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Developments in Ceramic Materials Research

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Model<strong>in</strong>g of Thermal Transport <strong>in</strong> <strong>Ceramic</strong>s Matrix Composites 177<br />

ceramic, multiple <strong>in</strong>filtrations are necessary to obta<strong>in</strong> an acceptable density of the composite.<br />

Polymeric precursors for ceramic matrices permits the usage of conventional polymer<br />

composite fabrication technology that is readily available and capitalise on processes used to<br />

make polymer matrix composites. Complex shape form<strong>in</strong>g and fabrication are possible and<br />

the fairly low process<strong>in</strong>g and pyrolys<strong>in</strong>g temperatures prevent fibre degradation and the<br />

formation of unsolicited reaction products at the fibre/matrix <strong>in</strong>terface.<br />

Figure 1. Schematic diagram of the <strong>in</strong>filtration technique.<br />

2.2. Thermal Behaviour of CMCs<br />

The behaviour of composite materials is often sensitive to changes <strong>in</strong> temperature. Such<br />

trends are displayed due to the temperature-dependent response of the matrix to an applied<br />

load. Also, alterations <strong>in</strong> temperature can <strong>in</strong>duce <strong>in</strong>ternal stresses because of a differential<br />

thermal contraction and expansion. These stresses ultimately affect the thermal expansion of<br />

the composite. Furthermore, thermal gradients are especially deleterious to CMCs as they<br />

possess relatively lower thermal diffusivities and are <strong>in</strong>herently heterogeneous. A thermal<br />

gradient is <strong>in</strong>versely related to thermal diffusivity (α) of a material, which is <strong>in</strong> turn related to<br />

thermal conductivity (k), specific heat (Cp) and density (ρ) of the material [2] as:<br />

(1)

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