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Applied numerical modeling of saturated / unsaturated flow and ...

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C/C 0 [-]<br />

C/C 0 [-]<br />

1<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0<br />

1<br />

0.1<br />

0.01<br />

0.001<br />

cambisol (dil.)<br />

podzol (dil.)<br />

chernozem (dil.)<br />

cambisol<br />

podzol<br />

chernozem<br />

0 50 100 150 200 250<br />

time [a]<br />

a) naphthalene b) phenanthrene<br />

c) naphthalene<br />

with degradation<br />

d) phenanthrene<br />

with degradation<br />

0 50 100 150 200 250<br />

time [a]<br />

Fig. 17: Concentration breakthrough curves at the groundwater surface below the road dam<br />

for three different subsoil types showing naphthalene without (a) <strong>and</strong> with degradation (c),<br />

<strong>and</strong> phenanthrene without (b) <strong>and</strong> with degradation (d) (Beyer et al., 2007b [EP 6]).<br />

The results allow important conclusions on<br />

mechanisms (e.g. capillary barrier effects)<br />

<strong>and</strong> complementary design criteria for road<br />

constructions, which can be used to reduce<br />

contaminant leaching to groundwater.<br />

4. Conclusions <strong>and</strong> outlook<br />

In this thesis, the utilization <strong>of</strong> process<br />

based <strong>numerical</strong> models <strong>of</strong> <strong>saturated</strong> / un<strong>saturated</strong><br />

<strong>flow</strong> <strong>and</strong> reactive contaminant transport<br />

is demonstrated for two different fields<br />

<strong>of</strong> application.<br />

The Virtual Aquifer (VA) concept is<br />

introduced, which uses <strong>numerical</strong> <strong>modeling</strong><br />

as a tool for the computer based evaluation<br />

<strong>of</strong> investigation <strong>and</strong> remediation strategies<br />

for contaminated soils <strong>and</strong> aquifers. In the<br />

application examples presented, the VA<br />

concept proves its usefulness for assessing<br />

the uncertainty involved in the investigation<br />

<strong>of</strong> heterogeneous sites <strong>and</strong> the parameterization<br />

<strong>of</strong> degradation process models.<br />

Moreover, the VA concept is successfully<br />

applied to test a newly developed approach<br />

for the inference <strong>of</strong> biodegradation parameters<br />

from data typically collected during site<br />

investigation. Both applications exemplify<br />

the importance but also the pitfalls <strong>of</strong> a<br />

careful <strong>and</strong> accurate collection <strong>of</strong> investigation<br />

data, if these are to be used for<br />

prognosis <strong>of</strong> the contaminant behaviour at a<br />

site. The main advantage <strong>of</strong> the VA is, that<br />

individual factors, such as hydraulic heterogeneity<br />

or conceptual model errors can be<br />

studied in detail at low costs <strong>and</strong> without<br />

high effort, either individually or in combination<br />

<strong>and</strong> under otherwise ideal <strong>and</strong><br />

controlled conditions. As the sum <strong>of</strong> these<br />

21

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