2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international

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In specimen L01-01-1 motor oil M20-V2 sampled from the area of industrial and construction dumps near the settlement of Nagurskoe, polychlorinated biphenyls were revealed in trace quantities. The content of all analyzed heavy metals does not exceed 0.1 mg/kg that is unsignificant and cannot be a source of pollution with this group of pollutant. In oil product specimens collected from in the area of fuel and lubricant storage facility in the Severnaya Bay: L02-01-1, L02-01-2, L02-02-4, L02-02-5 motor oil M20-V2 the total 15 PCB does not exceed the lower limit of metrological certified range for the used analysis method. In transmission and condenser oil specimens sampled from the surveyed area 15 PCB content was from 0.016 up to 0.45 mass percents. The maximum PCB content - 4,5 g/kg of oil product was reavealed in transmission oil specimen of viscosity class 18 TAp-15V L02-09-17, (site 252, stack of 200-L drums). A higher PCB content is typical for the surveyed area; the maximum one (up to 7.07 PC units point S02-05) was revealed near the object m254 (accumulation of drums). The maximum HM content in the specimens under study does not exceed 1 mg/kg for specific elements which is a norm for those oil products. In oil product specimens sampled from the area of the abandoned polar station: L03-12-21, L03-12-22 transmission oil of viscosity class 18 TAp-15V and L03-13-23 industrial oil IMSp-46, polychlorinated biphenyls were revealed in trace quantities. In specimen L03-10-18 - mix of spent oil products, the total 15 PCB was 2,3 mass percents (23 g/kg) (site280, a 1.5-L separate metal drum; in specimens L03-11-19 and L03-11-20 transmission oil of viscosity class 18 TAp-15V the total 15 PCB was 0,22 mass percents (2,2 g/kg) and 0,32 mass percents (3,2 g/kg) (site 273 stack of 200-L drums). For the same surveyed area, a relatively high PCB content in soil up to 0.53 PC units point S03-08 is typical. The maximum HM content in the specimens under study does not exceed 1 mg/kg for specific elements which is a norm for those oil products. In specimens L04-01-1 and L04-02-2, transformer oil TSp-14gip from the territory of the radar station commandant s office, the total 15 PCB does not exceed the lower limit of metrological certified range for the used analysis method. The maximum HM content in the specimens under study does not exceed 1 mg/kg for specific elements which is a norm for those oil products. In oil product specimens sampled from the area of radar station: L05-01-1, L05-02-2 - transmission oil of viscosity class 18 TAp-15V, the total 15 PCB was 1,94 mg/kg (site 329 stack of 200-L drums) and 4,3 mg/kg (site 162 a separate drum) respectively. In specimens L05-03-3, L05-03-4 and L05- 03-5.1 sulphuric-acid refining condenser oil according to GOST 5775-85, the total 15 PCB was 0,0005, 0,02 and 0,004 mass percents. Among the specimens collected in the area, the maximum 15 PCB congeners - 20.2 mg/kg of oil product was revealed in specimen L05-03-4 sulphuric-acid refining condenser oil according to GOST 5775-85, site 164 (Condenser KBG-P). For the same surveyed area, a relatively high PCB content in soil up to 0.91 PC units is typical. The HM content in the specimens under study does not exceed 0.5 mg/kg for specific elements which is a norm for those oil products. FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project Development of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in the Arctic by the Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste 138
7. SUBSTANTIATION OF EXPERIMENTAL SITE SELECTION FOR CLEAN UP Materials based on the results of additional survey: - situational plans of the areas with a specified number and location of hazardous and other technological infrastructure elements (report sections 4.1-4.3); - identification of types and grades of oil products to be disposed based on laboratory testing methods and study of PCB and HM content in oils (report sections 5.2-5.5);- - it allows us to recommend the area in south-west part of fuel and lubricant storage facility in the Severnaya Bay near the object 203 (Stack of drums) as the main experimental site, which contains a significant number of drums with transmission oil containing PCB in amount exceeding 1 g per 1 kg of oil product. The total numer of drums in the stack is estimated as 1600. The area in west part of the storage facility can be recommended as an additional site, near objects 178, 249, 250, 252, where a significant number of drums with transmission oil containing PCB amounting for 4.5 1 g per 1 kg of oil product were revealed. Taking into account an experimental nature of work and limited funding, the clean up of other surveyed areas is not expedient at this stage due to a significantly less number of accumulations and stacks of drums with fuel and lubricant, absence of technical liquids having significant PCB content, level of soil pollution and a larger scope of work needed to remove drums and other equipment from the ice. Location of the objects containing oil products with high PCB content and level of soil pollution in the location of especially hazardous technological infrastructure elements are shown in schematic mapd (Figures 7.1-7.5) FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project Development of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in the Arctic by the Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste 139
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APPROVED Project Coordinator ______
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LIST OF CONTENT 1 INTRODUCTION 7 2
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10 DEVELOPMENT OF TECHMOLOGICAL PRO
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1. INTRODUCTION This report contain
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2. ADDITIONAL SURVEY FOR SELECTING
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Table 2.2.1 Field work schedule Dat
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Picture 2.2.3 Tracked vehicle in th
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Picture 2.2.7 Accumulation of drums
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Picture 2.2.11 Wooden drum with tec
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Picture 2.2.15 Oil spill on the lan
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Picture 2.2.19 Diesel building (sit
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Picture 2.2.23 Accumulation of drum
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Picture 2.2.27 Destroyed building,
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Picture 2.2.31 PCB-containing insid
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Picture 2.2.35 Transformers, Antenn
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3 ADDITIONAL SURVEY FOR SELECTING A
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Map symbols Area boundaries Samplin
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Picture3.1.6 Schematic map of sampl
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Area Point Table 3.1.2 Location of
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Continuation of Table 3.1.2 1 2 3 4
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Table 3.1.3 gives the number of dig
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Territory of the radar station comm
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Picture 3.1.4 Accumulation of drums
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Picture 3.1.8 Radar station equipme
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Picture 3.1.12 High-voltage current
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Picture 3.1.16 Chemical agent pack
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wooden gantries; power lines; hea
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Figure4.1.1 Situational plan of the
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No. Number of the site on situation
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Figure4.2.1 Situational plan of of
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4.2.2 Territory of the abandoned po
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39 295 Territory littered with meta
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5 ASSESSMENT OF SOIL AND GROUND POL
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introduction of a methyl substituen
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The study of heavy metal content le
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When soil is contaminated with one
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toxic waste. In this case, the remo
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Point no. Soil type Pollution signs
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Table 5.2.6 Concentration of pollut
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Total 15 PCB mg/kg 0.00016 0.08957
Page 87 and 88: Figure 5.2.1 Spatial characteristic
Page 89 and 90: 5.4 Severnaya Bay 5.4.1 Area of fue
Page 91 and 92: Parameter Unit Concentration Concen
Page 97 and 98: Parameter Unit Table 5.2.8 Content
Page 99 and 100: On average content of volatile arom
Page 103 and 104: Table 5.2.9 Content of pollutants i
Page 109 and 110: Table 5.2.10 Content of pollutants
Page 113 and 114: 6. RESULTS OF THE LABORATORY STUDY
Page 115 and 116: metal drums (4 pcs) drum without la
Page 117 and 118: TU 38.1011007-84. Process Oil IMSi-
Page 119 and 120: Continuation of Table 6.1.2 Paramet
Page 121 and 122: 6.1.2 Severnaya Bay area Area of fu
Page 123 and 124: Parameter to bedetermined, unit of
Page 125 and 126: Territory of the abandoned polar st
Page 127 and 128: 6.1.3. Area of the abandoned air-de
Page 129 and 130: Area of radar station Parameter to
Page 131 and 132: Parameter to bedetermined, unit of
Page 133 and 134: No. of site Table 6.2.3 PCB content
Page 135 and 136: No. of site No. of sample Table 6.2
Page 137: No. of site No. of samp Grade (type
Page 141 and 142: Figure 7.2 Location of the objects
Page 143 and 144: Figure7.4 Location of the objects c
Page 145 and 146: 8. DETERMINATION OF INNOVATIVE TECH
Page 147 and 148: The decontamination of condensers w
Page 149 and 150: unidentified substances occurs with
Page 151 and 152: places. In this connection, with re
Page 153 and 154: is determined whether a waste is fu
Page 155 and 156: 9. DEVELOPMENT OF TECHMOLOGICAL PRO
Page 157 and 158: Amount reagent is determined by sta
Page 159 and 160: hazardous waste only. The principle
Page 161 and 162: Drum with removed is placed to a sp
Page 163 and 164: In accordance with the submitted sc
Page 165 and 166: wash water should be composed of at
Page 167 and 168: Solid-waste recycling module is des
Page 169 and 170: hydroxides and hydroxy. When expose
Page 171 and 172: In accordance with the submitted bl
Page 173 and 174: 11. DEVELOPMENT OF TECHMOLOGICAL PR
Page 175 and 176: in question should move to a pre-de
Page 177 and 178: instrumentation that enable manufac
Page 179 and 180: Air Barrles Methylene clorinated MC
Page 181 and 182: Module of deactivation of liquid wa
Page 183 and 184: This module is designed for the pro
Page 185 and 186: drain valve is usually not installe
Page 187 and 188: 11.3.3.2 Stage of washing of transf
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with regeneration PSB to burn 8
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the cavity in the afterburner (4).
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Assembly of equipment off-gas clean
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The composition of this line includ
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sovtol can be recycled; recycling t
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Therefore, the preservation of indu
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13. SELECTION OF INDUSTRIAL SITE AN
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13.2. Selection of industrial site
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access to technological equipment a
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Figure 13.5. Process module Figure
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14. EXPERIMENTAL TESTING OF MODERN
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12. Filing drums for disposal in Ar
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Figure 14.1 Placement of burnt drum
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Figure 14.4 Pressing result with ch
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Figure 14.7. Drum broaching using a
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Figure14.10. Drum compacting Figure
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14.2 Experimental handling of waste
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Figure 14.13. Marking of PCB-contai
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14.3 Control sampling on-site and c
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combustion. The results of the anal
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22.08.10. 08:00 020° 17:00 340° 4
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case, it becomes possible to utiliz
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a fairly short time away, drained,
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18. REFERENCES 1 .., .., .. , ..
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31 .., .., .., .., .., .., .
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», « »/ . : , 2009. 61 .
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