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Developments in Ceramic Materials Research

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Optical Fluoride and Oxysulfide <strong>Ceramic</strong>s: Preparation and Characterization 69<br />

Fluorescence, a.u.<br />

1.0<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

λ, nm<br />

CaF 2 :Er 3+ ceramics<br />

1% 5% 5%<br />

T=300 K<br />

4 I11/2 --> 4 I 15/2<br />

0.0<br />

950 960 970 980 990 1000 1010 1020 1030 1040<br />

Figure 14. Normalized fluorescence spectra of the CaF 2: Er 3+ ceramic samples measured at the 4 I 11/2 →<br />

4 I15/2 transition with different concentration of the Er 3+ ion at room temperature: CaF 2: Er 3+ (1%) – grey<br />

curve (В(2)2-06 sample) - 1, CaF2: Er 3+ (5%) – black curve (B(2)39-05 sample) - 2, CaF 2: Er 3+ (5%) –<br />

dark grey curve (В(1)3-06 sample) - 3.<br />

Fluorescence, a.u.<br />

1.0<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

1<br />

0.0<br />

950 960 970 980 990 1000 1010 1020 1030 1040<br />

λ, nm<br />

2<br />

3<br />

ErF 3 raw material<br />

for samples with 06 <strong>in</strong>dex<br />

T=300 K<br />

4 I11/2 --> 4 I 15/2<br />

Figure 15. Normalized fluorescence spectra of the ErF 3 precursor used for sample preparation with 06<br />

<strong>in</strong>dex measured at room temperature.

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