chemical thermodynamics of neptunium and plutonium - U.S. ...

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1.3 Review procedure and results 7they are based on. The quality aspect includes both the numerical values of the thermodynamicdata used in the model and the “completeness” of the chemical model used,e.g., the inclusion of all the relevant dissolved chemical species and solid phases. Forthe user it is important to consider that the selected data set presented in this review(Chapters 3 and 4) may not be “complete” with respect to all the conceivable systemsand conditions; there are gaps in the information. The gaps are pointed out in the varioussections of Parts III and IV, and this information may be used as a basis for theassignment of research priorities.
Page 1 and 2: 4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
Page 3 and 4: CHEMICAL THERMODYNAMICSVol. 1. Chem
Page 5 and 6: Published under the imprint NORTH-H
Page 7 and 8: viPREFACEviewed several of the othe
Page 9 and 10: viiiACKNOWLEDGEMENTSand Whiteshell
Page 11 and 12: xFOREWORDsending comments on the TD
Page 13 and 14: xiiCONTENTSIII Discussion of neptun
Page 15: xivCONTENTS11.1.4.2 Solid neptunium
Page 18 and 19: CONTENTSxvii20.5.1 PuSb(cr) . . . .
Page 20 and 21: List of Tables2.1 Symbols and termi
Page 22 and 23: LIST OF TABLESxxi20.2 Experimental
Page 24 and 25: List of Figures2.1 Standard order o
Page 26: Part IIntroductory material1
Page 29 and 30: 4 1. IntroductionInorganic Complexe
Page 31: 6 1. Introductionlected, but form a
Page 35 and 36: 10 2. Standards, Conventions, and C
Page 62: Part IITables of selected data37
Page 65 and 66: 40 3. Selected neptunium datausing
Page 67 and 68: 42 3. Selected neptunium dataTable
Page 75 and 76: 50 3. Selected neptunium dataSpecie
Page 79 and 80: 54 4. Selected plutonium dataa part
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58 4. Selected plutonium dataTable
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66 5. Selected auxiliary dataHCO
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68 5. Selected auxiliary dataTable
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Part IIIDiscussion of neptunium dat
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86 6. Elemental neptuniumTable 6.1:
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88 6. Elemental neptuniumTable 6.4:
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Chapter 7Neptunium aqua ionsNeptuni
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7.2 NpO 2+293This is straight forwa
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7.2 NpO 2+295Table 7.2: Experimenta
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7.3 NpO + 297and r H m (7.6, 1MHCl
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7.5 Np 3+ 99enthalpy of formation o
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7.6 Summary 101for reaction (7.9).
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7.6 Summary 103Figure 7.2:SHE.Forma
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106 8. Neptunium oxygen and hydroge
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Chapter 9Neptunium group 17 (haloge
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9.1 Neptunium halide compounds 133T
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9.1 Neptunium halide compounds 135a
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9.1 Neptunium halide compounds 141p
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9.1 Neptunium halide compounds 143T
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9.1 Neptunium halide compounds 1459
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9.2 Aqueous neptunium group 17 (hal
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Chapter 10Neptunium group 16compoun
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10.1 Neptunium sulphur compounds an
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188 11. Neptunium group 15 compound
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sol 3 M NaClO 4 22 (15.72±0.51) [9
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ed 0.51 M K 2 CO 3 ? (0.451±0.010)
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was unique. The interpretation (pro
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Method Ionic medium t log 10 K (I c
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sol 3 M NaClO 25 (4.76±0.04) (e) (
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sp 5 M NaCl 23 (2.91±0.20) [96RUN/
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sol 1 M NaClO 30 −(10.7±0.1) −
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KNpO 2 CO 3·xH 2 O(s) + 2CO 3Å K
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K 3 NpO 2 (CO 3 ) 2·xH 2 O(s) + CO
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Reference log 10 Ks,0 ◦ log 10 K1
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3complex (Cl − addition to NpO 2
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Np(CO 3 ) 4−4 + CO 2−3Å Np(CO
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Np 4+ + 3CO 2−3Å Np(CO 3 ) 2−3
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10 21 3 2 3 3 2 3 2 3log 10 K s,0 N
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Chapter 13Neptunium group 2(alkalin
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Chapter 14Neptunium group 1 (alkali
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14.4 Neptunium rubidium compounds 2
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Chapter 15Elemental plutonium15.1 P
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15.2 Plutonium ideal monatomic gas
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Chapter 16Plutonium aqua ionsPluton
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16.2 PuO 2+2303After incorporating
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16.3 PuO + 2305Table 16.2: Experime
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16.3 PuO + 2307Blanc and Madic [84B
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16.4 Pu 4+ 309Table 16.3: Experimen
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16.4 Pu 4+ 311Figure 16.2: Formal p
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16.5 Pu 3+ 31316.5 Pu 3+The values
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16.6 Summary 315Figure 16.3: Standa
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Chapter 17Plutonium oxygen and hydr
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17.1 Aqueous plutonium hydroxide co
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2:2 LPAS 25 0.1 M ClO − −7.3
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17.2 Solid plutonium oxides and hyd
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346 18. Plutonium group 17 (halogen
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PuO 2+2+ F − Å PuO 2 F + (b)cix
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Chapter 19Plutonium group 16 compou
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19.1 Plutonium sulphur compounds an
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402 20. Plutonium group 15 compound
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dis, TTA 2 M HClO 4 10 (0.57 ± 0.0
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ut does not exist as cited (there i
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Chapter 21Plutonium group 14 compou
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21.1 Plutonium carbon compounds and
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Chapter 22Plutonium group 2(alkalin
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22.2 Plutonium barium compounds 447
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Bibliography[22BRØ][22BRØ2][35GUG
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BIBLIOGRAPHY 453[49HIN/AME][49HIN/M
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BIBLIOGRAPHY 455[50BUS/COW][50EYR/W
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BIBLIOGRAPHY 457[53JON][53RAB][53WE
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BIBLIOGRAPHY 459[56RAB]Rabideau, S.
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BIBLIOGRAPHY 461[59AXE/IHL][59BJO/R
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BIBLIOGRAPHY 463[60RAB/KLI][61BEN/D
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BIBLIOGRAPHY 465[62SCH/NEB] Schwabe
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BIBLIOGRAPHY 467[64GEL/ZAI][64KAY/L
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BIBLIOGRAPHY 469[65MUL/ELL][65PAR][
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BIBLIOGRAPHY 471[66RAN][66RYK/YAK][
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BIBLIOGRAPHY 473[67SOL/TSV][68AHR/B
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BIBLIOGRAPHY 475[68TRE/GER][68ZAI/A
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BIBLIOGRAPHY 477[69SUL/ZIE][70AL-/W
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BIBLIOGRAPHY 479hexammine cobalt(II
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BIBLIOGRAPHY 481[72BLO/BUK][72BLO/B
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BIBLIOGRAPHY 483radioactif., CEN, F
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BIBLIOGRAPHY 485169, 169, 169, 170,
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BIBLIOGRAPHY 487[75ACK/RAU][75ALE/O
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BIBLIOGRAPHY 489other Actinides, he
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BIBLIOGRAPHY 491[76OET/RAN][76PAR][
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BIBLIOGRAPHY 493[77MUS/MAR] Musikas
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BIBLIOGRAPHY 495[78RAO/BAG][78RAO/B
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BIBLIOGRAPHY 497[79MUE/LAN][79PIT][
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BIBLIOGRAPHY 499and plutonium sesqu
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BIBLIOGRAPHY 501[81RAI/SWA][81ROL/G
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BIBLIOGRAPHY 503[82MOR/FUG][82NAI/C
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BIBLIOGRAPHY 505[83KIM/LIE][83MAR/H
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BIBLIOGRAPHY 507[84BUS/PLU][84CHO/R
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BIBLIOGRAPHY 509[84REE/DAN][84VAR/B
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BIBLIOGRAPHY 511The gaseous actinid
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BIBLIOGRAPHY 513[86BLA/FRE][86BRO/F
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BIBLIOGRAPHY 515and Radiation Chemi
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BIBLIOGRAPHY 517[87RAI/SWA][87RIC/S
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BIBLIOGRAPHY 519Can. J. Chem., 66 (
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BIBLIOGRAPHY 521[89RÖS/DIT][89SAW/
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BIBLIOGRAPHY 523[90KRI/HAG][90LEI][
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BIBLIOGRAPHY 525[91AND/CAS][91BYR/L
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BIBLIOGRAPHY 527[91WAN][91YAM/PRA][
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BIBLIOGRAPHY 529diochim. Acta, 58/5
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BIBLIOGRAPHY 531[93OKA/MAE][93OKA/R
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BIBLIOGRAPHY 533[94GIF/VIT][94GRI/C
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BIBLIOGRAPHY 535[94VEI/SMI][94YAM/S
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BIBLIOGRAPHY 537RC-1407 and COG-I-9
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BIBLIOGRAPHY 539lecular structure o
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BIBLIOGRAPHY 541in the Plutonium(IV
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List of cited authorsThis chapter c
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LIST OF CITED AUTHORS 545Table 23.1
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Part VAppendices569
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572 A. Discussion of selected refer
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y this review (from these experimen
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800 B. Ionic strength correctionsin
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802 B. Ionic strength correctionsEq
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810 B. Ionic strength correctionsNE
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812 B. Ionic strength correctionsIt
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814 B. Ionic strength correctionsTa
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The uncertainties represent the 95%
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824 C. Assigned uncertaintiesX ± 1
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826 C. Assigned uncertaintiesii. If
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828 C. Assigned uncertaintiestwo gr
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830 C. Assigned uncertaintiesNote t
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832 C. Assigned uncertaintiesI m el
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834 C. Assigned uncertaintiesBeving
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836 C. Assigned uncertaintiesIn the
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838 IndexIndex - generalabbreviatio
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840 IndexIndex - neptuniumactinide
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842 Indexlithium compoundsLi 2 NpO
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844 IndexPuOCl(cr), 360chlorine com
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