chemical thermodynamics of neptunium and plutonium - U.S. ...

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BIBLIOGRAPHY 515and Radiation Chemistry held 13–17 December in Tirupati, India”,1986, pp. 353–355. Cited pages 371, 546, 556, 560, 563, 722, 768,768[86MOR][86NOR/MUN][86ORL/PEN][86PRY/REE][86THE/JOV][86ULL/SCH][86WAR/KLE][86WEI/HEL][86WEI/KAT]Morss, L. R., Thermodynamic properties, in: The chemistry of theactinide elements, 2nd ed., vol. 2, London: Chapman and Hall,1986, pp. 1278–1360, Katz, J. J., Seaborg, G. T., Morss, L. R.,editors. Cited pages 91, 98, 129, 558Nordstrom, D. K., Munoz, J. L., Geochemical Thermodynamics,Palo Alto: Blackwell Sci. Publ., 1986, 477 p. Cited pages 21, 558,559Orlandini, K. A., Penrose, W. R., Nelson, D. M., “Plutonium(V)as the stable form of oxidized plutonium in natural waters”, Mar.Chem., 18 (1986) 47–57. Cited pages 391, 559, 559, 560Pryke, D. C., Rees, J. H., “Understanding the behaviour of the actinidesunder disposal conditions: a comparison between calculatedand experimental solubilities”, Radiochim. Acta, 40 (1986) 27–32.Cited pages 561, 562, 722Thevenin, T., Jove, J., Madic, C., “Crystal chemistry and 237 NpMössbauer investigations of neptunyl(VI) carbonate NpO 2 CO 3 ,Actinide 85, Aix-en-Provence”, J. Less-Common Met., 121 (1986)477–481. Cited pages 553, 556, 566, 721Ullman, W. J., Schreiner, F., “Calorimetric determination of theenthalpies of U(VI)-, Np(VI)-, and Pu(VI)-SO 2−4complexes inaqueous solution at 25 ◦ C”, Radiochim. Acta, 40 (1986) 179–183.Cited pages 178, 178, 179, 179, 179, 180, 180, 180, 180, 180, 389,389, 389, 390, 390, 391, 391, 563, 566, 617, 722, 728Ward, J. W., Kleinschmidt, P. D., Peterson, D. E., Handbook on thephysics and chemistry of the actinides, vol. 4, chap. “Thermochemicalproperties of the actinide elements and selected actinide-noblemetal intermetallics”, Amsterdam: North-Holland, 1986, pp. 309–412. Cited pages 88, 88, 88, 89, 299, 554, 560, 567Weigel, F., Hellmann, H., “On some sulphates of hexavalent neptuniumand plutonium”, J. Less-Common Met., 121 (1986) 415–423.Cited pages 185, 551, 567, 723Weigel, F., Katz, J. J., Seaborg, G. T., Plutonium, in: The chemistryof the actinide elements, 2nd edition, vol. 1, London: Chapman andHall, 1986, pp. 499–886, Katz, J. J., Seaborg, G. T., Morss, L. R.,editors. Cited pages 297, 342, 411, 415, 445, 449, 553, 563, 567
516 BIBLIOGRAPHY[87BEN][87BEN/HOF][87BRO/WAN][87CIA/IUL][87COR][87DEL][87FRE/LAN][87FUK/SIE][87GAR/PAR][87MAT/OHS][87NIT]Benedict, U., “Structural data of the actinide elements and of theirbinary compounds with non-metallic elements”, J. Less-CommonMet., 128 (1987) 7–45. Cited pages 187, 187, 544Bennett, D. A., Hoffman, D. C., Nitsche, H., Silva, R. J., “Preliminaryresults on the hydrolysis and carbonate complexation ofdioxoplutonium(V)”, Tech. Rep. LBL-24254, Lawrence BerkeleyLaboratory, California, USA, 1987, 22 p. Cited pages 544, 552,559, 564, 723Brown, P. L., Wanner, H., Predicted formation constants using theunified theory of metal ion complexation, Paris, France: OECDNuclear Energy Agency, 1987, 102 p. Cited pages 116, 116, 431,545, 567Ciavatta, L., Iuliano, M., Porto, R., “The hydrolysis of the La(III)ion in aqueous perchlorate solution at 60 ◦ C”, Polyhedron, 6 (1987)1283–1290. Cited pages 34, 546, 553, 561Cort, B., “Thermal expansion of neptunium”, J. Less-CommonMet., 135 (1987) L13–L17. Cited pages 85, 547Delegard, C. H., “Solubility of PuO 2·xH 2 O in alkaline Hanfordhigh-level waste solution”, Radiochim. Acta, 41 (1987) 11–21.Cited pages 439, 548, 723Freeman, A. J., Lander, G. H., eds., Handbook on the physicsand chemistry of the actinides, vol. 5, Amsterdam: North-Holland,1987, 375 p. Cited pages 4Fuks, L., Siekierski, S., “The position of plutonium /III/ in thelanthanide series in respect to thermodynamic functions of complexformation with nitrates and thiocyanates”, J. Radioanal. Nucl.Chem., 108 (1987) 139–148. Cited pages 405, 405, 550, 564, 723Garvin,D.,Parker,V.B.,White,Jr.,H.J.,CODATA thermodynamictables: Selection of some compounds of calcium and relatedmixtures: A prototype set of tables, Berlin: Springer-Verlag, 1987,356 p. Cited pages 23, 550, 560, 567Matsui, T., Ohse, R. W., “Thermodynamic properties of uraniumnitride, plutonium nitride and uranium-plutonium mixed nitride”,High Temp. High Pressures, 19 (1987) 1–17. Cited pages 401,402, 403, 404, 557, 559Nitsche, H., “Solubility of AmOHCO 3 in aqueous solution underatmospheric conditions”, Tech. Rep. LBL-21237 and UC-814,Lawrence Berkeley Lab., California, 1987, 9 p. Cited pages 559,724
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
Page 489 and 490: 464 BIBLIOGRAPHY[61SCH][61STO/FRY][
Page 491 and 492: 466 BIBLIOGRAPHY[63ROB/WAL] Roberts
Page 493 and 494: 468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
Page 495 and 496: 470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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Page 501 and 502: 476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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Page 505 and 506: 480 BIBLIOGRAPHY[71MOS][71MOS2][71M
Page 507 and 508: 482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
Page 509 and 510: 484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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Page 513 and 514: 488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
Page 515 and 516: 490 BIBLIOGRAPHY298.15 K”, J. Che
Page 517 and 518: 492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
Page 519 and 520: 494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
Page 521 and 522: 496 BIBLIOGRAPHYof plutonium(IV)”
Page 523 and 524: 498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
Page 525 and 526: 500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
Page 527 and 528: 502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
Page 529 and 530: 504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532: 506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
Page 533 and 534: 508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
Page 535 and 536: 510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538: 512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
Page 547 and 548: 522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
Page 549 and 550: 524 BIBLIOGRAPHY254, 258, 258, 264,
Page 551 and 552: 526 BIBLIOGRAPHY[91MEI][91NIT][91OK
Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
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Page 557 and 558: 532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
Page 563 and 564: 538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
Page 567 and 568: 542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
Page 569 and 570: 544 LIST OF CITED AUTHORSTable 23.1
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566 LIST OF CITED AUTHORSTable 23.1
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568 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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