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55Table 4.1: Selected thermodynamic data for plutonium compounds and complexes. Allionic species listed in this table are aqueous species. Unless noted otherwise, all datarefer to the reference temperature of 298.15 K and to the standard state, i.e., a pressureof 0.1 MPa and, for aqueous species, infinite dilution (I = 0). The uncertainties listedbelow each value represent total uncertainties and correspond in principal to the statisticallydefined 95% confidence interval. Values obtained from internal calculation,cf. footnotes (a) and (b), are rounded at the third digit after the decimal point and maytherefore not be exactly identical to those given in Part IV. Systematically, all the valuesare presented with three digits after the decimal point, regardless of the significanceof these digits. The data presented in this table are available on PC diskettes or othercomputer media from the OECD Nuclear Energy Agency.Compound f G ◦ m f Hm ◦ Sm ◦ Cp,m◦(kJ · mol −1 ) (kJ · mol −1 ) (J · K −1 · mol −1 ) (J · K −1 · mol −1 )Pu(cr) 0.000 0.000 54.460 31.490 (c)β − Pu (e)γ − Pu (e)δ − Pu (e)δ ′ − Pu (e)ε − Pu (e)±0.800 ±0.400Pu(g) 312.415 (a) 349.000 (b) 177.167 20.854 (c)±3.009 ±3.000 ±0.005 ±0.010Pu 3+ −578.984 −591.790 −184.510 (b)±2.688 ±1.964 ±6.154Pu 4+ −477.988 −539.895 −414.535±2.705 ±3.103 ±10.192PuO 1.61 (cr, bcc) −834.771 (a) −875.500 83.000 61.200 (c)±10.113 ±10.000 ±5.000 ±5.000PuO 2 (cr) −998.113 (a) −1055.800 66.130 66.250 (c)±1.031 ±1.000 ±0.260 ±0.260PuO 2 (hyd, aged)−963.654 (b)±6.324PuO + 2 −852.646 (b) −910.127 (a) 1.480 (b)±2.868 ±8.920 ±30.013PuO 2+2 −762.353 −822.036 −71.246±2.821 ±6.577 ±22.120Pu 2 O 3 (cr) −1580.375 (a) −1656.000 163.000 117.000 (c)PuOH 2+±10.013 ±10.000 ±0.600 ±0.500−776.739 (b)±3.187(Continued on next page)
56 4. Selected plutonium dataTable 4.1: (continued)Compound f G ◦ m f Hm ◦ Sm ◦ Cp,m◦(kJ · mol −1 ) (kJ · mol −1 ) (J · K −1 · mol −1 ) (J · K −1 · mol −1 )PuOH 3+ −710.676 (b) −789.725 (b) −238.773 (a)±4.364 ±10.470 ±36.889PuO 2 OH(am) −1061.246 (b) −1159.793 (a) 97.000 86.000±4.046 ±6.036 ±15.000 ±20.000PuO 2 OH(aq)≥−1034.247 (b)PuO 2 OH + −968.099 (b) −1079.866 (b) −12.680 (b)±4.013 ±16.378 ±55.786Pu(OH) 3 (cr)−1200.218 (b)±8.975PuO 2 (OH) 2 (aq) (d) −1161.287 (b)±9.015PuO 2 (OH) 2·H 2 O(cr) −1442.379 (b) −1632.808 (a) 190.000 170.000±6.368 ±13.522 ±40.000 ±20.000(PuO 2 ) 2 (OH) 2+2 (d) −1956.176 (b)±8.026PuF(g) −140.967 (a) −112.600 251.000 33.500 (c)±10.113 ±10.000 ±5.000 ±3.000PuF 3+ −809.970 (b) −866.145 (b) −228.573 (b)±2.850 ±3.859 ±12.753PuF 2 (g) −626.151 (a) −614.300 297.000 51.500 (c)±6.704 ±6.000 ±10.000 ±5.000PuF 2+2−1130.651 (b) −1199.595 (b) −104.666 (b)±3.246 ±6.026 ±20.058PuF 3 (cr) −1517.369 (a) −1586.700 126.110 92.640 (c)±3.709 ±3.700 ±0.360 ±0.280PuF 3 (g) −1161.081 (a) −1167.800 336.110 72.240 (c)±4.758 ±3.700 ±10.000 ±5.000PuF 4 (cr) −1756.741 (a) −1850.000 147.250 116.190±20.002 ±20.000 ±0.370 ±0.290PuF 4 (g) −1517.874 (a) −1548.000 359.000 92.400 (c)±22.202 ±22.000 ±10.000 ±5.000PuF 6 (cr) −1729.856 (a) −1861.350 221.800 168.100 (c)±20.174 ±20.170 ±1.100 ±2.000PuF 6 (g) −1725.064 (a) −1812.700 368.900 129.320 (c)±20.104 ±20.100 ±1.000 ±1.000PuOF(cr) −1091.571 (a) −1140.000 96.000 69.400 (c)PuO 2 F +PuO 2 F 2 (aq)PuCl 2+±20.222 ±20.000 ±10.000 ±10.000−1069.905 (b)±3.121−1366.783 (b)±4.059−717.051 (b)±2.923(Continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
Page 29 and 30: 4 1. IntroductionInorganic Complexe
Page 31 and 32: 6 1. Introductionlected, but form a
Page 34 and 35: Chapter 2Standards, Conventions, an
Page 36 and 37: 2.1 Symbols, terminology and nomenc
Page 48 and 49: 2.2 Units and conversion factors 23
Page 50 and 51: 2.2 Units and conversion factors 25
Page 52 and 53: 2.3 Standard and reference conditio
Page 54 and 55: 2.3 Standard and reference conditio
Page 56 and 57: 2.5 Uncertainty estimates 31Table 2
Page 58 and 59: 2.7 Presentation of the selected da
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Page 64 and 65: Chapter 3Selected neptunium dataThi
Page 66 and 67: 41Table 3.1: Selected thermodynamic
Page 68 and 69: 43Table 3.1: (continued)Compound f
Page 72 and 73: 47Table 3.2: Selected thermodynamic
Page 74 and 75: 49Table 3.2: (continued)SpeciesReac
Page 78 and 79: Chapter 4Selected plutonium dataThi
Page 86 and 87: 61SpeciesPu(OH) 3 (cr)ReactionTable
Page 90 and 91: Chapter 5Selected auxiliary dataThi
Page 102 and 103: (footnotes continued)(p) Data from
Page 104 and 105: 79Table 5.2: (continued)Species Rea
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Page 110 and 111: Chapter 6Elemental neptunium6.1 Nep
Page 112 and 113: 6.1 Neptunium crystal and liquid 87
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Page 119 and 120: 94 7. Neptunium aqua ionsto the sta
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Page 123 and 124: 98 7. Neptunium aqua ionsnon-system
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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