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Title: Alternative Sweeteners

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486 Fry and Hoek<br />

real applications than tests conducted with water. Figure 2 indicates a relative<br />

sweetness figure for Twinsweet of about 350 times as sweet as sucrose in water<br />

and 400 times as sweet in pH 3.2 citrate at 4% sucrose equivalence. The higher<br />

relative sweetness in the citrate buffer is consistent with observations of the behavior<br />

of aspartame, which also tastes sweeter in acid solution than in water.<br />

Across the full range of concentration, the relative sweetness of Twinsweet<br />

is 11% higher than could be obtained from the same weight of an equimolar<br />

mixture of aspartame with acesulfame-K. This is because the sweetenersweetener<br />

salt contains only active sweeteners and no potassium. The latter accounts<br />

for 19.4% of acesulfame-K by weight but contributes no sweetness. In a<br />

similar vein, Twinsweet has a very low moisture content, whereas the aspartame<br />

component of a physical blend can contain up to 4.5% moisture (strictly ‘‘loss<br />

on drying’’) while remaining within international specification limits. The overall<br />

saving on nonsweet components, namely potassium and moisture, means that the<br />

aspartame-acesulfame salt is a more effective sweetener on a weight-for-weight<br />

Figure 3 Synergy in a blend of aspartame (APM) with acesulfame-K (AceK) as a function<br />

of blend ratio, also showing the fixed equimolar ratio of aspartame-acesulfame (Twinsweet).<br />

Solvent pH 3.2 citrate buffer, blend concentration 400 ppm at all ratios,<br />

aspartame-acesulfame concentration 360 ppm. (From Ref. 6.)

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