Applied numerical modeling of saturated / unsaturated flow and ...
Applied numerical modeling of saturated / unsaturated flow and ...
Applied numerical modeling of saturated / unsaturated flow and ...
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C/C 0 [-]<br />
C/C 0 [-]<br />
1<br />
0.9<br />
0.8<br />
0.7<br />
0.6<br />
0.5<br />
0.4<br />
0.3<br />
0.2<br />
0.1<br />
0<br />
1<br />
0.1<br />
0.01<br />
0.001<br />
cambisol (dil.)<br />
podzol (dil.)<br />
chernozem (dil.)<br />
cambisol<br />
podzol<br />
chernozem<br />
0 50 100 150 200 250<br />
time [a]<br />
a) naphthalene b) phenanthrene<br />
c) naphthalene<br />
with degradation<br />
d) phenanthrene<br />
with degradation<br />
0 50 100 150 200 250<br />
time [a]<br />
Fig. 17: Concentration breakthrough curves at the groundwater surface below the road dam<br />
for three different subsoil types showing naphthalene without (a) <strong>and</strong> with degradation (c),<br />
<strong>and</strong> phenanthrene without (b) <strong>and</strong> with degradation (d) (Beyer et al., 2007b [EP 6]).<br />
The results allow important conclusions on<br />
mechanisms (e.g. capillary barrier effects)<br />
<strong>and</strong> complementary design criteria for road<br />
constructions, which can be used to reduce<br />
contaminant leaching to groundwater.<br />
4. Conclusions <strong>and</strong> outlook<br />
In this thesis, the utilization <strong>of</strong> process<br />
based <strong>numerical</strong> models <strong>of</strong> <strong>saturated</strong> / un<strong>saturated</strong><br />
<strong>flow</strong> <strong>and</strong> reactive contaminant transport<br />
is demonstrated for two different fields<br />
<strong>of</strong> application.<br />
The Virtual Aquifer (VA) concept is<br />
introduced, which uses <strong>numerical</strong> <strong>modeling</strong><br />
as a tool for the computer based evaluation<br />
<strong>of</strong> investigation <strong>and</strong> remediation strategies<br />
for contaminated soils <strong>and</strong> aquifers. In the<br />
application examples presented, the VA<br />
concept proves its usefulness for assessing<br />
the uncertainty involved in the investigation<br />
<strong>of</strong> heterogeneous sites <strong>and</strong> the parameterization<br />
<strong>of</strong> degradation process models.<br />
Moreover, the VA concept is successfully<br />
applied to test a newly developed approach<br />
for the inference <strong>of</strong> biodegradation parameters<br />
from data typically collected during site<br />
investigation. Both applications exemplify<br />
the importance but also the pitfalls <strong>of</strong> a<br />
careful <strong>and</strong> accurate collection <strong>of</strong> investigation<br />
data, if these are to be used for<br />
prognosis <strong>of</strong> the contaminant behaviour at a<br />
site. The main advantage <strong>of</strong> the VA is, that<br />
individual factors, such as hydraulic heterogeneity<br />
or conceptual model errors can be<br />
studied in detail at low costs <strong>and</strong> without<br />
high effort, either individually or in combination<br />
<strong>and</strong> under otherwise ideal <strong>and</strong><br />
controlled conditions. As the sum <strong>of</strong> these<br />
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