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Applied numerical modeling of saturated / unsaturated flow and ...

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1.3m<br />

0.3m<br />

as a representative for highly soluble salts,<br />

naphthalene for moderately sorbing <strong>and</strong><br />

phenanthrene for strongly sorbing organic<br />

compounds. Contaminant leaching from the<br />

DW to the groundwater surface is studied<br />

with six different characteristic subsoil<br />

units <strong>of</strong> Germany (BGR, 2006) to be able to<br />

compare the influence <strong>of</strong> hydraulic <strong>and</strong><br />

basic physico-chemical soil properties on<br />

contaminant attenuation. Fig. 14 presents<br />

the conceptual model for the road dam.<br />

Here coarse grained DW is used as unbound<br />

base / subbase layers below the<br />

asphalt surface <strong>of</strong> the road. According to<br />

German road construction regulations, the<br />

base / subbase layers are covered by low<br />

<strong>and</strong> high permeable soil layers along the<br />

embankment (Fig. 14).<br />

RCB<br />

Körnung 0/32<br />

b horizon<br />

c horizon<br />

symmetry axis<br />

10m 1.5m<br />

asphalt layer<br />

impermeable low permeable soil<br />

3%<br />

4%<br />

12%<br />

1:1. 5<br />

2.3m<br />

10 cm high<br />

permeable soil<br />

2m<br />

groundwater surface<br />

(point <strong>of</strong> compliance)<br />

Fig. 14: Road construction with demolition<br />

waste recycled in base / subbase layers<br />

(Beyer et al., 2007b [EP 6]).<br />

The simulation strategy for this study<br />

combines the Eulerian <strong>and</strong> Lagrangian<br />

frameworks <strong>of</strong> transport <strong>modeling</strong>. Un<strong>saturated</strong><br />

<strong>flow</strong>, i.e. the hydraulics <strong>of</strong> the constructions,<br />

is modeled with GeoSys /<br />

Rock<strong>flow</strong> using st<strong>and</strong>ard FEM. Fig. 15<br />

shows that the two-dimensional scenarios<br />

exhibit complex <strong>flow</strong> patterns under un<strong>saturated</strong><br />

conditions. The velocity vectors at<br />

the element nodes <strong>of</strong> the FEM mesh for the<br />

road dam presented in Fig. 15 indicate<br />

unhindered infiltration <strong>of</strong> water from the<br />

low permeable soil on top <strong>of</strong> the embankment<br />

into the DW material. Along the<br />

sloped material boundary with high permeable<br />

soil on top <strong>of</strong> the coarse DW, however,<br />

strong capillary barrier effects are observed.<br />

These cause a concentration <strong>of</strong> the water<br />

flux on top <strong>of</strong> the DW <strong>and</strong> generation <strong>of</strong><br />

lateral run<strong>of</strong>f, almost completely bypassing<br />

the DW.<br />

Fig. 15: Element nodes <strong>and</strong> velocity vectors<br />

<strong>of</strong> un<strong>saturated</strong> water <strong>flow</strong> in a section <strong>of</strong> the<br />

model domain (Beyer et al., 2007b [EP 6]).<br />

Reactive transport <strong>of</strong> the model compounds<br />

is simulated using the stream tube concept<br />

<strong>of</strong> the SMART code, to take full advantage<br />

<strong>of</strong> the reactive process models implemented<br />

in SMART (degradation, intraparticle<br />

diffusion kinetics, sorption, etc.). Coupling<br />

between GeoSys / Rock<strong>flow</strong> <strong>and</strong> SMART is<br />

achieved through the travel time pdf. These<br />

are generated by simulation <strong>of</strong> conservative<br />

tracer breakthrough curves by GeoSys /<br />

Rock<strong>flow</strong> using the FEM. The pdf are used<br />

as input for the reactive transport simulations<br />

with SMART. The model output <strong>of</strong><br />

SMART for the three model substances at<br />

the groundwater surface represents concentrations<br />

integrated along the cross-section<br />

<strong>of</strong> the contaminant transport path only.<br />

These breakthrough curves for the tracer in<br />

the road dam are displayed in Fig. 16 as<br />

grey curves. The three black curves<br />

represent the same tracer breakthrough<br />

concentrations but are integrated along the<br />

groundwater surface <strong>of</strong> the overall model<br />

domain. Hence, they account for dilution by<br />

uncontaminated seepage water which<br />

bypasses the actual transport path due to the<br />

capillary barrier.<br />

Breakthrough curves in relative concentrations<br />

C/C0 [-] are given here for three <strong>of</strong><br />

the six soils regarded in this study, i.e. for a<br />

cambisol, a podzol <strong>and</strong> a chernozem. Comparing<br />

the concentration breakthrough for<br />

the transport path (grey curves), it is found<br />

that the earliest breakthrough time for the<br />

19

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