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Title: Alternative Sweeteners

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Isomalt 269<br />

IV. PHYSICO-CHEMICAL PROPERTIES<br />

A. Physical Properties<br />

The sorption isotherm (see Fig. 4) shows that isomalt has a very low water activity.<br />

At 25°C isomalt absorbs virtually no water up to a relative humidity of 85%.<br />

Furthermore, isomalt does not start absorbing water until the temperature reaches<br />

60°C at 75% relative humidity (rh) or 80°C at 65% rh (9). This very low hygroscopicity<br />

means that isomalt can be stored easily and distributed without much<br />

special care. Furthermore, this explains why products exclusively or mainly based<br />

on isomalt (e.g., hard candies) tend to be not sticky and have a long shelf-life.<br />

As depicted in Fig. 5, the solubility of isomalt-ST is much lower than<br />

that of sugar at 20°C, namely 24.5 g/100 g solution compared with a value of<br />

66.7 g/100 g solution for sugar (4, 9). Because of its low solubility, oversaturated<br />

solutions can be obtained with a relatively low concentration of isomalt. The<br />

solubility of isomalt increases with increasing temperature and is comparable to<br />

sucrose at most processing temperatures (85°C).<br />

Figure 4 Sorption isotherm for isomalt-ST at three temperatures (25, 60, and 80°C);<br />

w s is the amount of water absorbed by isomalt (kg water/kg isomalt).

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