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On the Formation of Nitrogen Oxides During the Combustion of ...

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3.1 Droplet <strong>Combustion</strong> Facility<br />

The combustion chamber is installed on <strong>the</strong> fourth platform <strong>of</strong> <strong>the</strong> DCU<br />

(Fig. 3.2, E) and has inner dimensions <strong>of</strong> (140×50×54) mm 3 (W×D×H). Its<br />

temperature is precisely controlled by a K-type <strong>the</strong>rmocouple that is attached<br />

to <strong>the</strong> inner combustion chamber wall and by heating cartridges that are integrated<br />

into <strong>the</strong> combustion chamber housing. Two fur<strong>the</strong>r <strong>the</strong>rmocouples<br />

(S-type) measure <strong>the</strong> gas temperature inside <strong>the</strong> combustion chamber. Apart<br />

from <strong>the</strong>se <strong>the</strong>rmal aspects, <strong>the</strong> combustion chamber also houses four symmetrically<br />

aligned sample probes for exhaust gas sampling [208, 293, 294, 296].<br />

The combustion chamber is designed in line with <strong>the</strong> following operational<br />

specification:<br />

• Facilitate fast heat-up periods starting from an ambient temperature<br />

level (within 45 to 60 min)<br />

• Maintain preheating temperature at set-point <strong>of</strong> e.g. 500±1K<br />

• Exchange air/exhaust from inside <strong>the</strong> combustion chamber within 15s<br />

• Restore set-point temperature within 40s after an air exchange<br />

• Facilitate execution <strong>of</strong> nominal experiment sequence including <strong>the</strong> insertion<br />

<strong>of</strong> <strong>the</strong> droplet array holder and <strong>the</strong> exhaust gas collection through<br />

<strong>the</strong> exhaust gas sampling system (see also Chap. 3.2.6)<br />

• Operate combustion chamber shutter (open/close position) in accordance<br />

with <strong>the</strong> experiment sequence<br />

• Minimize heat loss <strong>of</strong> combustion chamber induced by <strong>the</strong> insertion <strong>of</strong><br />

<strong>the</strong> cold droplet array holder (steel frame)<br />

In particular <strong>the</strong> shutter design (Fig. 3.8) must not counteract <strong>the</strong> <strong>the</strong>rmal insulation<br />

and airtightness <strong>of</strong> <strong>the</strong> combustion chamber. The latter requirement<br />

is essential for <strong>the</strong> flushing sequence at <strong>the</strong> end <strong>of</strong> a combustion run, which<br />

is subdivided into a complete evacuation and a succeeding refilling with fresh<br />

air. A leak at <strong>the</strong> shutter sealing might cause a major interference with <strong>the</strong><br />

global pressure regulation <strong>of</strong> <strong>the</strong> DCU.<br />

By lifting <strong>the</strong> droplet array into <strong>the</strong> combustion chamber, a little air gap <strong>of</strong><br />

1mm on average remains between <strong>the</strong> combustion chamber opening (Fig. 3.8,<br />

D) and <strong>the</strong> steel frame <strong>of</strong> <strong>the</strong> droplet array holder inserted. This gap must<br />

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