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Applied numerical modeling of saturated / unsaturated flow and ...

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Fig. 9: Influence <strong>of</strong> dispersivity parameterization on estimated degradation rate constants for<br />

2<br />

method 4 (<strong>and</strong> method 3 with �T = 0) <strong>of</strong> Tab. 1 <strong>and</strong> four degrees <strong>of</strong> aquifer heterogeneity � Y<br />

(Bauer et al., 2006a [EP 2]). Symbols represent ensemble medians <strong>of</strong> 100 realizations.<br />

Extensive monitoring networks<br />

For the previous studies, linearly arranged<br />

center line observation wells have been<br />

used for the VA investigation (compare Fig.<br />

6). Contaminant plumes in natural heterogeneous<br />

aquifers may however show a<br />

substantial amount <strong>of</strong> me<strong>and</strong>ering (Wilson<br />

et al., 2004) resulting in non-linear center<br />

line orientations. As documented, an<br />

inappropriate assumption <strong>of</strong> a linear center<br />

line may result in misplacement <strong>of</strong> the<br />

observation wells <strong>and</strong> in significant overestimation,<br />

if degradation rate constants are to<br />

be derived. Moreover, only measurements<br />

in observation wells located on the plume<br />

axis are evaluated <strong>and</strong> additional information<br />

possibly at h<strong>and</strong> (i.e. well data downgradient<br />

from the source but not on the<br />

center line) is not explicitly accounted for<br />

in the rate estimation. Therefore the performance<br />

<strong>of</strong> methods 1, 3 <strong>and</strong> 4 <strong>of</strong> Tab. 1 was<br />

Fig. 10: Site investigation for degradation<br />

rate constant evaluation by (A) non-linearly<br />

positioned center line wells <strong>and</strong> (B) using<br />

all observation wells <strong>of</strong> the monitoring<br />

network (Beyer et al., 2007a [EP 5]). Small<br />

dark squares show observation well<br />

locations, larger squares show presumed<br />

center line well locations, contour lines are<br />

concentrations calculated analytically with<br />

the approach <strong>of</strong> Stenback et al. (2004).<br />

15

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