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IGCAR : Annual Report - Indira Gandhi Centre for Atomic Research

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IGC<br />

<strong>Annual</strong> <strong>Report</strong> 2007<br />

Thermal expansion (%)<br />

2.5<br />

2.0<br />

1.5<br />

1.0<br />

0.5<br />

0.0<br />

UO 2<br />

10 mol % GdO 1.5<br />

20 mol % GdO 1.5<br />

50 mol % GdO 1.5<br />

Gd 2<br />

O 3<br />

400 800 1200 1600 2000<br />

Temperature (K)<br />

Fig.2 Thermal expansion (%) as a<br />

function of temperature<br />

<strong>for</strong> UO 2 -GdO 1.5 solid solutions<br />

on these solid solutions 298-<br />

1973 K using high temperature<br />

X-ray diffraction. The thermal<br />

expansion of these solid<br />

solutions are shown in Fig.2.<br />

U-Zr metal alloys will be used<br />

as the blanket material in fast<br />

breeder reactors. Hence heat<br />

capacity data of U-Zr alloys is<br />

important. Heat capacity data<br />

of U-Zr alloys are available<br />

only <strong>for</strong> alloys with >13 at.% Zr<br />

. Heat capacity measurements<br />

were carried out on U-Zr alloy<br />

with 2, 5 and 10 wt.% Zr using<br />

heat flux differential calorimeter<br />

in the temperature range 298-<br />

800 K to generate the first<br />

experimental data which are<br />

shown in Fig.3. The measured<br />

heat capacity of pure U along<br />

C p, m<br />

(J K -1 mol -1 )<br />

45<br />

40<br />

35<br />

30<br />

25<br />

C p, m<br />

U<br />

C p, m<br />

U Hulgren et al.<br />

C p, m<br />

U Nakumura et al.<br />

C p, m<br />

U-2 wt.% Zr<br />

C p, m<br />

U-5 wt.% Zr<br />

C p, m<br />

U-10 wt.% Zr<br />

300 400 500 600 700 800 900<br />

Temperature (K)<br />

Fig.3 Heat capacity of U and U-Zr<br />

alloys<br />

with other literature values is<br />

also shown in Fig. 3 along with<br />

the literature values.<br />

IV.A.5. An Automated Facility <strong>for</strong> Charging of Fuel<br />

Micro Spheres into the Sintering Furnace<br />

Fuel preparation in the <strong>for</strong>m<br />

of micro spheres generated by<br />

the SOLGEL process is an<br />

attractive alternative to the<br />

powder route of preparation.<br />

An automated fabrication<br />

facility on the SOLGEL route<br />

has been set up in the<br />

Radiochemistry Laboratory.<br />

The fuel materials in the <strong>for</strong>m<br />

of micro spheres produced by<br />

the gelation process are first<br />

dried and are then to be<br />

loaded in a charge carrier and<br />

placed remotely into a high<br />

temperature furnace <strong>for</strong><br />

sintering.This operation is to be<br />

mechanized and per<strong>for</strong>med<br />

remotely. Towards this,an<br />

automated gripping device<br />

positionable along three coordinates,<br />

<strong>for</strong> positioning and<br />

subsequent lowering of the<br />

charge carrier into the furnace,<br />

has been developed. The<br />

device consists of an<br />

electrically actuated x-y<br />

plat<strong>for</strong>m which is mounted<br />

above the furnace as shown<br />

Fig.1. The plat<strong>for</strong>m which can<br />

be positioned in the horizontal<br />

plane, is holding an electrically<br />

operated telescopic arm fitted<br />

with a pneumatically actuated<br />

two jaw gripper.The Z axis<br />

position indicator mounted on<br />

the plat<strong>for</strong>m indicates the depth<br />

to which the gripper has been<br />

lowered. A reed sensor fixed<br />

on the end effectors is used <strong>for</strong><br />

sensing the gripping<br />

operation.The system has been<br />

commissioned with an overall<br />

positioning accuracy of 0.5<br />

mm.With no direct vision,the<br />

lowering of the charge into the<br />

furnace is assisted by a PAN-<br />

TILT camera ,as shown in the<br />

inset in Fig.1.<br />

Fig.1 Automated gripping devices<br />

<strong>for</strong> the introduction of charge<br />

carrier into the sintering furnace<br />

FUEL CYCLE 87

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