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On the Formation of Nitrogen Oxides During the Combustion of ...

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4 Numerical Modeling and Simulation<br />

1.4<br />

s<br />

Initial droplet diameter D 0<br />

1.2<br />

D 2 law<br />

Simulation<br />

Vaporization time τv<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

0.0<br />

0 x 10 −6 50 x 10 −6 100 x 10 −6 150 x 10 −6 200 x 10 −6 m<br />

Figure 4.8: Validation <strong>of</strong> Vaporization Time for Different Initial Droplet Diameters. The vaporization<br />

time τ v is evaluated for water droplets as a function <strong>of</strong> <strong>the</strong> initial droplet<br />

diameter D 0 .<br />

stopped when <strong>the</strong> droplet diameter D drops below 0.1 % <strong>of</strong> D 0 . The D² law<br />

and single droplet model show <strong>the</strong> same dependency on D 0 : The characteristic<br />

time <strong>of</strong> vaporization τ v is proportional to D 2 0<br />

, and <strong>the</strong> vaporization rate k is<br />

approximately constant at a constant ambient temperature T ∞ . Generally, <strong>the</strong><br />

results are in good agreement. However, at large diameters, small differences<br />

in k result in an increased absolute difference in τ v .<br />

The droplet or, more precisely, <strong>the</strong> droplet surface temperature T S as a function<br />

<strong>of</strong> <strong>the</strong> ambient temperature T ∞ is illustrated in Figure 4.9. The initial<br />

droplet diameter D 0 is again kept constant at 100µm. As shown in Figure 4.9,<br />

<strong>the</strong>re is a roughly linear increase <strong>of</strong> T S with an increase <strong>of</strong> T ∞ , and both models<br />

reproduce this behavior. The data points fit very well. The analytical<br />

D² law predicts slightly higher droplet (surface) temperatures T S at high ambient<br />

temperature T ∞ [298].<br />

Generally, <strong>the</strong> analytical D² law is in good agreement with <strong>the</strong> numerical calculations<br />

<strong>of</strong> <strong>the</strong> single droplet model. However, <strong>the</strong>re are some discrepancies,<br />

especially at high ambient temperature T ∞ : The vaporization time τ v is lower<br />

146

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