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On the Formation of Nitrogen Oxides During the Combustion of ...

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5 Results<br />

4.0<br />

g kg −1<br />

Emission index <strong>of</strong> NOx EINOx<br />

3.0<br />

2.0<br />

1.0 With heat extraction (ref. reacting mass)<br />

With heat extraction (ref. droplet mass)<br />

Without heat extraction (ref. reacting mass)<br />

Without heat extraction (ref. droplet mass)<br />

0.0<br />

0.0 0.2 0.4 0.6 0.8 1.0<br />

Pre-vaporization rate Ψ<br />

Figure 5.3: Emission Index <strong>of</strong> NO x as a Function <strong>of</strong> Pre-Vaporization Rate. The initial<br />

droplet diameter <strong>of</strong> <strong>the</strong> illustrated simulation runs is set to D 0 = 100µm. The<br />

positions <strong>of</strong> heat introduction and extraction are set to <strong>the</strong> constant values <strong>of</strong><br />

r m,in = 0.8×10 −3 m and r m,ex = 1.4×10 −3 m, respectively [298].<br />

gas phase is discretized with N = 200 grid points, twice as many as used for<br />

<strong>the</strong> configuration discussed in Chapter 5.1. Apart from that, <strong>the</strong> production <strong>of</strong><br />

NO x remains negligible in <strong>the</strong> outer radius <strong>of</strong> <strong>the</strong> gas phase because <strong>of</strong> moderate<br />

ambient temperatures <strong>of</strong> <strong>the</strong> burning regime investigated. The emissions<br />

caused by mere droplet combustion are equivalent to <strong>the</strong> total emissions here<br />

(cf. Eqs. (5.1) and (5.2), i.e. m NOx ,atm≈0) [297, 298].<br />

Baessler et al. [31, 32] reported that pre-vaporization <strong>of</strong> fuel spray becomes<br />

beneficial with respect to NO x formation only if <strong>the</strong> degree <strong>of</strong> vaporization<br />

is above a minimum limit and combustion is run in <strong>the</strong> lean regime. If insufficient<br />

fuel is vaporized before ignition, <strong>the</strong> NO x emissions stay almost<br />

unaffected. This correlation is clearly observable in <strong>the</strong> results reprinted in<br />

Figure 2.3. The numerical simulations discussed here reproduce this trend<br />

for single droplets, and its characteristics are reflected in detail in Figure 5.3.<br />

Squares and circles indicate setups in which heat is introduced into <strong>the</strong> computational<br />

domain to enforce ignition and where it is also extracted after a<br />

characteristic time to keep <strong>the</strong> energy balance (cf. Figs. 4.2 and 4.3). For comparison,<br />

<strong>the</strong> triangles mark emissions if heat is introduced only but not ex-<br />

162

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