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View - ResearchSpace@Auckland - The University of Auckland

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More recently 'Air Quality Indexes' were developed to better inform the public about air<br />

quality or the degree <strong>of</strong> pollution on any given day. <strong>The</strong>se are composite measures <strong>of</strong><br />

common air pollutants for which there are demonstrable adverse effects on health and the<br />

environment. At the current time these include CO, NOz, SO2, ground level ozone, suspended<br />

particulate matter (sometimes expressed as a coefficient <strong>of</strong> haze) and total reduced sulphur<br />

compounds. <strong>The</strong> Index is reported on a scale <strong>of</strong> 0 to 100 (or more) with scales <strong>of</strong> 'very good"<br />

air quality being 0-15 and 'very poor' near the 100 mark (Hilternann, Stolk et al. 1998;<br />

Abelsohn, Stieb et al.2002).<br />

2.2.3 Nitrogen oxides in pollution<br />

NO is a potentially toxic molecule; and both NO and its interrelated forms were discovered as<br />

components in pollution. Space shuttle and jet plane exhaust, lightening and smog are all<br />

known to have a high proportion <strong>of</strong> NO (Nathan 1992). Nitrogen oxides were detected in the<br />

evaluation <strong>of</strong> air pollution from the Titan tr firings @iamond and Johnson 1965). NO forms<br />

part <strong>of</strong> the origin <strong>of</strong> the shuttle glow which was observed in 1983, and was carefully examined<br />

because <strong>of</strong> concern that it would interfere with space-based spectroscopy. It was found to be<br />

the reaction between NO and 02 forming an excited form <strong>of</strong> NO2 which released light as it<br />

desorbed (Viereck, Murad et al. 1991). Increases in air traffic have resulted in increases in<br />

nitrogen oxides in the troposphere, again causing concern about the effects in atmospheric<br />

chemistry (Johnson, Henshaw et al. 1992). <strong>The</strong>re exists an array <strong>of</strong> compounds that includes<br />

NO, nitrosoium cation (NO +), nitroxyl anion (NO-), peroxynitrite (ONOO-) and hydroxyl<br />

anion (OH-). Most <strong>of</strong> these are inherently unstable compounds and interact with other<br />

elements particularly ozone and oxygen, so the main compound measurable in pollution from<br />

this class <strong>of</strong> gases is the stable gas NO2. <strong>The</strong> ambient NOz levels in London vary between25-<br />

58ppb (24 hour average), European air levels are 78ppb (24 hour average) and the level in the<br />

USA is 53ppb (one year average) (Nicolai 1999).<br />

Many epidemiological studies <strong>of</strong> outdoor pollution have found associations between NO2<br />

exposure and disease, even at levels below the current WHO guidelines. <strong>The</strong> 'Air Pollution on<br />

Health: European Approach' studies incorporated data from 15 cities with a total population<br />

<strong>of</strong> greater than 25 million. A rise in NOz over the one hour safety maximum <strong>of</strong> 50 pglm3 was<br />

associated with a 2.6Vo increase in asthma admissions and a l.3%o increase in daily all cause<br />

mortality (Touloumi, Katsouyanni et al. 1997). In Toronto, from the total number <strong>of</strong><br />

premature deaths related to air pollution, NOz was assessed to be responsible for almost 407o,<br />

and, <strong>of</strong> the hospital admissions, 60Vo was also thought to be attributable to NOz levels, with<br />

56

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