03.03.2013 Views

2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international

2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international

2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

The decontamination of condensers with subsequent recycling of metals involves washing of<br />

condensers, their dismantling, second wash of their cases and core. After this, the cases<br />

containing less than 50 ppm, are sent for disposal, as the core is crushed and additionally washed<br />

from PCB, usually with a hot solvent. Cleaned and crushed aluminum core contains less than 50<br />

ppm of PCB, and is also sent for disposal. The cost of processing of one ton of condensers is<br />

about $ 2200 U.S.<br />

The technologies of condenser deactivation existing in Russia are also divided into two groups<br />

by their implementation. The first one is combustion methods, which use [52]:<br />

explosion of packaged explosive, containing chemically neutralized PCB in the particles of<br />

crushed condensers;<br />

fuel in the high-powdered mixture of filtration combustion (PSFG);<br />

bubble furnace with afterburner systems and neutralization of waste gases.<br />

The second one is condenser burning-in.<br />

The examination of technical and environmental characteristics of Russian methods of disposal<br />

of PCB-containing condensers showed that technology with using explosion, tested on an<br />

industrial scale and technology using PSFG fuel tested on pilot scale for other waste are quite<br />

simple. However, for environmental reasons, they can not be recommended for further<br />

examination, since it does not allow us to guarantee the absence of emissions of both<br />

undecomposed PCB and dioxins. The cost of creating a single unit with explosion of 500 tons of<br />

condensers per year is 2 million dollars and the cost of the elimination of one ton of condensers<br />

is 1350 U.S. dollars. The cost of creating a plant using PSFG fuel is 70000 U.S. dollars and the<br />

cost of processing one ton of condensers is from 4000 to 6000 U.S. dollars.<br />

Tested in industrial conditions on Metallurgical Complex the technology of decontamination of<br />

condensers by their calcination and subsequent disposal of metal also cannot be recommended<br />

for further replication in Russia, because the completeness of the transformation of PCB and<br />

dioxins in waste gases is unknown.<br />

Upon the review of these technologies from a technical, environmental and economic point<br />

of view, the most appropriate technology is that using bubbling melting furnace with<br />

afterburner systems and neutralization of waste gases.<br />

Despite the absence of a full-scale testing, this technology should meet the European<br />

requirements for the degree of PCB conversion - no less than 99.9999% and the content of<br />

dioxins in flue gases - less than 0.1 ng / m 3 , which is provided by the technological conditions of<br />

the process.<br />

The cost of such an installation capacity of 4000 tons of condensers in the year amounted to<br />

1,6 million U.S. and the cost of processing one ton of condensers to be about 1000 U.S.dollars.<br />

8.1.3 Analysis of technologies of PCB and spent oil elimination<br />

Existing in the Russian Federation, methods and technologies of neutralization of PCB and spent<br />

oils, by analogy with the global practice can be divided into three options for their<br />

implementation [52]:<br />

burial of waste in accordance with applicable rules, regulations and security measures to protect<br />

the environment;<br />

FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project Development<br />

of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in the Arctic by the<br />

Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste<br />

147

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!