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advanced building skins 14 | 15 June 2012 - lamp.tugraz.at - Graz ...

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2 M<strong>at</strong>erial PMMA<br />

Advanced Building Skins<br />

Polymethyl methacryl<strong>at</strong>e, PMMA for short, is the chemical name of a highly transparent plastic.<br />

Brand names for it are Plexiglas® or Acrylite® for example. PMMA belongs to the group of<br />

transparent thermoplastics and stands out due to good we<strong>at</strong>hering resistance and a rel<strong>at</strong>ive hard surface<br />

as well as its transparency. For sheet m<strong>at</strong>erial there are mainly two manufacturing processes, extrusion<br />

and cast.<br />

The m<strong>at</strong>erial characteristics are dependent on the type of manufacturing and the environmental<br />

influences such as temper<strong>at</strong>ure and exposure time. The most important m<strong>at</strong>erial characteristics under<br />

standard clim<strong>at</strong>e conditions according to DIN 7823 are summarized in Table 1.<br />

Table 1: M<strong>at</strong>erial characteristics according to DIN 7823<br />

Extruded PMMA Cast PMMA Unit<br />

Young´s Modulus ≥ 2900 ≥ 3000 MPa<br />

Tensile Strength ≥ 60 ≥ 70 MPa<br />

Tensile Strain ≥ 2 ≥ 4 %<br />

Flexural Strength 100-1<strong>15</strong> 100-1<strong>15</strong> MPa<br />

Density 1,19 1,19 g/cm³<br />

Thermal Expansion<br />

Coefficient<br />

7 x 10 -5 7 x 10 -5 1/K<br />

In Figure 1 the dependence th<strong>at</strong> Young’s Modulus has with the temper<strong>at</strong>ure is shown. At 23°C you can<br />

see a young´s modulus of 3300 MPa. At 60°C it drops down to 2500 MPa.<br />

Figure 1: Temper<strong>at</strong>ure dependency of young´s<br />

modulus [Evonik Industries]<br />

- 2 -<br />

Figure 2: Relax<strong>at</strong>ion [Evonik Industries]<br />

The strain can be divided into three different parts. An energy elastic strain occurs immedi<strong>at</strong>ely when<br />

a load is applied. The second part is an entropic elastic strain, with which the position of the molecule<br />

chains rel<strong>at</strong>ive to one another is changed. This part of the strain is slowly reduced after the load is<br />

relieved. The third part is a viscous flow th<strong>at</strong> represents an irreversible deform<strong>at</strong>ion. In Figure 2, the<br />

stress relax<strong>at</strong>ion over the dur<strong>at</strong>ion of the load is plotted. With a steady deform<strong>at</strong>ion, the stress is<br />

relaxed significantly over time. The relax<strong>at</strong>ion is dependent on the level of stress th<strong>at</strong> is applied.<br />

PMMA has a very high transmission, which results in the m<strong>at</strong>erial he<strong>at</strong>ing up only a very small<br />

amount in the sun.

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