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ENVIRONMENTAL EXPOSURE ASSESSMENT Explanation of symbols Dair aerial deposition flux per kg of soil [mg . kg -1. d -1 ] eq. (52) t time [d] k first order rate constant for removal from top soil [d -1 ] eq. (56) Csoil concentration in soil [mg . kg -1 ] In the formula above, the aerial deposition flux is used in mg substance per kg of soil per day. Dair can be derived by converting the total deposition flux (DEPtotalann) as follows: Explanation of symbols 80 D air = DEPtotalann DEPTH RHO soil • soil DEPtotalann annual average total deposition flux [mg . m -2. d -1 ] eq. (44) DEPTHsoil mixing depth of soil [m] Table 11 RHOsoil bulk density of soil [kg . m -3 ] eq. (18) Dair aerial deposition flux per kg of soil [mg . kg -1. d -1 ] The differential equation (51) has an analytical solution, given by: C soil (52) Dair ⎡ Dair ⎤ - k t ( t) = - - Csoil • e k ⎢ (0) ⎣ k ⎥ (53) ⎦ With this equation, the concentration can be calculated at each moment in time, when the initial concentration in that year is known. Accumulation of the substance may occur when sludge is applied over consecutive years. This is illustrated in Figure 11. As a realistic worst-case exposure scenario, it is assumed that sludge is applied for 10 consecutive years. To indicate for potential persistency of the substance, the percentage of the steady-state situation is calculated. As shown in Figure 11, the concentration in soil is not constant in time. The concentration will be high just after sludge application (in the beginning of the growth season), and lower at the end of the year due to removal processes. Therefore, for exposure of the endpoints, the concentration needs to be averaged over a certain time period. Different averaging times should be considered for these endpoints: for the ecosystem a period of 30 days after application of sludge is used. In Concentration (% of initial) 160 140 120 100 80 60 40 20 0 0 1 2 time (year) 3 4 Figure 11 Accumulation in soil due to several years of sludge application
Concentration (% of initial) 160 140 120 100 80 60 40 20 0 0 50 100 150 200 250 300 350 tim e (d a ys ) Figure 12 The concentration in soil after 10 years. The shaded area is the integrated concentration over a period of 180 days ENVIRONMENTAL EXPOSURE ASSESSMENT order to determine biomagnification effects and indirect human exposure, it is more appropriate to use an extended period of 180 days. This averaging procedure is illustrated in Figure 12 where the average concentration is given by the area of the shaded surface, divided by the number of days. The local concentration in soil is defined as the average concentration over a certain time period T. The average concentration over T days is given by: 1 T Clocal soil = C soil (t) dt T 0 • ∫ (54) Solving this equation for the range 0 to T gives the final equation for the average concentration in this period: Explanation of symbols Clocal soil = D k air 1 + k T ⎡ ⎢ ⎣ C soil (0) - D k air ⎤ ⎥ ⎦ • −kT [ 1- e ] Dair aerial deposition flux per kg of soil [mg . kg -1. d -1 ] eq. (52) T averaging time [d] Table 11 k first order rate constant for removal from top soil [d -1 ] eq. (56) Csoil (0) initial concentration (after sludge application) [mg . kg -1 ] eq. (63) Clocalsoil average concentration in soil over T days [mg . kg -1 ] (55) 81
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Institute for Health and Consumer P
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LEGAL NOTICE Neither the European C
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OVERVIEW This Technical Guidance Do
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CONTENTS 1 GENERAL INTRODUCTION ...
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4.2.3.4 Use of biodegradation scree
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1 GENERAL INTRODUCTION 1.1 BACKGROU
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GENERAL INTRODUCTION countries in t
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GENERAL INTRODUCTION PNEC is regard
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2 ENVIRONMENTAL EXPOSURE ASSESSMENT
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ENVIRONMENTAL EXPOSURE ASSESSMENT r
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2.2 MEASURED DATA ENVIRONMENTAL EXP
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ENVIRONMENTAL EXPOSURE ASSESSMENT w
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ENVIRONMENTAL EXPOSURE ASSESSMENT o
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ENVIRONMENTAL EXPOSURE ASSESSMENT T
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ENVIRONMENTAL EXPOSURE ASSESSMENT r
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Production ENVIRONMENTAL EXPOSURE A
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Page 43 and 44: Explanation of symbols ENVIRONMENTA
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Page 61 and 62: constant of zero. However, if it ca
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Page 69 and 70: Primary Settler Aeration Tank 2 5 3
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Page 79 and 80: Table 10 Overview of different expo
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Page 83 and 84: 2.3.8.3 Calculation of PEClocal for
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Page 87: Guidance for calculating PEClocal i
Page 93 and 94: Calculation of PEClocalsoil For soi
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Page 99 and 100: Output ENVIRONMENTAL EXPOSURE ASSES
Page 101 and 102: 3 EFFECTS ASSESSMENT 3.1 INTRODUCTI
Page 103 and 104: 3.2.1.1 Completeness of data New su
Page 105 and 106: EFFECTS ASSESSMENT • it is clearl
Page 107 and 108: EFFECTS ASSESSMENT 3.3 EFFECTS ASSE
Page 109 and 110: Table 16 Assessment factors to deri
Page 111 and 112: Input data EFFECTS ASSESSMENT The m
Page 113 and 114: Estimation of the PNEC The PNEC is
Page 115 and 116: EFFECTS ASSESSMENT biodegradability
Page 117 and 118: Table 17 Test systems for derivatio
Page 119 and 120: EFFECTS ASSESSMENT representative o
Page 121 and 122: In the partitioning method, it is a
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Page 125 and 126: 3.6.2.1 Calculation of PNEC using t
Page 127 and 128: 3.7 EFFECTS ASSESSMENT FOR THE AIR
Page 129 and 130: EFFECTS ASSESSMENT procedure availa
Page 131 and 132: EFFECTS ASSESSMENT bioaccumulation
Page 133 and 134: EFFECTS ASSESSMENT For some chemica
Page 135 and 136: EFFECTS ASSESSMENT i.e. without enh
Page 137 and 138: Conversion factors for laboratory a
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EFFECTS ASSESSMENT • relative sen
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EFFECTS ASSESSMENT Earthworms are a
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MARINE RISK ASSESSMENT environment
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MARINE RISK ASSESSMENT of equal rel
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4.2.3.3 Marine biodegradation simul
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MARINE RISK ASSESSMENT In addition
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Explanation of symbols MARINE RISK
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MARINE RISK ASSESSMENT evaluate the
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MARINE RISK ASSESSMENT marine water
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MARINE RISK ASSESSMENT The addition
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MARINE RISK ASSESSMENT Statistical
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MARINE RISK ASSESSMENT sediment, fo
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Table 27 Assessment factors for der
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Table 28 continued Acute and chroni
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MARINE RISK ASSESSMENT of different
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MARINE RISK ASSESSMENT • a measur
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MARINE RISK ASSESSMENT b. the conce
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MARINE RISK ASSESSMENT mechanisms s
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MARINE RISK ASSESSMENT The use of t
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4.4.4.2 Assessment of measured BCF
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MARINE RISK ASSESSMENT required to
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Table 33 Overview of PEC/PNEC ratio
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RISK CHARACTERISATION If a refineme
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Classified dangerous to the Environ
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RISK CHARACTERISATION eaters. This
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6 TESTING STRATEGIES 6.1 INTRODUCTI
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TESTING STRATEGIES Performance of a
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TESTING STRATEGIES Care must be tak
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Algal testing Algae toxicity test (
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TESTING STRATEGIES • long-term te
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Microbial assays TESTING STRATEGIES
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TESTING STRATEGIES A soil bioassay
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REFERENCES Brandes LJ, den Hollande
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REFERENCES IPCS (2000). Framework f
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REFERENCES OECD (1984f). Activated
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REFERENCES Pack S. (1993). A review
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REFERENCES US EPA (1996). Whole Sed
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APPENDIX I volume imported in the E
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APPENDIX I MC IV “Wide dispersive
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APPENDIX I 210 Stage Main category
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APPENDIX I the number of days over
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APPENDIX I Stage Main category Ia I
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APPENDIX I manufacturing of motor c
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APPENDIX I 1. extension of the tabl
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APPENDIX I 220 A-tables Estimates f
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APPENDIX I PRIVATE USE Not applicab
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APPENDIX I IC = 3: CHEMICAL INDUSTR
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APPENDIX I IC = 5: PERSONAL /DOMEST
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APPENDIX I Table A4.1 continued Com
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APPENDIX I IC = 7: LEATHER PROCESSI
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APPENDIX I IC = 9: MINERAL OIL AND
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APPENDIX I WASTE TREATMENT Table A5
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APPENDIX I For the emission factors
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APPENDIX I INDUSTRIAL USE Table A3.
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APPENDIX I INDUSTRIAL USE Table A3.
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APPENDIX I PRIVATE USE Table A4.5 C
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APPENDIX I PRIVATE USE Table A3.16
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APPENDIX I 246 B-tables Estimates f
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APPENDIX I FORMULATION Table B2.2 f
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APPENDIX I IC = 3: CHEMICAL INDUSTR
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APPENDIX I IC = 5: PERSONAL/DOMESTI
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APPENDIX I IC = 7: LEATHER PROCESSI
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APPENDIX I IC = 9: MINERAL OIL AND
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APPENDIX I IC = 11: POLYMERS INDUST
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APPENDIX I IC =13: TEXTILE PROCESSI
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APPENDIX I IC = 16: ENGINEERING IND
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APPENDIX I Appendix I-a: List of sy
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APPENDIX I No. Use Category No. Fun
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APPENDIX I Appendix I-b: List of sy
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APPENDIX I 290 Organic intermediate
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APPENDIX I Other IC/UC combinations
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APPENDIX II Appendix II Fate of che
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APPENDIX II b) Inherent biodegradab
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APPENDIX II log H % removal -4 -3 -
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APPENDIX III Appendix III Evaluatio
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APPENDIX III Field studies In gener
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APPENDIX IV together the mentioned
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290 Table 1 Selected soil test meth
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292 Table 1 continued Selected soil
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298 Table 1 Selected freshwater sed
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APPENDIX VII Appendix VII Toxicity
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APPENDIX VIII collection), and that
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APPENDIX VIII chemicals (see Sectio
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APPENDIX VIII Multimedia fate model
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APPENDIX VIII Monitoring data Metal
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APPENDIX VIII homeostatic regulatio
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APPENDIX IX based on the proportion
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APPENDIX IX Definition of “blocks
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APPENDIX IX these “blocks” will
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APPENDIX IX and PNECs for the “bl
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APPENDIX XI Appendix XI Environment
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APPENDIX XII Appendix XII Connectio
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APPENDIX XII +40% compared to 1992.
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APPENDIX XIII other substance is be
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APPENDIX XIV Taxonomic group No. of
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