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On the Formation of Nitrogen Oxides During the Combustion of ...

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5 Results<br />

16<br />

g kg −1<br />

Emission index <strong>of</strong> NOx EINOx<br />

12<br />

8<br />

4<br />

Ignition fixed,<br />

heat sink fixed<br />

Ignition variable,<br />

heat sink at fixed position<br />

Ignition variable,<br />

heat sink at fixed distance<br />

0<br />

0.0 0.2 0.4 0.6 0.8 1.0<br />

Pre-vaporization rate Ψ<br />

Figure 5.5: Emission Index <strong>of</strong> NO x for Different Ignition Approaches. The emission index<br />

EI NOx is related to <strong>the</strong> initial droplet mass m fuel,0 and shown as a function <strong>of</strong> prevaporization<br />

rate Ψ (cf. Fig. 5.3 and B.2). The initial droplet diameter, before prevaporization,<br />

is set to D 0 = 100µm [297].<br />

position and expansion <strong>of</strong> <strong>the</strong> heat extraction volume V ex is marginal with regard<br />

to flame position and relative NO x production. This is due to <strong>the</strong> larger<br />

radial distance <strong>of</strong> r m,ex , <strong>the</strong> overall wide stretch <strong>of</strong> V ex , and <strong>the</strong> low values <strong>of</strong> <strong>the</strong><br />

volumetric heat sink ˙q v [297]. Figure 5.5 opposes <strong>the</strong> emission indices EI NOx<br />

calculated for <strong>the</strong> investigated methods <strong>of</strong> heat introduction and extraction to<br />

one ano<strong>the</strong>r. Squares depict emissions for <strong>the</strong> case <strong>of</strong> heat introduction and<br />

extraction at <strong>the</strong> constant positions r m,in = 0.8×10 −3 m and r m,ex = 1.4×10 −3 m,<br />

respectively. Circles show emissions for an ignition at φ r = 0.5 and a fixed<br />

heat extraction at r m,ex = 1.4×10 −3 m (“ignition variable, heat sink at fixed position”).<br />

Triangles also indicate emissions for an ignition position at φ r = 0.5<br />

but a fixed heat extraction distance from this φ r -position (“ignition variable,<br />

heat sink at fixed distance”) [297].<br />

A large difference emerges in <strong>the</strong> absolute values <strong>of</strong> EI NOx for <strong>the</strong> two different<br />

ignition approaches (Fig. 5.5). The emissions are significantly higher for <strong>the</strong><br />

spatially variable ignition (φ r = 0.5), and an increase <strong>of</strong> fuel pre-vaporization<br />

results in continuous NO x reduction. A significant NO x reduction seems to be<br />

feasible in <strong>the</strong> range <strong>of</strong> Ψ = 0.15 to 0.6. However, <strong>the</strong> real potential for NO x<br />

166

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