Title: Alternative Sweeteners

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Contents Preface iii Contributors ix 1. Alternative Sweeteners: An Overview 1 Lyn O’Brien Nabors Part I. Low-Calorie Sweeteners 2. Acesulfame K 13 Gert-Wolfhard von Rymon Lipinski and Lisa Y. Hanger 3. Alitame 31 Michael H. Auerbach, Graeme Locke, and Michael E. Hendrick 4. Aspartame 41 Harriett H. Butchko, W. Wayne Stargel, C. Phil Comer, Dale A. Mayhew, and Sue E. Andress 5. Cyclamate 63 Barbara A. Bopp and Paul Price 6. Neohesperidin Dihydrochalcone 87 Francisco Borrego and Helena Montijano v
vi Contents 7. Tagatose 105 Hans Bertelsen, Søren Juhl Hansen, Rene Soegaard Laursen, James Saunders, and Kristian Eriknauer 8. Neotame 129 W. Wayne Stargel, Dale A. Mayhew, C. Phil Comer, Sue E. Andress, and Harriett H. Butchko 9. Saccharin 147 Ronald L. Pearson 10. Stevioside 167 A. Douglas Kinghorn, Christine D. Wu, and Djaja Djendoel Soejarto 11. Sucralose 185 Leslie A. Goldsmith and Carolyn M. Merkel 12. Less Common High-Potency Sweeteners 209 A. Douglas Kinghorn and César M. Compadre Part II. Reduced-Calorie Sweeteners 13. Erythritol 235 Milda E. Embuscado and Sakharam K. Patil 14. Hydrogenated Starch Hydrolysates and Maltitol Syrups 255 Laura Eberhardt 15. Isomalt 265 Marie-Christel Wijers and Peter Jozef Sträter 16. Maltitol 283 Kazuaki Kato and Alan H. Moskowitz 17. Lactitol: A New Reduced-Calorie Sweetener 297 Paul H. J. Mesters, John A. van Velthuijsen, and Saskia Brokx 18. Sorbitol and Mannitol 317 Anh S. Le and Kathleen Bowe Mulderrig
Page 3 and 4: ISBN: 0-8247-0437-1 This book is pr
Page 5: iv Preface these sweeteners are bei
Page 10 and 11: Contributors Sue E. Andress The Nut
Page 12 and 13: Contributors xi Carolyn M. Merkel M
Page 14 and 15: 1 Alternative Sweeteners: An Overvi
Page 16 and 17: Overview 3 II. RELATIVE SWEETNESS P
Page 18 and 19: Overview 5 IV. INTERNATIONAL REGULA
Page 20 and 21: Overview 7 V. U.S. REGULATION OF SW
Page 22 and 23: Overview 9 General recognition of s
Page 24 and 25: Overview 11 the maximum dietary lev
Page 26 and 27: 2 Acesulfame K Gert-Wolfhard von Ry
Page 28 and 29: Acesulfame K 15 Figure 3 Acesulfame
Page 30 and 31: Acesulfame K 17 Figure 4 Sweetness
Page 32 and 33: Acesulfame K 19 The acute oral toxi
Page 34 and 35: Acesulfame K 21 Table 2 Stability o
Page 36 and 37: Acesulfame K 23 were preferred over
Page 38 and 39: Acesulfame K 25 losses during bakin
Page 40 and 41: Acesulfame K 27 All methods describ
Page 42 and 43: Acesulfame K 29 24. Report of the S
Page 44 and 45: 3 Alitame Michael H. Auerbach Danis
Page 46 and 47: Alitame 33 IV. SOLUBILITY At the is
Page 48 and 49: Alitame 35 Figure 3 Alitame and asp
Page 50 and 51: Alitame 37 Figure 5 Metabolism of a
Page 52 and 53: Alitame 39 autonomic, gastrointesti
Page 54 and 55: 4 Aspartame Harriett H. Butchko, W.
Page 56 and 57:
Aspartame 43 Figure 2 Principal con
Page 58 and 59:
Aspartame 45 A wide range exists ov
Page 60 and 61:
Aspartame 47 Figure 4 Dietary intak
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Aspartame 49 day for 60-kg adults (
Page 64 and 65:
Aspartame 51 mood, and behavior (88
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Aspartame 53 VI. WORLDWIDE REGULATO
Page 68 and 69:
Aspartame 55 30. A Bar, C Biermann.
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Aspartame 57 67. HH Butchko, C Tsch
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Aspartame 59 104. AF Stokes, A Belg
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Aspartame 61 144. D Squillacote. As
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64 Bopp and Price Figure 1 Structur
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66 Bopp and Price Table 1 Regulator
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68 Bopp and Price V. ADMIXTURE POTE
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70 Bopp and Price and thickeners (1
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72 Bopp and Price XII. METABOLISM C
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74 Bopp and Price sodium cyclamate
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76 Bopp and Price ied during the pa
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78 Bopp and Price the studies invol
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80 Bopp and Price 0.42 µg/ml and w
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82 Bopp and Price 4. U.S. Patent No
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84 Bopp and Price 48. SM Sieber, RH
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6 Neohesperidin Dihydrochalcone Fra
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Neohesperidin Dihydrochalcone 89 Fi
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Neohesperidin Dihydrochalcone 91 Fi
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Neohesperidin Dihydrochalcone 93 in
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Neohesperidin Dihydrochalcone 95 ot
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Neohesperidin Dihydrochalcone 97 Ta
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Neohesperidin Dihydrochalcone 99 th
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Neohesperidin Dihydrochalcone 101 c
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Neohesperidin Dihydrochalcone 103 5
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7 Tagatose Hans Bertelsen and Søre
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Tagatose 107 the same type of Food
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Tagatose 109 in pigs according to m
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Tagatose 111 IV. USE OF D-TAGATOSE
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Tagatose 113 rinsing periods or dur
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Tagatose 115 anaerobic bacterial fe
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Tagatose 117 The intestines of both
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Tagatose 119 Table 1 Relative Sweet
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Tagatose 121 D. Hygroscopicity Taga
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Tagatose 123 Table 2 Heat of Soluti
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Tagatose 125 In conclusion, tagatos
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Tagatose 127 24. BB Jensen, B Buema
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130 Stargel et al. Figure 1 Compari
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132 Stargel et al. Figure 2 Matrix
Page 147 and 148:
134 Stargel et al. ness of neotame
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136 Stargel et al. Figure 4 Taste p
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138 Stargel et al. Table 1 Solubili
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140 Stargel et al. study strains in
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142 Stargel et al. to 10,000 µg/pl
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144 Stargel et al. for general use
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9 Saccharin Ronald L. Pearson PMC S
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Saccharin 149 proved for use in the
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Saccharin 151 was added to sodium d
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Saccharin 153 Table 2 Economics of
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Saccharin 155 Table 4 Saccharin Adm
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Table 6 Flavor Profile and Cost Com
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Saccharin 159 Figure 5 Hydrolysis o
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Saccharin 161 malian repellant (52,
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Saccharin 163 REFERENCES 1. GE DuBo
Page 178:
Saccharin 165 67. GP Schoenig, et a
Page 181 and 182:
168 Kinghorn et al. herbarium speci
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170 Kinghorn et al. Figure 1 Struct
Page 185 and 186:
172 Kinghorn et al. V. USE AND ADMI
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174 Kinghorn et al. sulting in the
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176 Kinghorn et al. Figure 2 Struct
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178 Kinghorn et al. iol administere
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180 Kinghorn et al. cus mutans, or
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182 Kinghorn et al. a natural sweet
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11 Sucralose Leslie A. Goldsmith an
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Sucralose 187 Figure 2 Sweeteness i
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Sucralose 189 cant difference was f
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Sucralose 191 fructose, and/or insu
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Sucralose 193 Figure 4 Sucralose so
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Sucralose 195 Figure 6 Viscosities
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Sucralose 197 Table 2 Sucralose Int
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Sucralose 199 tively, compared with
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Sucralose 201 Figure 10 Breakdown o
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Sucralose 203 Table 3 Percent Mass
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Sucralose 205 Table 4 Initial Appli
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Sucralose 207 4. Sucralose Safety A
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210 Kinghorn and Compadre establish
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212 Kinghorn and Compadre grosvenor
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214 Kinghorn and Compadre form. Phy
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216 Kinghorn and Compadre of the de
Page 231 and 232:
218 Kinghorn and Compadre Figure 5
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Page 235 and 236:
Page 237 and 238:
Page 239 and 240:
226 Kinghorn and Compadre sweet tas
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Page 243 and 244:
230 Kinghorn and Compadre 5. O Tana
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232 Kinghorn and Compadre 41. S Nir
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13 Erythritol Milda E. Embuscado an
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Erythritol 237 The commercial produ
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Table 2 Properties of Erythritol Co
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Erythritol 241 used to obtain the d
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Erythritol 243 crose stabilized and
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Erythritol 245 Figure 4 (A) Rate of
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Table 6 Assessment Criteria for the
Page 262 and 263:
Table 7 Summary of Pivotal Toxicity
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Erythritol 251 VI. FOOD AND PHARMAC
Page 266 and 267:
Erythritol 253 5. C Servo, J Pabo,
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14 Hydrogenated Starch Hydrolysates
Page 270 and 271:
Figure 1 (a) Chemical structures fo
Page 272 and 273:
Hydrogenated Starch Hydrolysates an
Page 274 and 275:
Page 276 and 277:
Page 278 and 279:
15 Isomalt Marie-Christel Wijers* P
Page 280 and 281:
Isomalt 267 GPM depends on the isom
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Isomalt 269 IV. PHYSICO-CHEMICAL PR
Page 284 and 285:
Isomalt 271 temperature than sucros
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Isomalt 273 C. Diabetics A number o
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Isomalt 275 Figure 7 Changes in wei
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Isomalt 277 C. Chewing Gum Sticks,
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Isomalt 279 isomalt is significantl
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Isomalt 281 der Sorbit-Toleranz ges
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16 Maltitol Kazuaki Kato Towa Chemi
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Maltitol 285 Like the other polyols
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Maltitol 287 of shape over time), h
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Maltitol 289 results of this confer
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Maltitol 291 available on certain p
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Maltitol 293 Table 3 Worldwide Stat
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Maltitol 295 alcohol. Unpublished r
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298 Mesters et al. Figure 1 The che
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300 Mesters et al. rium and equal m
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302 Mesters et al. sugars are then
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304 Mesters et al. Figure 2 Telemet
Page 319 and 320:
306 Mesters et al. Figure 3 Moistur
Page 321 and 322:
308 Mesters et al. Figure 6 Viscosi
Page 323 and 324:
310 Mesters et al. tose are the mai
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312 Mesters et al. Figure 8 The wat
Page 327 and 328:
314 Mesters et al. food containing
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18 Sorbitol and Mannitol Anh S. Le
Page 332 and 333:
Sorbitol and Mannitol 319 Figure 2
Page 334 and 335:
Table 1 Physical Properties of the
Page 336 and 337:
Sorbitol and Mannitol 323 Figure 4
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Sorbitol and Mannitol 325 bases are
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Sorbitol and Mannitol 327 is used a
Page 342 and 343:
Sorbitol and Mannitol 329 ‘‘cap
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Sorbitol and Mannitol 331 that mann
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Sorbitol and Mannitol 333 Mannitol
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19 Xylitol Philip M. Olinger Polyol
Page 350 and 351:
Xylitol 337 Milled forms of xylitol
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Xylitol 339 Table 2 Solubility of S
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Xylitol 341 tol in a fluoride tooth
Page 356 and 357:
Xylitol 343 The recognition of xyli
Page 358 and 359:
Xylitol 345 tion of the availabilit
Page 360 and 361:
Xylitol 347 grow and metabolize opt
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Xylitol 349 VIII. USE OF XYLITOL AS
Page 364 and 365:
Xylitol 351 IX. USE OF XYLITOL IN P
Page 366 and 367:
Xylitol 353 Human tolerance of high
Page 368 and 369:
Xylitol 355 29. CS Gong, TA Claypoo
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Xylitol 357 71. JDB Featherstone, T
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Xylitol 359 112. JS Van der Hoeven.
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Xylitol 361 tans omz 176 by xylitol
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Xylitol 363 BL Horecker, K Lang, Y
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Xylitol 365 of Certain Food Additiv
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368 White and Osberger II. MANUFACT
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370 White and Osberger scribe impro
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372 White and Osberger Figure 1 Cyc
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374 White and Osberger When asparta
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376 White and Osberger Table 5 Temp
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378 White and Osberger Figure 3 Met
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380 White and Osberger Figure 5 Com
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382 White and Osberger Table 6 Glyc
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384 White and Osberger Table 8 Low-
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386 White and Osberger F. Confectio
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388 White and Osberger In 1993, Vui
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390 White and Osberger 18. AL Forbe
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392 Buck Table 1 Market Division be
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394 Buck Table 3 World HFS Consumpt
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396 Buck Figure 3 Production of 42%
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398 Buck Table 4 Typical Characteri
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400 Buck Table 5 Effect of Temperat
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402 Buck Table 7 International Soci
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404 Buck Because of the high purity
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406 Buck VII. APPLICATIONS HFCS rep
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408 Buck is a benefit and in other
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410 Buck 1986. This evaluation conc
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22 Isomaltulose William E. Irwin* P
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Isomaltulose 415 Figure 2 Isosweet
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Isomaltulose 417 Figure 3 Solubilit
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Isomaltulose 419 Figure 6 Plasma in
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Isomaltulose 421 6. Dreissig VW, Lu
Page 437 and 438:
424 Richards and Dexter various pla
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426 Richards and Dexter from assays
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428 Richards and Dexter desiccation
Page 443 and 444:
430 Richards and Dexter 2. Taste Qu
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432 Richards and Dexter parative da
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434 Richards and Dexter Table 3 Com
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436 Richards and Dexter dissipate t
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438 Richards and Dexter unpublished
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440 Richards and Dexter IX. SHELF-L
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Figure 7 Egg white (95 g) was mixed
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444 Richards and Dexter Figure 10 B
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446 Richards and Dexter Figure 12 O
Page 461 and 462:
448 Richards and Dexter Figure 14 T
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450 Richards and Dexter XIII. CARIO
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452 Richards and Dexter tions was s
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454 Richards and Dexter activity, a
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456 Richards and Dexter E. 14-day T
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458 Richards and Dexter 3. J Leibow
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460 Richards and Dexter 41. LM Crow
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24 Mixed Sweetener Functionality Ab
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Mixed Sweetener Functionality 465 2
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Mixed Sweetener Functionality 467 T
Page 482 and 483:
Page 484 and 485:
Mixed Sweetener Functionality 471 F
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Page 488 and 489:
Page 490 and 491:
Page 492 and 493:
Mixed Sweetener Functionality 479 I
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25 Aspartame-Acesulfame: Twinsweet
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Aspartame-Acesulfame: Twinsweet 483
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Page 500 and 501:
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Page 510 and 511:
Page 512 and 513:
26 Polydextrose Helen Mitchell Dani
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Polydextrose 501 Table 1 Approximat
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Polydextrose 503 at 25°C. Polydext
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Polydextrose 505 Figure 4 Hygroscop
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Polydextrose 507 Table 5 Functional
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Polydextrose 509 F. Fiber Polydextr
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Polydextrose 511 providing bulk, mo
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Polydextrose 513 H. Soft Candy The
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Polydextrose 515 B. International T
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Polydextrose 517 chemical and econo
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520 Deis I. FAT IS ESSENTIAL AND FU
Page 535 and 536:
522 Deis Figure 1 Ingredient suppor
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524 Deis binding water, thus provid
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526 Deis The U.S. Department of Agr
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528 Deis stabilizer, thickener, or
Page 543 and 544:
530 Deis mouth feel and rate of gel
Page 545 and 546:
532 Deis Figure 4 Structure of glyc
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534 Deis Table 4 General Categories
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536 Deis ninths of the fat availabl
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538 Deis the same function in all f
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540 Deis 28. Anon. Glycerine: like
Page 555 and 556:
542 Index [Alitame] solubility, 33
Page 557 and 558:
544 Index [Erythritol] gastrointest
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546 Index [High fructose corn syrup
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548 Index Mogrosides, 211-213 prope
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550 Index [Polyols] isomalt, 265-28
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552 Index [Sucralose] safety, 189-1
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