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HEADING PAGE - port of ploce authority * welcome

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ENVIRONMENTAL IMPACT STUDY<br />

Rn: 03-033 CONTAINER TERMINAL PLOCE <strong>PAGE</strong>:56/9<br />

By comparing the set maximum values <strong>of</strong> single contaminants in sediment<br />

provided for dredging in the Port <strong>of</strong> Ploce under EU criteria, being still under<br />

consideration, the implication is as follows:<br />

- Only cadmium concentration meet the class 1<br />

- Total oil, cooper, zinc, lead, chromium and nickel concentrations meet<br />

the limit values for the class 2<br />

- Mercury concentration exceeds the limit value for the class 2 by more<br />

then 50%<br />

The same proposal defines the limit values for PCB and PAH just for the class<br />

3: for PCB this is 0.03 mg/kg dry weight and for PAH 1.0 mg/kg dry weight.<br />

We have already mentioned that there is no evidence <strong>of</strong> PCB presence in<br />

examined sediments (detection limit 0.25 µg/kg). For this parameter the PAH<br />

concentration are lower then the limit values by two orders <strong>of</strong> magnitude.<br />

Maximum metal concentration set in sediment <strong>of</strong> the Port <strong>of</strong> Ploce and limit<br />

values <strong>of</strong> single contaminant and sediment class according to the Norwegian<br />

standard and criterion being under EU consideration are given parallel in<br />

order to have an easy reference to the shown on the Fig. 2.<br />

It can be concluded that sediment in the Port <strong>of</strong> Ploce can be classified<br />

in the class 2, i.e. poorly contaminated sediments. In addition, the<br />

comparison <strong>of</strong> concentration examined hazardous substances with<br />

reference concentrations for the Adriatic area indicates to poorly<br />

contaminated sediment.<br />

Sediments <strong>of</strong> such characteristics may be deposit in the sea on specifically<br />

determined territorial sea area outside <strong>of</strong> the coastal zone, i.e. on depth<br />

deeper then 30 m.<br />

Estimate <strong>of</strong> Contaminant from Sediment<br />

It is planned to use dredged material to embank quays. In respect to dredging<br />

technology with which sediment when extracting shall be mixed with specific<br />

water amount (app. 40 % sediment and app. 60 % water) water shall be<br />

leached from material deposited in land. For this reason, the leaching test for<br />

contaminants from sediment has been carried out. The surface sediment layer<br />

PLS01, proved as the most contaminated has been selected for testing. The<br />

leaching test has been carried out according to the standard EN 12457 for<br />

granulated waste and sludge. Tested material has been mixed with water in<br />

pro<strong>port</strong>ion 1: 10. Following parameters has been determined in water <strong>port</strong>ion<br />

<strong>of</strong> the sediment containing desorbed, dispersed and dissolved substances<br />

from the sample <strong>of</strong> tested material: pH, electrical conductivity, phenols, and<br />

metals: Cu, Pb, Zn, Ni, Cd, Cr and Hg.<br />

The table 6 shows the testing results. In addition, the same Table shows limit<br />

values for waste eluates that may, according to the Regulations on Waste<br />

Treatment Conditions (Official Gazette No. 123/1997 and 112/2001), be<br />

deposited in landfills and limit values for hazardous substances that may,<br />

according to Regulations on Limit Values <strong>of</strong> Indicators <strong>of</strong> Hazardous and<br />

Other Substances in Waste Water (Official Gazette 40/1999 and 6/2001), be<br />

discharged into the sea.<br />

RIJEKAPROJEKT d.o.o.

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