chemical thermodynamics of neptunium and plutonium - U.S. ...

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LIST OF CITED AUTHORS 565Table 23.1: (continued)AuthorStepanova, E. S.Stephens, D. R.Sterner, S. R.Steunenberg, R. K.Stokes, R. H.Storms,E.K.Stoughton, R. W.Street, R. S.Strickert, R. G.Stromatt, R. W.Struchkov, Y. T.Stumm, W.Sturtevant, J. M.Sudakov, L. V.Suglobov, D. N.Sullivan, J.Sullivan, J. C.Sutcliffe, P. W.Suzuki, Y.Sverjensky, D. A.Swang, O.Swanson, J. L.Swendeman, N.Sykes, K. W.Sylva, R. N.Syverud, A. N.Söhnel, O.Tran The, P.Tait, D. C.Takahashi, Y.Talnikar, S. G.Tanaka, S.Tananaev, I. G.Tanet, G.Tanger, IV, J. C.Tannenbaum, I. R.Taranov, A. P.Tasker, I. R.Taylor, B. L.Taylor, J. R.Taylor, P.References[76SHI/STE][66STE][97FEL/RAI][61TRE/SHI][59ROB/STO][84HOL/RAN][61STO/FRY][62RAN/FOX], [65GAR/MAR][85KRU/RAI][58STR/PEE][94GRI/CHA][81STU/MOR][59STU][73SUD/SOL][76VOD/KOL][54SUL/AME][54SUL/HIN], [55COH/SUL], [59SUL/HIN], [61SUL/HIN],[69SUL/ZIE], [78WOO/MIT], [80SCH/GOR], [81WES/SUL],[82SUL/WOO], [83SCH/GOR], [83WES/SUL], [84MUL/GOR],[85NEW/SUL], [85SCH/FRI], [85THO/NAS], [91SUL/CHO],[93PAS/KIM], [93PAS/KIM2], [94RIZ/RAO][70LEE/MEN], [78HAL/LEE][83SUZ/ARA], [92SUZ/MAE], [93OKA/MAE], [94ARA/OKA],[97NAK/ARA], [97NAK/ARA2][89SHO/HEL2], [92SHO/OEL][95HAA/MAR][80RAI/SER2], [81RAI/SWA], [87RAI/SWA][59DEB/LIC][62SYK/TAY], [64GAI/SYK][83BRO/ELL][85CHA/DAV][85SÖH/NOV][91VIT/TRA][96CLA/CON], [96CLA/CON2][88NAG/TAN][79CHI/TAL][88NAG/TAN], [89TAN/NAG], [91ITA/TAN], [92ITA/NAK][89TAN], [90TAN], [91SHI/TAN], [94TAN][85BID/TAN][88TAN/HEL][56FLO/TAN][79BEL/SMI][88TAS/O’H][62SYK/TAY][82TAY][93TAY/LEM](Continued on next page)
566 LIST OF CITED AUTHORSTable 23.1: (continued)AuthorTeague, L. S.Tennery, V. J.Tetenbaum, M.Thevenin, T.Thomason, H. P.Thompson, M. C.Thompson, M. E.Thompson, R. C.Thorn, R. J.Thorstenson, D. C.Timoshev, V. G.Tochiyama, O.Tolmachev, Y. M.Tomat, G.Tomilin, S. V.Tondello, E.Torres, R. A.Torretto, P. C.Trabalka, J. R.Trautmann, N.Treiber, W.Tremaine, P. R.Trevorrow, L. E.Truswell, A. E.Tsvetkova, Z. N.Tucker, D. B.Tul’skii, M. N.Turcotte, R. P.Ueno, K.Ueta, S.Ullman, W. J.Unrein, P. J.Ustinov,V.A.VanCamp, J. B.Varlashkin, P. G.Vasil’ev, V. P.Vasil’ev, V. Y.Vaughn, G. A.Vavilov, S. K.Veirs, D. K.Veits, I. V.Vernyi, E. A.Vinogradov, A. V.References[80BEN/TEA][71TEN/BOM][81FLO/TET], [83TET][86THE/JOV][86EWA/HOW], [92EWA/SMI][83SCH/GOR][85THO/NAS][80SCH/GOR][66ACK/FAI][80PAR/THO][59SHE/TIM][85INO/TOC], [85INO/TOC2][75BEL/IL’][72CAS/MAG2][79VOL/TOM], [79VOL/VIS], [79VOL/VIS2], [81VOL/VIS],[81VOL/VIS2], [81VOL/VIS3], [81VOL/VIS4][72CAS/MAG][92BEN/HOF][96ROB/SIL][80BON/TRA][89KIM/KAN2][85LIE/TRE][80LEM/TRE], [89HOV/NGU][61TRE/SHI], [68TRE/GER][54DAW/ELL][67SOL/TSV][88TUC/STA][78DRO/SER][76FAH/TUR][70UEN/HOS], [75UEN/SAI], [77SAI/UEN], [78SAI/UEN][95YAJ/KAW][86ULL/SCH], [88ULL/SCH][76CHO/UNR][74ARK/GUT], [79BEL/DOB][61PAU/GAL][84VAR/BEG], [84VAR/HOB][62VAS][73RYK/BLO], [75VAS/AND], [75VAS/AND2][70WIT/VAU][69LEB/BAB][94VEI/SMI], [96ALL/VEI][82GLU/GUR][64MAR/VER][64MAR/VER](Continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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Page 543 and 544: 518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
Page 547 and 548: 522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
Page 549 and 550: 524 BIBLIOGRAPHY254, 258, 258, 264,
Page 551 and 552: 526 BIBLIOGRAPHY[91MEI][91NIT][91OK
Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
Page 555 and 556: 530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
Page 557 and 558: 532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
Page 563 and 564: 538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
Page 567 and 568: 542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
Page 569 and 570: 544 LIST OF CITED AUTHORSTable 23.1
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Page 596 and 597: Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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