chemical thermodynamics of neptunium and plutonium - U.S. ...

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sp 0.1 M NaCl 23 (4.68±0.03) [96RUN/NEU]sol 0.1 M NaCl 23 (4.88±0.1) [96RUN/NEU] (h)sp 0.5 M NaClO 4 22 (4.3±0.1) (4.41±0.1) (c)(d) [90RIG]sol 0.5 M NaClO 4 75 (4.8±0.28) [93LEM/BOY] (c)(b)sol 1 M NaClO 4 25 (4.49±0.06) (4.57±0.35) (c)(d) [83MAY]sol 1 M NaClO 4 25 (4.6±0.1) (i)dis 1 M NaClO 4 25 (4.14±0.01) (4.14±0.5) (c) [85INO/TOC]sp 1 M NaClO 4 22 (4.3±0.2) [90RIG]sol 1 M NaClO 4 25 (4.50±0.04) (e) (4.48±0.36) (c) [91KIM/KLE]sol 1 M NaClO 4 30 (4.7±0.1) (4.77±0.51) (c)(b) [93LEM/BOY]sol 1 M NaClO 4 50 (5.6±0.2) (5.7±0.54) (c)(b)sol 1 M NaClO 4 75 (5.80±0.58) (5.2±0.54) (c)(b)sol 1 M NaCl 23 (4.32±0.07) [96RUN/NEU] (g)(h)sp 2 M NaClO 4 22 (4.6±0.3) [90RIG]sol 3 M NaClO 4 22 (5.09±0.57) (5.25±0.29) (c)(d) [86GRE/ROB] (j)(f) log 10 β 1 = (1.335 ± 0.084) + (829 ± 27)·T −1 (303 < T < 343 K)(Continued on next page)(g) Cited in [96RUN/NEU] from a report that was not available to the reviewer: Runde W. and Kim J. I. (1994) RCM-01094, Institut für Radiochemie, TU München.(h) Molal units(i) Recalculated in the [93LEM/BOY] publication.(j) The reference is noted [86GRE/ROB] for a series of Vitorge et al.’s publications that used the same experimental results [84VIT, 85CÔM, 85KIM, 90RIG, 98VIT/CAP].12.1 Neptunium carbon compounds and complexes 227
sol 3 M NaClO 25 (4.76±0.04) (e) (4.77±0.43) (c) [91KIM/KLE]sol43 M NaCl 23 (4.3±0.1) [96RUN/NEU] (h)sp 3 M NaCl 23 (4.67±0.07) [96RUN/NEU] (g)(h)sol 5 M NaClO 4 25 (5.00±0.05) (4.92±0.81) (c) [94NEC/KIM]sol 5 M NaCl 23 (4.71±0.04) [96RUN/NEU] (g)(h)sp 5 M NaCl 23 (4.72±0.13) [96RUN/NEU] (g)(h)sol 5 M NaCl 25 5.70 4.68 (k) [94NEC/KIM]NpO 2 CO − 3 + CO2− 3Å NpO 2 (CO 3 ) 3−2sp 0.008 M CO 2−3+? ? (2.5±0.5) [81BIL] (a)(b)dis 0.1 M HCO − 3? (2.3±1.0) [79MOS/POZ] (a)sol 0.1 M NaClO 4 25 (2.02±0.08) (e) (2.08±0.22) (c) [91KIM/KLE]sp 0.1 M NaClO 4 25 (2.02±0.3) [94NEC/RUN]sp 0.1 M TBANO 3 23 1.98 [96CLA/CON]sp 0.1 M TBANO 3 70 1.99 (l)sp 0.04 M Na 2 CO 3 22 (1.4±0.3) [90RIG] (c)sol 0.05 M Na 2 CO 3 (2.08±0.29) [75UEN/SAI] (a)(b)(k) Corrected by the author for Cl − complex formation(Continued on next page)12. Neptunium group 14 compounds and complexes(l) log 10 K 2 = 2.046 + 18·T −1 , (303 < T < 343 K)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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Page 212 and 213: Chapter 11Neptunium group 15compoun
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Page 222 and 223: 11.2 Neptunium phosphorus compounds
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Page 226 and 227: Chapter 12Neptunium group 14compoun
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Page 230 and 231: cal 0.3-1.6 M Na 2 SO 4 25 r H m =
Page 232 and 233: vlt 0 25 (0.340±0.002) (k) [95OFF/
Page 234 and 235: sol K + ,CO 2−3 , 20 −(2.31±0.
Page 254 and 255: dis 0.2 M NaClO 25 2.93 (3.42±1.0)
Page 256 and 257: sol 1 M NaCl 23 (2.06±0.13) [96RUN
Page 258 and 259: sol 0.15 M Na 2 CO 3 −(2.58±0.64
Page 260 and 261: sol 1 M NaClO 30 −(4.0±0.2) [93L
Page 262 and 263: sol 3 M NaClO 25 −(2.14±0.18)
Page 264 and 265: (f) Values selected in this review
Page 282 and 283: (V vs. SHE) (V vs. SHE) (V · K −
Page 284 and 285: (h) 1MK 2 CO 3 is written in Table
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12.1 Neptunium carbon compounds and
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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