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On the Formation of Nitrogen Oxides During the Combustion of ...

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5 Results<br />

6.0<br />

g kg −1<br />

Emission index <strong>of</strong> NOx EINOx<br />

4.0<br />

2.0<br />

T ∞ = 500 K<br />

T ∞ = 600 K<br />

T ∞ = 700 K<br />

0.0<br />

0.0 0.2 0.4 0.6 0.8 1.0<br />

Pre-vaporization rate Ψ<br />

Figure 5.16: Impact <strong>of</strong> Ambient Preheating on NO x Abatement Potential due to Pre-<br />

Vaporization by Referring to <strong>the</strong> Reacting Fuel Mass. The positions <strong>of</strong> heat introduction<br />

and extraction are set to <strong>the</strong> constant values <strong>of</strong> r m,in = 0.8×10 −3 m and<br />

r m,ex = 1.4×10 −3 m (cf. Fig. 5.3).<br />

Emissions altoge<strong>the</strong>r are lower when relating <strong>the</strong> emission index EI NOx to <strong>the</strong><br />

initial droplet mass (Fig. 5.15) than to <strong>the</strong> reacting fuel (Fig. 5.16). Despite<br />

<strong>the</strong> temperature difference <strong>of</strong> ∆T ∞ = 100 and 200K, pre-vaporization is capable<br />

<strong>of</strong> compensating <strong>the</strong> increased NO x formation at Ψ= 0.5 and 0.8, respectively<br />

(Fig. 5.15). This is essential, as temperature level and pre-vaporization<br />

time are major design parameters that need to be weighed up against each<br />

o<strong>the</strong>r in <strong>the</strong> layout <strong>of</strong> many combustion systems. Fur<strong>the</strong>rmore, with an increase<br />

in T ∞ , <strong>the</strong> process <strong>of</strong> obtaining lower NO x emissions starts at lower degrees<br />

<strong>of</strong> vaporization. This is due to an increased diffusive transport at those<br />

higher temperature levels. As pointed out in Chapter 5.2, a certain amount<br />

<strong>of</strong> gaseous, unburned fuel remains in <strong>the</strong> outer region <strong>of</strong> <strong>the</strong> gas atmosphere.<br />

This fuel can be consumed in <strong>the</strong> fur<strong>the</strong>r course <strong>of</strong> <strong>the</strong> combustion process<br />

within a technical application. For a preheating temperature <strong>of</strong> T ∞ = 700K<br />

and a pre-vaporization rate <strong>of</strong> Ψ = 0.8, this fuel amount rises up to 278 % <strong>of</strong><br />

<strong>the</strong> fuel consumed in <strong>the</strong> droplet flame. Figure 5.16 shows <strong>the</strong> NO x emissions<br />

<strong>of</strong> <strong>the</strong> droplet after correcting <strong>the</strong> results for this influence. The trend is uniform<br />

for all three temperature levels. The <strong>of</strong>fset <strong>of</strong> <strong>the</strong> individual curves alone<br />

180

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