chemical thermodynamics of neptunium and plutonium - U.S. ...

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LIST OF CITED AUTHORS 553Table 23.1: (continued)AuthorInoue, Y.Iorga, E. V.Itagaki, H.Iuliano, M.Ivanov, M. I.Ivantsov, A. I.Janecky, D. R.Jeffery, A. J.Jemine, X.Jenkins, H. D. B.Jensen,B.S.Jensen, K. A. (chairman)Jette, E. R.Johns, I. B.Johnson, C. E.Johnson, G. K.Johnson, J. W.Johnson, K. A.Johnson, K. S.Jones, B. F.Jones, M. M.Joshi, A. R.Joshi, J. K.Jouniaux, B.Jove, J.Kallay, N.Kanellakopulos, B.Kapshukov, I. I.Karle, I.Kasar, U. M.Kasha, M.Kato, Y.Katz,J.J.Kawamura, Y.Kay, A. E.Kazantsev, G. N.Keenan, T. K.Keller, C.von Keller, C.Kelley, K. K.Kent, R. A.References[85INO/TOC], [85INO/TOC2][75IOR/SHC][89TAN/NAG], [91ITA/TAN], [92ITA/NAK][87CIA/IUL][57POP/IVA][67SOL/TSV][96CLA/CON][85HAL/JEF], [86HAL/JEF], [90HAL/JEF][91GOU/JEM][82MOR/FUG][82JEN][71JEN][55JET][45JOH][61JOH/FIS][69JOH/DEV], [73JOH/SMI], [88TAS/O’H][92SHO/OEL][65MUL/ELL][79JOH/PYT][90NOR/PLU][53JON][84KAS/JOS][82NAI/CHA][79JOU/LEG][86THE/JOV][88MIL/CVI][89KIM/KAN], [89KIM/KAN2], [91KIM/KLE], [92NEC/KIM],[94NEC/KIM], [94NEC/RUN][73SUD/SOL], [74SIM/VOL], [74VIS/VOL], [74VOL/KAP],[74VOL/KAP2], [76VOL/VIS], [77VOL/VIS], [79VOL/TOM],[79VOL/VIS], [79VOL/VIS2], [81VOL/VIS], [81VOL/VIS2],[81VOL/VIS3], [81VOL/VIS4], [84VOL/KAP][49ABR/BRO][84KAS/JOS][49KAS][93LI/KAT], [96KAT/KIM][49ABR/BRO], [49HAG/ABR], [51KAT/RAB], [57KAT/SEA],[86WEI/KAT][95YAJ/KAW][64KAY/LOA][84LEB/KOB][54NIG/PEN], [64KEE/KRU], [65KEE][71KEL][69KEL/FAN][73HUL/DES][68KEN], [69KEN], [69KEN/LEA](Continued on next page)
554 LIST OF CITED AUTHORSTable 23.1: (continued)AuthorKetels, J.Khachkuruzov, G. A.Khalkin, V. A.Khalturin, G. V.Kharitonov, Y. Y.Khodakovskii, I. L.Khodakovsky, I. L.Khopkar, P. K.Kim, J. I.Kim, J. J.Kimura, M.Kimura, T.King, E. L.Kipatsi, H.Kirkham, D. H.Kleinschmidt, P. D.Klenze, R.Klimov, V. C.Kline, R. J.Knoch, W.Knott, H. W.Kober, V. I.Koehly, G.Kok-Scheele, A.Kolokoltsov, V. B.Komarov, E. V.Konings, R. J. M.Konobeevskii, S. T.Koppold, F.Kovaleva, T. V.Kovács, A.Kramer-Schnabel, U.Krasnova, O. G.Kraus, K. A.Kremers, H. E.References[65CHO/KET][82GLU/GUR][87RÖS/MIL], [89RÖS/DIT], [90RÖS/HUN][76SEV/KHA][73KHA/MOS][95PAR/KHO][72NIK/SER], [92FUG/KHO][74KHO/MAT][83KIM/LIE], [84KIM/BER], [84LIE/KIM], [85EIS/KIM], [85KIM],[85LIE/TRE], [86LIE/KIM], [88BÜP/KIM], [88KLE/KIM],[89KIM/KAN], [89KIM/KAN2], [91KIM/KLE], [91KIM/PAS],[92NEC/KIM], [92RUN/MEI], [93PAS/KIM], [93PAS/KIM2],[93PAS/RUN], [94KIM], [94NEC/KIM], [94NEC/RUN],[94RUN/KIM], [95FAN/NEC], [95NEC/FAN], [95NEC/RUN],[95PAS/KIM], [96FAN/NEC], [96MOR/KIM], [97NEC/FAN],[97PAS/CZE][74PIT/KIM][68KIM/SCH][96KAT/KIM][49KIN][80ALL/KIP][74HEL/KIR], [81HEL/KIR][86KLE/WAR], [86WAR/KLE], [92KLE/LAU], [92KLE/LAU2],[93WIL/KLE][88KLE/KIM], [91KIM/KLE][66GOR/KLI][60RAB/KLI][70LAH/KNO][79MUE/LAN][84LEB/KOB][83BOU/GUI][96KOV/BOO][76VOD/KOL][68KRY/KOM], [68KRY/KOM2], [69KRY/KOM], [69KRY/KOM2],[69KRY/KOM3], [69KRY/KOM4][90COR/KON], [90COR/KON2], [92GRE/FUG], [95HAA/MAR],[96KON/BOO], [96KOV/BOO], [98KON/HIL][58BOC/KON][84KIM/BER][76VOD/KOL][96KON/BOO], [96KOV/BOO][92BIS/KRA][96KON/BOO][45DAM/KRA], [46KRA/DAM], [46KRA/DAM2], [48KRA/NEL],[48KRA/NEL2], [49KRA/DAM], [49KRA/DAM2],[49KRA/DAM3], [50KRA/NEL], [56KRA][45MOE/KRE](Continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
Page 527 and 528: 502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
Page 529 and 530: 504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532: 506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
Page 533 and 534: 508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
Page 535 and 536: 510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538: 512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
Page 539 and 540: 514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
Page 541 and 542: 516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
Page 543 and 544: 518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
Page 547 and 548: 522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
Page 549 and 550: 524 BIBLIOGRAPHY254, 258, 258, 264,
Page 551 and 552: 526 BIBLIOGRAPHY[91MEI][91NIT][91OK
Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
Page 555 and 556: 530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
Page 557 and 558: 532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
Page 563 and 564: 538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
Page 567 and 568: 542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
Page 569 and 570: 544 LIST OF CITED AUTHORSTable 23.1
Page 577: 552 LIST OF CITED AUTHORSTable 23.1
Page 596 and 597: Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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