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Food Lipids: Chemistry, Nutrition, and Biotechnology

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1. The basic oleochemical business is a coproduct-balanced, commodity operation.<br />

Profitability is dependent on tight control of manufacturing processes<br />

<strong>and</strong> costs, <strong>and</strong> on maximizing the value of every product produced<br />

as a result of the splitting process.<br />

2. These industries are process driven. The plants have been designed around<br />

<strong>and</strong> optimized for profitability based on a relatively narrow range of feedstock<br />

composition. In the case of lauric fats, coconut, <strong>and</strong> palm kernel, the<br />

balance of the fatty acid streams produced dictates the profitability of the<br />

total operation. Major shifts in fatty acid distribution in the feedstock disrupt<br />

this balance <strong>and</strong> require changes in the way the end products are<br />

treated as saleable items. To clarify this point, note the difference in fatty<br />

acid composition of laurate canola versus palm kernel oil <strong>and</strong> coconut oil<br />

as shown in Table 3.<br />

As can be seen, laurate canola does not contain as much C12 as either coconut oil<br />

or palm kernel oil. In addition to decreased levels of this fatty acid, note also the<br />

total absence of the medium chain fatty acids, C8:0 <strong>and</strong> C10:0, typically present in<br />

the tropical fats. Specific markets for these medium chains have been developed, <strong>and</strong><br />

their sales contribution is important to the overall profitability of the splitting operation.<br />

The approach, then, to achieve utility within the existing framework of the<br />

massive oleochemical complex, would be to develop triglycerides having such massive<br />

doses of C12:0 that coproduct values would be obviated in st<strong>and</strong>ard feedstock<br />

sources. This would mean the development of triglycerides having C12:0 levels<br />

greater than 85%. Is such a goal possible utilizing this technology? The answers are<br />

not yet known, but the research still required is not trivial—as discussed above—<br />

<strong>and</strong> the impact of achieving such high levles of a specific fatty acid on the viability<br />

of the resulting plant is not known.<br />

What has been learned from this exercise?<br />

1. High expressions of specific fatty acids in plant triglycerides should be<br />

considered only in the context of alternative sources of such fatty acids,<br />

<strong>and</strong> the coproduct value of the rest of the components.<br />

2. Supply limitations as drivers for specific fatty acids can be a viable foundation<br />

for product development if current sources of feedstock triglycerides<br />

do not necessarily offer cost offsets because of the value of coproducts.<br />

Table 3 Fatty Acid Composition (%) of Laurate Canola versus Coconut,<br />

Palm Kernel, <strong>and</strong> Canola Oils<br />

Fatty acids Laurate canola Coconut oil Palm kernel oil Canola<br />

Lauric 38.0 49.0 47.0 0.0<br />

Myristic 4.0 17.5 16.0 0.1<br />

Oleic 31.0 5.0 16.5 61.5<br />

Linoleic 11.0 1.8 2.5 20.0<br />

Other 16.0 26.7 18.0 18.4<br />

Total 100.0 100.0 100.0 100.0<br />

Copyright 2002 by Marcel Dekker, Inc. All Rights Reserved.

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