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6.5 Some Major Global Biogeochemical Cycles 117<br />

6.5 Some Major Global<br />

Biogeochemical Cycles<br />

With Figure 6.14’s b<strong>as</strong>ic diagram in mind, we can now consider<br />

complete chemical cycles, though still quite simplified.<br />

Each chemical element h<strong>as</strong> its own specific cycle, but all the<br />

cycles have certain features in common (Figure 6.15).<br />

The Carbon Cycle<br />

Carbon is the b<strong>as</strong>ic building block of life and the element<br />

that anchors all organic substances, from coal and<br />

oil to DNA (deoxyribonucleic acid), the compound that<br />

carries genetic information. Although of central importance<br />

to life, carbon is not one of the most abundant elements<br />

in <strong>Earth</strong>’s crust. It contributes only 0.032% of the<br />

weight of the crust, ranking far behind oxygen (45.2%),<br />

silicon (29.5%), aluminum (8.0%), iron (5.8%), calcium<br />

10, 11<br />

(5.1%), and magnesium (2.8%).<br />

The major pathways and storage reservoirs of the carbon<br />

cycle are shown in Figure 6.16. This diagram is simplified<br />

to show the big picture of the carbon cycle. Details<br />

Oceans and land ecosystems: In the p<strong>as</strong>t half-century,<br />

ocean and land ecosystems have removed about 3.1 0.5<br />

GtC/yr, which is approximately 45% of the carbon emitted<br />

from burning fossil fuels during that period.<br />

Land-use change: Deforestation and decomposition of<br />

what is cut and left, <strong>as</strong> well <strong>as</strong> burning of forests to make<br />

room for agriculture in the tropics, are the main re<strong>as</strong>ons<br />

2.2 0.8 GtC/yr is added to the atmosphere. A small<br />

flux of carbon (0.2 0.5 GtC/yr) from hot tropical<br />

are<strong>as</strong> is pulled from the atmosphere by growing forests.<br />

In other words, when considering land-use change, deforestation<br />

is by far the dominant process.<br />

Residual land sink: The observed net uptake of<br />

CO 2 from the atmosphere (see Figure 6.16) by land<br />

ecosystems suggests there must be a sink for carbon in<br />

land ecosystems that h<strong>as</strong> not been adequately identified.<br />

The sink is large, at 2 to 3 GtC/yr, with large uncertainty<br />

( 1.7GtC/yr). Thus, our understanding of the<br />

carbon cycle is not yet complete.<br />

Carbon h<strong>as</strong> a g<strong>as</strong>eous ph<strong>as</strong>e <strong>as</strong> part of its cycle, occurring<br />

in the atmosphere <strong>as</strong> carbon dioxide (CO 2 ) and<br />

methane (CH 4 ), both greenhouse g<strong>as</strong>es. Carbon enters<br />

are much more complex. 12 Soil and rock minerals (slow turnover) Water<br />

Atmosphere<br />

Dust and<br />

inorganic g<strong>as</strong>es<br />

Biological uptake<br />

Biological rele<strong>as</strong>e<br />

Rain<br />

and<br />

dust<br />

Organic material<br />

From the<br />

biosphere<br />

Mineralization<br />

Biological uptake<br />

To the<br />

biosphere<br />

Soil (available)<br />

Mineral formation<br />

Weathering<br />

flow<br />

FIGURE 6.15 B<strong>as</strong>ic biogeochemical cycle.

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