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Food Lipids: Chemistry, Nutrition, and Biotechnology

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vascular health is a function not only of the fatty acid composition but of the positional<br />

distribution of the fatty acids along the glycerol backbone. An enhanced underst<strong>and</strong>ing<br />

of structure–function relationships of triacylglycerols <strong>and</strong> cardiovascular<br />

health would provide suitable targets for manipulating the pattern of triacylglycerol<br />

assembly in transgenic plants for the purpose of promoting health. A related example<br />

would entail producing medium chain triacylglycerols, which have value as dietary<br />

supplements for patients requiring medical <strong>and</strong> nutritional interventions (29). Other<br />

types of structured glyceride conferring nutritional benefit include Salatrim <strong>and</strong><br />

Caprenin, which are mixtures of short <strong>and</strong> long chain fatty acids <strong>and</strong> contribute fewer<br />

calories to the diet than do conventional food oils (249) (see Chapter 22). Presently,<br />

these reduced-calorie fats are prepared by postproduction, chemical processes.<br />

ACKNOWLEDGMENTS<br />

This contribution was supported by the College of Agricultural <strong>and</strong> Life Sciences of<br />

the University of Wisconsin–Madison. The author is grateful for the technical assistance<br />

of Ms. Dawn M. Hyatt with the manuscript <strong>and</strong> Mr. Eric A. Mischo with the<br />

figures.<br />

REFERENCES<br />

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10. J. L. Harwood. Lipid metabolism. In: The Lipid H<strong>and</strong>book, 2nd ed. (F. D. Gunstone,<br />

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633.<br />

11. C. O. Rock <strong>and</strong> J. E. Cronan. Escherichia coli as a model for the regulation of<br />

dissociable (type II) fatty acid biosynthesis. Biochim. Biophys. Acta 1302:1 (1996).<br />

12. R. Lehner <strong>and</strong> A. Kuksis. Biosynthesis of triacylglycerols. Prog. Lipid Res. 35:169<br />

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Copyright 2002 by Marcel Dekker, Inc. All Rights Reserved.

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