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Cork insulation; a complete illustrated textbook on cork insulation ...

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HEAT AND THERMAL EXPANSION 11<br />

lish that "the volume of a given mass of any gas under c<strong>on</strong>stant<br />

pressure increases by a c<strong>on</strong>stant fracti<strong>on</strong> of its volume<br />

at zero for each rise of temperature of 1°C." The ratio of<br />

standard steam temperature (the minimum temperature of<br />

pure steam at 16 cm. pressure) to ice temperature (the temperature<br />

of pure melting ice at 76 cm. pressure) has been<br />

found by the air thermometer to be 1.367, or<br />

Steam temp. S<br />

=—= 1 .367<br />

Ice temp. I<br />

On the Centigrade scale S — I = 100, and from these<br />

two simple equati<strong>on</strong>s we find that S = ZTh° and I = 273°,<br />

approximately, Centigrade. Any other temperature may be<br />

determined by measuring its ratio to I or to S by means of<br />

the air thermometer. Temperatures measured in this way<br />

are called absolute temperatures, and thus it will be noted that<br />

the absolute zero <strong>on</strong> the Absolute scale is 273 degrees below<br />

the freezing point <strong>on</strong> the Centigrade scale. It has been<br />

established, since Jacques Alexandre Cesar Charles (1746-<br />

1822), a French physicist and aer<strong>on</strong>aut, gave us his Law of<br />

Charles, that the volumes of the same mass of gas under<br />

c<strong>on</strong>stant pressure are proporti<strong>on</strong>al to the temperature <strong>on</strong><br />

this Absolute scale, or<br />

V t+213 T<br />

vi U+213 T,<br />

if t + 273 is expressed by T, and t^ -f 273 by Tj.<br />

37.—Expansi<strong>on</strong> and C<strong>on</strong>tracti<strong>on</strong>.—If equal volumes of<br />

various gases are heated, under c<strong>on</strong>stant pressure, they were<br />

thought by Joseph Louis Gay-Lussac (1778-1850), a French<br />

chemist and physicist, to expand equivalent amounts for the<br />

same rise in temperature, but very careful measurements have<br />

since dem<strong>on</strong>strated quite perceptible differences of expansi<strong>on</strong><br />

of various gases, amm<strong>on</strong>ia, for example, being distinctly dif-<br />

ferent in its expansi<strong>on</strong> from hydrogen. Gases that are near<br />

their points of liquefacti<strong>on</strong> depart widely from Gay-Lussac's<br />

law ; amm<strong>on</strong>ia, sulphur dioxide and methyl chloride gases are<br />

easily liquefied and are comm<strong>on</strong>ly referred to as vapors.<br />

Hydrogen, <strong>on</strong> the other hand, is not easily liquefied under

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