BIBLIOGRAPHY 537RC-1407 and COG-I-9
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BIBLIOGRAPHY 539lecular structure o
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BIBLIOGRAPHY 541in the Plutonium(IV
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List of cited authorsThis chapter c
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LIST OF CITED AUTHORS 545Table 23.1
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Part VAppendices569
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572 A. Discussion of selected refer
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y this review (from these experimen
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800 B. Ionic strength correctionsin
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802 B. Ionic strength correctionsEq
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804 B. Ionic strength correctionsTh
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806 B. Ionic strength correctionsof
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808 B. Ionic strength correctionsFi
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810 B. Ionic strength correctionsNE
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812 B. Ionic strength correctionsIt
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814 B. Ionic strength correctionsTa
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The uncertainties represent the 95%
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824 C. Assigned uncertaintiesX ± 1
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826 C. Assigned uncertaintiesii. If
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828 C. Assigned uncertaintiestwo gr
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830 C. Assigned uncertaintiesNote t
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832 C. Assigned uncertaintiesI m el
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834 C. Assigned uncertaintiesBeving
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836 C. Assigned uncertaintiesIn the
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838 IndexIndex - generalabbreviatio
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840 IndexIndex - neptuniumactinide
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842 Indexlithium compoundsLi 2 NpO
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844 IndexPuOCl(cr), 360chlorine com
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