chemical thermodynamics of neptunium and plutonium - U.S. ...

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BIBLIOGRAPHY 525[91AND/CAS][91BYR/LEE][91CHO/MAT]Anderson, G. M., Castet, S., Schott, J., Mesmer, R. E., “The densitymodel for estimation of thermodynamic parameters of reactions athigh temperatures and pressures”, Geochim. Cosmochim. Acta, 55(1991) 1769–1779. Cited pages 33, 543, 546, 557, 563Byrne, R. H., Lee, J. H., Bingler, L. S., “Rare earth elementcomplexation by PO 3−4ions in aqueous solution”, Geochim.Cosmochim. Acta, 55 (1991) 2729–2735. Cited pages 545, 546,555, 637Choppin, G. R., Mathur, J. N., “Hydrolysis of actinyl(VI) cations”,Radiochim. Acta, 52/53 (1991) 25–28. Cited pages 546, 557, 750[91DIN] Dinsdale, A. T., “SGTE data for pure elements”, CALPHAD, 15(1991) 317–425. Cited pages 27, 548[91FRE/KEL][91GOU/JEM][91ITA/TAN][91KIM/KLE][91KIM/PAS]Freeman, A. J., Keller, C., eds., Handbook on the physics and chemistryof the actinides, vol. 6, Amsterdam: North-Holland, 1991, 742p. Cited pages 4Goudiakas, J., Jemine, X., Fuger, J., “Thermodynamics of lanthanideand actinide perovskite-type and related oxides: V. Molar enthalpiesof formation of M 2 NpO 4 (M = Li, Na, K, or Cs) and ofβ-Na 4 NpO 5 ”, J. Chem. Thermodyn., 23 (1991) 513–520. Citedpages 291, 291, 292, 292, 292, 293, 550, 550, 553, 750Itagaki, H., Tanaka, S., Yamawaki, M., “Neptunium chemical behaviorin underground environments using ultrafiltration and centrifugation”,Radiochim. Acta, 52–53 (Part 1) (1991) 91–94. Citedpages 553, 565, 568, 731Kim, J. I., Klenze, R., Neck, V., Sekine, T., Kanellakopulos,B., “Hydrolyse, Carbonat- und Huma-Komplexierung von Np(V)”,Tech. Rep. RCM 01091, Institut für Radiochemie, Technische UniversitätMünchen, Germany, 1991, 61 p., in German. Cited pagesxxi, xxii, 222, 222, 226, 227, 228, 228, 229, 229, 230, 231, 231,231, 232, 233, 233, 233, 238, 239, 241, 241, 241, 242, 242, 242,242, 243, 244, 246, 250, 250, 275, 275, 277, 279, 553, 554, 554,559, 563, 632, 714, 744, 745, 750, 750, 751, 751, 751, 752, 753,754, 760, 761, 774, 774, 774, 775, 775, 775, 775, 776, 776, 776,776, 779, 780, 785Kim, J. I., Pashalidis, I., “Bildung und Pu(VI)-Komplexierungvon Hypochlorit in radiolisierenden stark salinen Lösungen”, Tech.Rep. RCM 01291, TU München, München, 1991, 49 p., in German.Cited pages 385, 554, 560
526 BIBLIOGRAPHY[91MEI][91NIT][91OKA/REE][91POS/ROV][91PRA/YAM][91SHI/TAN][91SUL/CHO][91VIT/OLI][91VIT/TRA]Meinrath, G., Carbonate complexation of the trivalent americiumunder groundwater conditions, Ph.D. thesis, Technische UniversitätMünchen, Garching, Germany, 1991, 199 p., in German. Citedpages 557, 774Nitsche, H., “Solubility studies of transuranium elements for nuclearwaste disposal: Principles and overview”, Radiochim. Acta,52/53 (1991) 3–8. Cited pages 121, 559Okajima, S., Reed, D. T., Beitz, J. V., Sabau, C. A., Bowers,D. L., “Speciation of Pu(VI) in near-neutral solutions via laser photoacousticspectroscopy”, Radiochim. Acta, 52/53 (1991) 111–117.Cited pages 319, 327, 544, 545, 559, 562, 562, 738, 738, 754, 767Posokhov, A. K., Rovnyi, S. I., “Features of the sorption and depositionof actinides onto stainless steel from HNO 3 : II, Forms of Npsorbed from HNO 3 ”, Radiochemistry (Moscow), 33 (1991) 183–186. Cited pages 561, 562, 754Pratopo, M. I., Yamaguchi, T., Moriyama, H., Higashi, K., “Adsorptionof Np(IV) on quartz in carbonate solutions”, Radiochim.Acta, 55 (1991) 209–213. Cited pages 552, 558, 561, 568, 767Shilov, V. P., Tananaev, I. G., Krot, N. N., “Form of Np(VII) inacidic media”, Sov. Radiochem., 33 (1991) 250–251. Cited pages92, 105, 555, 564, 565Sullivan, J. C., Choppin, G. R., Rao, L. F., “Calorimetric studiesof NpO + 2hydrolysis”, Radiochim. Acta, 54 (1991) 17–20. Citedpages 110, 546, 561, 565, 755Vitorge, P., Oliver, J., Mangin, J. P., Billon, A., “Studies of thephysico-chemical properties on the transuranian elements in connectionwith the migration phenomenon in the geosphere, Task 3characterization of radioactive waste forms, a series of final reports(1985-89) – No. 30”, Tech. Rep. EUR 13673, CEC Nuclear Scienceand Technology, Commission of the European CommunitiesLuxembourg, Luxembourg, 1991. Cited pages 544, 556, 559, 567,619, 714, 755Vitorge, P., Tran The, P., “Solubility limits of radionuclides in interstitialwater – Americium in cement. Task 3–Characterizationofradioactive waste forms. A series of final reports (1985–89) – No.34”, Tech. Rep. EUR 13664, Commission of the European CommunitiesLuxembourg, Luxembourg, 1991, 39 p. Cited pages 565,567, 722
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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Page 513 and 514: 488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
Page 515 and 516: 490 BIBLIOGRAPHY298.15 K”, J. Che
Page 517 and 518: 492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
Page 519 and 520: 494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
Page 521 and 522: 496 BIBLIOGRAPHYof plutonium(IV)”
Page 523 and 524: 498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
Page 525 and 526: 500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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Page 529 and 530: 504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532: 506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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Page 535 and 536: 510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538: 512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
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Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
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Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
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Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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Page 569 and 570: 544 LIST OF CITED AUTHORSTable 23.1
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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