2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
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Available information on the technical and economic feasibility of the technology of high<br />
temperature oxidation in terms of the main economic indicators i.e. the cost of manufacturing of<br />
the installation and the cost of processing of 1 ton of PCB have shown the advantages of using<br />
cyclone reactors [52].<br />
However, the available information on this technology shows the expediency of its application in<br />
large-scale elimination of PCB in the steady-state conditions. Approximate cost of a stationary<br />
installation capable to process 1000 tons of PCB per year will be 653,000 U.S. dollars with an<br />
estimated cost of processing equal to 320 USD per 1 ton of PCB.<br />
Moreover, there is structural complexity, high cost of mobile version, as well as a number of<br />
technical difficulties related to blockage of nozzles and impossibility to operate at low<br />
temperatures.<br />
Among similar methods of high-temperature oxidation, the method of burning up toxic waste in<br />
a specially designed furnace can be distinguished [64], in which the combustion process is a<br />
combination of two consecutive phases:<br />
conversion of a hazardous substance into the gas phase;<br />
combustion itself of vapors of dangerous substances in the furnace and their subsequent<br />
reburning and end gas cleaning.<br />
An experimental study of this method of disposal of hazardous waste, including the example of<br />
the elimination of pesticides [65] has shown prospectivity of its implementation for solving the<br />
problem of the elimination of POPs.<br />
In addition, work in this field is being carried out within the framework of experimental<br />
development "Agriculture", funded from the federal budget for the federal target program "The<br />
National System of Chemical and Biological Security of the Russian Federation (2009 -<br />
2013) . In this regard, the reworking of technologies addressed to the disposal of liquid PCB<br />
waste and spent oil can be significantly reduced compared to the installation of a cyclone<br />
furnace.<br />
8.1.4 Substantiation of technology of elimination of spent technical liquids and oils as applied to<br />
Alexandra Island<br />
Particularities of the pollution on the island are the presence of hazardous technical liquids in<br />
different containers and locations.<br />
So, according to preliminary inventory in 2008, spent oils M-20V2, TAP-15V, TSC - 14gip,<br />
IMSp 46 are in 200-L drums. According the quantitative chemical analysis, PCB content does<br />
not exceed trace amounts in most drums.<br />
However, the PCB content in a number of drums with oil TAP-15V and TSC - 14gip reaches<br />
about 4.3 mg /kg. The main PCB content (more than 20.2 mg / kg) is found in sulphuric-acid<br />
refining condenser oil, in condensers KBG-P and transformers at the destroyed storage facility<br />
and transformer dump.<br />
Additional studies in September 2010, showed that in addition to information received in recent<br />
years on the location and quality of technical liquids a secondary detection and identification<br />
occurs of hazardous PCB-containing wastes. There were found about eight new PCB sources,<br />
located within the mapped areas.<br />
Thus, spent technical liquidss, including those containing PCB, may be located in different<br />
FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project Development<br />
of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in the Arctic by the<br />
Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste<br />
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