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On the Formation of Nitrogen Oxides During the Combustion of ...

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6 Summary and Conclusions<br />

In times <strong>of</strong> depleting resources, processes involving <strong>the</strong> combustion <strong>of</strong> fossil<br />

fuels have to be highly efficient. Moreover, it is essential to develop novel<br />

combustion concepts that <strong>of</strong>fer a high potential for improvement towards environmentally<br />

neutral combustion engines and low exhaust gas emissions. Especially<br />

in aero-engines, <strong>the</strong> NO x emissions are seen to have a large potential<br />

for fur<strong>the</strong>r reduction. In this respect, partial premixed combustion with a partial<br />

degree <strong>of</strong> liquid fuel vaporization aims at combining <strong>the</strong> advantages <strong>of</strong><br />

lean premixed and nonpremixed combustion. The study at hand was undertaken<br />

to help resolve <strong>the</strong> issue <strong>of</strong> a possible effect <strong>of</strong> partial droplet vaporization<br />

on <strong>the</strong> overall NO x production under idealized conditions. Against this<br />

background, <strong>the</strong> vaporization and combustion <strong>of</strong> single droplets and linear<br />

droplet arrays were investigated by experiments as well as modeled and numerically<br />

simulated.<br />

The microgravity environment was utilized because it allows a detailed observation<br />

<strong>of</strong> <strong>the</strong> most essential phenomena in droplet combustion without <strong>the</strong><br />

disturbance <strong>of</strong> natural convection. These experiments also provided a basis<br />

for <strong>the</strong> validation <strong>of</strong> an advanced model on droplet combustion. Linear<br />

droplet arrays <strong>of</strong> <strong>the</strong> hydrocarbon C 10 H 22 were burned without relative velocity<br />

to <strong>the</strong> ambient gas. A sophisticated design and optimized control procedures<br />

were used to guarantee representative gas samples from <strong>the</strong> experiment<br />

runs and a reliable, subsequent gas analysis on <strong>the</strong> ground.<br />

Numerical work was performed, studying <strong>the</strong> driving forces <strong>of</strong> NO x generation<br />

in single droplet combustion based on a spherically symmetric 1D model.<br />

Microgravity conditions were applied correspondingly and detailed kinetics<br />

were used. Since none <strong>of</strong> <strong>the</strong> C 10 H 22 mechanisms considered contains NO x<br />

chemistry by default, an approach for combining chemical kinetics was established,<br />

and an energetically neutral ignition method was formulated within<br />

<strong>the</strong> droplet combustion model proposed. It was essential to provide a manageable<br />

combination <strong>of</strong> <strong>the</strong> fields <strong>of</strong> droplet vaporization, ignition, combus-<br />

195

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