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Natural Science in Archaeology

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8.5 Glazes 191<br />

from throughout the island group <strong>in</strong>dicate that pottery mak<strong>in</strong>g us<strong>in</strong>g local raw materials<br />

was once a widespread <strong>in</strong>dustry (Dye and Dick<strong>in</strong>son 1996).<br />

One of the most thorough and <strong>in</strong>clusive case studies of the provenance of ceramic<br />

raw materials focused on the Bronze Age of the island of Cyprus. This study orig<strong>in</strong>ated<br />

<strong>in</strong> efforts to reconstruct prehistoric production and exchange systems. The<br />

result<strong>in</strong>g monograph assesses the various analytical techniques used <strong>in</strong> sourc<strong>in</strong>g<br />

Cypriot pottery and clays (Knapp and Cherry 1994). In this assessment the authors<br />

po<strong>in</strong>t out that sourc<strong>in</strong>g pottery raw materials has proven exceed<strong>in</strong>gly difficult.<br />

An <strong>in</strong>terest<strong>in</strong>g example of temper comes from a Late Archaic to Early Woodland<br />

(4500–3000 BP) culture <strong>in</strong> the state of South Carol<strong>in</strong>a. In addition to pottery<br />

that was sand-tempered, some pottery was fiber-tempered, visible as a secondary<br />

porosity. This fiber material was identified as Spanish moss (Tillandsia usneoides)<br />

(Smith and Tr<strong>in</strong>kley 2006). Petrographic methods can readily identify tempers and<br />

frequently can determ<strong>in</strong>e their geographic/geologic source or sources. In the state<br />

of North Dakota, the grit temper of granodioritic composition was available from<br />

local glacial tills (Josephs 2005).<br />

Although geographically limited <strong>in</strong> scope, the most wide-rang<strong>in</strong>g and thorough<br />

look at the archaeom<strong>in</strong>eralogy of tempers is provided by Dick<strong>in</strong>son (2006) who<br />

exam<strong>in</strong>ed 2223 prehistoric sherds <strong>in</strong> th<strong>in</strong> section from sites across the southwest<br />

Pacific Ocean. These tempers <strong>in</strong>cluded calcareous as well as terrigenous sands.<br />

Only the latter can be assigned a source from a specific island or island group.<br />

Petrographically the temper sands fell <strong>in</strong>to three groups: (1) light m<strong>in</strong>eral gra<strong>in</strong>s<br />

<strong>in</strong>clud<strong>in</strong>g quartz and feldspar; (2) heavy iron-magnesium m<strong>in</strong>erals and opaque<br />

iron oxides; and (3) polycrystall<strong>in</strong>e lithic fragments. In 106 cases temper had been<br />

imported; two-thirds of these <strong>in</strong>volved distances of less than 200 km, and most of<br />

the others <strong>in</strong>volved distances of 200–600 km. A few cases were recorded where<br />

temper analysis <strong>in</strong>dicated imports from 1000 km or more. This volume <strong>in</strong>cludes 30<br />

<strong>in</strong>structive th<strong>in</strong>-section photomicrographs <strong>in</strong> color.<br />

8.5 Glazes<br />

Glazes are vitreous (glassy) coat<strong>in</strong>gs melted on the surfaces of pottery to make them<br />

watertight. They may also be used to impart color and decoration to the pottery<br />

surface. All glazes by def<strong>in</strong>ition conta<strong>in</strong> silica, and most have compositional ranges<br />

similar to other types of glass (see Sect. 8.7 on glass). Early glazes were derived<br />

from silica sands and glass frits (such as those found on glazed faience beads dat<strong>in</strong>g<br />

from the fourth millennium BCE <strong>in</strong> Egypt). From Egypt, Anatolia, and the Persian<br />

Gulf colored glazes were produced from the fifth millennium. These glazes all seem<br />

to have conta<strong>in</strong>ed some antimony.<br />

Glazes must conta<strong>in</strong> a flux agent <strong>in</strong> order to lower the melt<strong>in</strong>g temperature of the<br />

silica. Without a flux agent, the melt<strong>in</strong>g temperature of the glaze would also melt<br />

and deform the ceramic body to which the glaze is applied. The range of effective<br />

fir<strong>in</strong>g temperatures is different for each type of flux agent. There are both “high”

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