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RD&D-Programme 2004 - SKB

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and the rock matrix, is also crucial for radionuclide transport. Matrix diffusion and sorption are<br />

the two most important retention processes for radionuclides in the geosphere. Another factor<br />

that can be of importance for retention is sorption on colloidal particles and transport with them.<br />

The chemical environment in the water determines which speciation (chemical form) the radionuclides<br />

will have, which is crucial particularly for the sorption phenomena. Certain nuclides<br />

can be transported in the gas phase. Radioactive decay influences the groundwater’s content of<br />

radionuclides and must therefore be included in the description of transport phenomena.<br />

The research programme for the different processes in the geosphere is discussed in the<br />

following sections.<br />

19.2.2 Heat transport<br />

Conclusions in RD&D 2001 and its review<br />

In RD&D 2001, the viewpoint is expressed that heat is transported in the geosphere by conduction<br />

in the intact rock, and that existing models and calculation methods are sufficiently verified<br />

to enable the design criterion to be met.<br />

In the opinion of the authorities, the maximum temperature nearest the canister is underestimated<br />

in large-scale models with widespread heat loads, and the influence of simplified<br />

calculation assumptions should be examined more closely. The THMC modellings that are<br />

done in the future should be updated with the latest temperature calculations.<br />

Newfound knowledge since RD&D 2001<br />

The problem of the temperature evolution in the rock has been thoroughly addressed since<br />

RD&D 2001, above all with a view to the maximum temperature nearest the canisters /19-1/.<br />

The studies reveal relationships between the maximum temperature of the canister, the heat<br />

transport properties of the rock, the heat output of the canisters at deposition, the deposition<br />

geometry and the conditions in the buffer. The geometry of the individual canister is taken<br />

into account so that the temperature evolution in the near-field, above all at the hottest part at<br />

canister mid-height, is correctly calculated. Figure 19-1 shows an example. In the calculations,<br />

which are performed with different combinations of analytical and numerical methods, the heat<br />

transport problem is dealt with on all scales. The study also shows how sensitive the calculated<br />

maximum temperature on the canister surface is to errors in input data, such as errors in the<br />

thermal conductivity and heat capacity of the rock. The impacts of the simplified assumptions<br />

that are generally made, for example the approximation to disregard the temperature dependence<br />

of the thermal conductivity and the influence of the different heat transport properties of<br />

the tunnel backfill, are analyzed and quantified.<br />

Different laboratory-based methods for prediction of the thermal conductivity of the rock<br />

nearest a borehole have been compared with a large-scale method for direct measurement in<br />

boreholes, the thermal response test /19-2/. The thermal response test overestimates the thermal<br />

conductivity by about 25 percent compared with the results obtained using laboratory methods<br />

to determine the properties of the individual mapped rock types and calculate the effective<br />

thermal conductivity based on the mapped rock type distribution. The interpretation is that<br />

the full-scale method needs to be developed to compensate for the effects of water movements<br />

in the borehole during measurement.<br />

A systematic evaluation has been carried out of several methods for determination of thermal<br />

conductivity and heat capacity in the laboratory /19-3/. The methods yield on average differences<br />

on the order of a percent or so for a number of measured samples, while the variation<br />

between individual samples can be considerably greater.<br />

244 RD&D-<strong>Programme</strong> <strong>2004</strong>

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