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Food Lipids: Chemistry, Nutrition, and Biotechnology

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flow rate, decreasing the size of the gap between the disks, <strong>and</strong> increasing the surface<br />

roughness of the disks. Colloid mills are more suitable than most other types of<br />

homogenizer for homogenizing intermediate or high viscosity fluids (e.g., peanut<br />

butter, fish or meat pastes), <strong>and</strong> they typically produce emulsions with droplet diameters<br />

between 1 <strong>and</strong> 5 �m.<br />

3. High Pressure Value Homogenizers<br />

Like colloid mills, high pressure valve homogenizers are more efficient at reducing<br />

the size of the droplets in a coarse emulsion premix than at directly homogenizing<br />

two separate phases [26]. The coarse emulsion premix is forced through a narrow<br />

orifice under high pressure, which causes the droplets to be broken down because<br />

of the intense disruptive stresses (e.g., impact forces, shear forces, cavitation, turbulence)<br />

generated inside the homogenizer [27]. Decreasing the size of the orifice<br />

increases the pressure the emulsion experiences, which causes a greater degree of<br />

droplet disruption <strong>and</strong> therefore the production of smaller droplets. Nevertheless, the<br />

throughput is reduced <strong>and</strong> more energy must be expended. A food manufacturer must<br />

therefore select the most appropriate homogenization conditions for each particular<br />

application, depending on the compromise between droplet size, throughput, <strong>and</strong><br />

energy expenditure. High pressure valve homogenizers can be used to homogenize<br />

a wide variety of food products, ranging from low viscosity liquids to viscoelastic<br />

pastes, <strong>and</strong> can produce emulsions with droplet sizes as small as 0.1 �m.<br />

4. Ultrasonic Homogenizers<br />

A fourth type of homogenizer utilizes high intensity ultrasonic waves that generate<br />

intense shear <strong>and</strong> pressure gradients. When applied to a sample containing oil <strong>and</strong><br />

water, these waves cause the two liquids to intermingle <strong>and</strong> the large droplets formed<br />

to be broken down to smaller ones. There are two types of ultrasonic homogenizer<br />

commonly used in the food industry: piezoelectric transducers <strong>and</strong> liquid jet generators<br />

[28]. Piezoelectric transducers are most commonly found in the small benchtop<br />

ultrasonic homogenizers used in many laboratories. They are ideal for preparing<br />

small volumes of emulsion (a few milliliters to a few hundred milliliters), a property<br />

that is often important in fundamental research when expensive components are used.<br />

The ultrasonic transducer consists of a piezoelectric crystal contained in some form<br />

of protective metal casing, which is tapered at the end. A high intensity electrical<br />

wave is applied to the transducer, which causes the piezoelectric crystal inside to<br />

oscillate <strong>and</strong> generate an ultrasonic wave. The ultrasonic wave is directed toward the<br />

tip of the transducer, where it radiates into the surrounding liquids, generating intense<br />

pressure <strong>and</strong> shear gradients (mainly due to cavitational affects) that cause the liquids<br />

to be broken up into smaller fragments <strong>and</strong> intermingled with one another. It is<br />

usually necessary to irradiate a sample with ultrasound for a few seconds to a few<br />

minutes to create a stable emulsion. Continuous application of ultrasound to a sample<br />

can cause appreciable heating, <strong>and</strong> so it is often advantageous to apply the ultrasound<br />

in a number of short bursts.<br />

Ultrasonic jet homogenizers are used mainly for industrial applications. A<br />

stream of fluid is made to impinge on a sharp-edged blade, which causes the blade<br />

to rapidly vibrate, thus generating an intense ultrasonic field that breaks up any<br />

droplets in its immediate vicinity though a combination of cavitation, shear, <strong>and</strong><br />

turbulence [28]. This device has three major advantages: it can be used for contin-<br />

Copyright 2002 by Marcel Dekker, Inc. All Rights Reserved.

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