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Botkin Environmental Science Earth as Living Planet 8th txtbk

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482 CHAPTER 21 Air Pollution<br />

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Me<strong>as</strong>uring Stratospheric Ozone<br />

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O 3 is produced by<br />

photodissociation of O 2<br />

by UVC from the sun.<br />

O then combines with O 2<br />

to produce O 3 .<br />

O 3 is destroyed by<br />

catalytic chain reaction<br />

of ClO. Similar reactions<br />

occur with NO x and BrO x .<br />

Net result<br />

FIGURE 21.15 Processes of<br />

natural formation of ozone and<br />

destruction by CFCs, N 2 O, and<br />

methyl bromide. (Source: Modified<br />

from NASA-GSFC, “Stratospheric<br />

Ozone,” accessed August 22, 2000,<br />

at http://see.gsfc.n<strong>as</strong>a.gov.)<br />

Sun<br />

O 2<br />

O + O 2<br />

O 3<br />

Cl + O 3<br />

ClO + O<br />

ClO + O 2<br />

Cl + O 2<br />

O + O 3<br />

2O 2<br />

O<br />

Ozone is<br />

destroyed<br />

NO x<br />

ClO x<br />

BrO x<br />

Stratosphere<br />

Troposphere<br />

N 2 O<br />

CFCs<br />

Emissions<br />

from <strong>Earth</strong><br />

Methyl<br />

bromide<br />

Catalytic agents are<br />

produced from long-lived<br />

source g<strong>as</strong>es, rele<strong>as</strong>ed<br />

into the troposphere,<br />

and transported to the<br />

stratosphere

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