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HEADING PAGE - port of ploce authority * welcome

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ENVIRONMENTAL IMPACT STUDY<br />

Rn: 03-033 CONTAINER TERMINAL PLOCE <strong>PAGE</strong>:56/4<br />

Dry weight content (S.T.) in analyzed samples varies from 58.6 to 73.7 %. In<br />

addition to the sample <strong>of</strong> sediment surface layer PLS01, it is a matter also <strong>of</strong><br />

material with high <strong>port</strong>ion <strong>of</strong> solid substance. Portion <strong>of</strong> combustible<br />

substances (rough estimate for content <strong>of</strong> solid substancess) is the highest in<br />

the sample PLS01 0-10 cm (24.1 %) and the lowest in the sample PLS02 30-<br />

40 cm (11.6 %).<br />

Differences at heavy metal concentrations in single samples are not big. The<br />

biggest difference has been determined at zinc and chromium concentrations.<br />

Zinc concentration varies from 72.7 to 157 mg/kg S.T.<br />

The sediment surface layer at the station PLS01 is considerably loaded with<br />

this metal in respect to other samples. This is probably the result <strong>of</strong> discharge<br />

<strong>of</strong> untreated sewage being as a rule loaded with zinc into the maritime zone<br />

between the pier 5 th and 7 th .<br />

Chromium concentration ranges from 14.1 to 34.7 mg/kg S.T. Vertical and<br />

horizontal distribution <strong>of</strong> this metal is something different then the zinc<br />

distribution. The lowest value has been obtained in the surface layer PLS02<br />

and the highest in the layer from 30 to 40 cm on the same station.<br />

Nickel concentrations range from 30.7 to 43.4 mg/kg S.T. The distribution <strong>of</strong><br />

this metal is very similar to the distribution <strong>of</strong> chromium. The surface layer on<br />

the station PLS01 contains a higher concentration then the layer being at 50 –<br />

60 cm depth. On the station PLS02 the situation is inverse.<br />

Mercury concentration ranges from 0.83 to 1.00 mg/kg S.T.<br />

The sediment surface layer on both stations is more loaded with total and<br />

mineral oils then the deeper sediment layers. The concentrations range from<br />

28.3 to 52.0 respectively from 5.7 to 9.7 mg/kg S.T.<br />

Polycyclic aromatic hydrocarbons are widespread sea environment<br />

contaminants. They originate mainly from combustion process or pouring out<br />

petroleum products. The sediment surface layer is as well when oils are in<br />

question more loaded on both stations being an expected phenomenon. The<br />

values obtained by this examination (20.6 do 34.9 µg/kg S.T.) are something<br />

lower then the values obtained by examination in the year 2003 (104 – 112<br />

µg/kg S.T.).<br />

Presence <strong>of</strong> polychlorinated biphenyls has not been identified in any sample<br />

as well as in the year 2003. Use <strong>of</strong> these organochlorine compounds as well<br />

as transformer and condenser oils and specially their use in open systems i.e.<br />

lubrication oils, colors etc. is forbidden therefore such finding has been<br />

obtained.<br />

Comparing the results <strong>of</strong> these examinations with results <strong>of</strong> examination<br />

performed in the year 2003 it could be said that concentration levels <strong>of</strong><br />

examined metals are practically the same at both examinations. It has to be<br />

noted that mercury examination has been not performed in the year 2003.<br />

Sediment Pollution Estimate<br />

Sediment Contamination Estimate Based on Comparison with Reference<br />

Values for the Adriatic Area<br />

Attention to problems related to quality evaluation <strong>of</strong> sediment developed<br />

through <strong>port</strong> maintenance and its disposal has been paid in Croatia only in<br />

recent time. Oceanographic institutes are in charge for examination <strong>of</strong> sea<br />

sediment contamination in Croatia (Adriatic East Coast) within the Adriatic<br />

Systematic Contamination Research Project (Project Jadran, Vir Konavle,<br />

RIJEKAPROJEKT d.o.o.

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