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RESEARCH<br />

Fig. 22: Influence of casting speed on grain refinement with AlTiB master alloys<br />

Fig. 23: Influence of casting speed on grain<br />

refinement with AlTiC master alloys<br />

rameter for DC casting is the casting<br />

speed. Mo<strong>de</strong>rn DC casting systems<br />

for extrusion ingots make high casting<br />

speeds possible. These are only<br />

achievable because efficient grain<br />

refiners comprising AlTiB master alloys<br />

are available. Through grain refinement,<br />

the occurrence of hot and<br />

cold cracking, which becomes more<br />

likely with increasing casting speeds,<br />

can be effectively offset. Higher casting<br />

speeds not only increase the occurrence<br />

of cracks but also the formation<br />

of columnar crystals in the<br />

cast structure of the ingots. This is<br />

shown in Figs. 22 and 23 for 157 mm<br />

diameter billets. These figures also illustrates<br />

the effect of different types,<br />

and varying amounts, of grain refining<br />

master alloys [29]. It can be clearly<br />

seen that the formation of columnar<br />

crystals are enhanced by increasing<br />

casting temperatures. It is also evi<strong>de</strong>nt<br />

that AlTiC master alloys are, as in the<br />

case of casting temperature, sensitive<br />

to an increase in casting speed. It can<br />

be assumed that the influence of increased<br />

casting speed can be traced<br />

back to an increase in melt turbulence<br />

in the ingot pool and the temperature<br />

gradient in the melt ahead of the solidification<br />

front.<br />

Thus, it is clear that an increase in<br />

the casting speed necessitates an increase<br />

in the amount of grain refiner<br />

in or<strong>de</strong>r to achieve a fully equiaxed<br />

grain structure. It also shows that, in<br />

future mould <strong>de</strong>velopment, engineering<br />

a system that provi<strong>de</strong>s an environment<br />

that encourages the formation<br />

of an equiaxed grain structure will be<br />

necessary in or<strong>de</strong>r to achieve higher<br />

casting speeds.<br />

In addition to the process parameters<br />

discussed above, the as-cast<br />

structure of a DC cast ingot is also influenced<br />

by the flow of the melt into<br />

the mould, and the resulting fluid flow<br />

field in the liquid pool of the ingot.<br />

Particularly in the higher temperature<br />

gradient range, there is a risk of columnar<br />

structure formation, notably in the<br />

form of feathery crystals. An example<br />

is shown in Fig. 24 for the level pour<br />

casting of extrusion billets [30]. It can<br />

be seen that columnar crystals form<br />

opposite the mould gate in the area<br />

where the highest temperature gradients<br />

occur during casting as <strong>de</strong>monstrated<br />

in the simulation in Fig. 25.<br />

The same negative impact of high temperature<br />

gradients also exists for the<br />

DC casting of rolling ingots, as shown<br />

in Fig. 26, were the molten metal is fed<br />

by means of a nozzle and distributor.<br />

In the susceptible area, the requirements<br />

for improved grain refinement<br />

increased, which in turn can lead to<br />

excessive amounts of grain refiner being<br />

ad<strong>de</strong>d. In mould <strong>de</strong>velopment, e<strong>special</strong>ly<br />

where higher casting speeds<br />

are <strong>de</strong>sired, optimisation of the melt<br />

feeding system must be effected in<br />

or<strong>de</strong>r to achieve a flow distribution<br />

in the ingot pool which favours grain<br />

refinement. This, however, must also<br />

take place in conjunction with the<br />

optimisation of the melt temperature<br />

at the mould gate and smoothing the<br />

temperature distribution in multiple<br />

ingot casting stations.<br />

As reported in numerous other<br />

places, grain refinement with TiB 2<br />

is mainly influenced by the concentration<br />

and the type of alloying elements.<br />

Correspondingly, the “growth<br />

restriction factor” values show that<br />

the different alloying elements have<br />

Fig. 24: Feathery crystal formation opposite<br />

to the pouring gate for unsufficient grain<br />

refinement<br />

Fig. 25: Velocities and temperatures at a<br />

horizontal cross section, referring to Fig. 24<br />

76 ALUMINIUM · 6/2007

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