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1.5. Heat driven cooling<br />

1.5.1 Absorption<br />

There are two major types <strong>of</strong> absorption cycles:<br />

• Carré cycle which is used for cooling <strong>and</strong> air conditioning (as well<br />

as heat pumps) in the range <strong>of</strong> 15 kw to megawatts.<br />

• Platen Munters cycle which is used for small (household size)<br />

refrigerators/freezers.<br />

The two cycles are in principle almost identical, but in practice they<br />

differ a lot - hence the very different applications. In the following<br />

sections, the two types will be described.<br />

1.5.2 Carré cycle<br />

The basic principle <strong>of</strong> the absorption cycle is developed by the French<br />

scientist Ferdin<strong>and</strong> Carré about 1860.<br />

Working media.<br />

The fluid in the absorption cycle consists <strong>of</strong> a pair <strong>of</strong> a refrigerant <strong>and</strong><br />

an absorption medium which is capable to absorb the refrigerant. More<br />

than 40 refrigerants <strong>and</strong> 200 absorption media exist [35].<br />

The most common pairs are ammonia-water (N H 3 − H 2 O) <strong>and</strong> waterlithium<br />

bromide (H 2 O − LiBr ). Ammonia is the refrigerant in the N H 3 −<br />

H 2 O solution (ammonia has a lower boiling point than water), whereas<br />

water is the refrigerant in the H 2 O − LiBr solution.<br />

Ammonia-water is usable for small as well as large scale units<br />

working at various temperatures, e.g. air conditioning or industrial<br />

cooling/freezing (evaporator temperatures down to -60 ◦ C).<br />

Water-lithium bromide has a limited temperature range due to the<br />

freezing point <strong>of</strong> water, <strong>and</strong> in practical applications the chilled water<br />

should never be lower than 6 ◦ C [27]. Thus this pair is feasible for<br />

applications such as production <strong>of</strong> chilled water or air conditioning.<br />

9

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