2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
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The decontamination of condensers with subsequent recycling of metals involves washing of<br />
condensers, their dismantling, second wash of their cases and core. After this, the cases<br />
containing less than 50 ppm, are sent for disposal, as the core is crushed and additionally washed<br />
from PCB, usually with a hot solvent. Cleaned and crushed aluminum core contains less than 50<br />
ppm of PCB, and is also sent for disposal. The cost of processing of one ton of condensers is<br />
about $ 2200 U.S.<br />
The technologies of condenser deactivation existing in Russia are also divided into two groups<br />
by their implementation. The first one is combustion methods, which use [52]:<br />
explosion of packaged explosive, containing chemically neutralized PCB in the particles of<br />
crushed condensers;<br />
fuel in the high-powdered mixture of filtration combustion (PSFG);<br />
bubble furnace with afterburner systems and neutralization of waste gases.<br />
The second one is condenser burning-in.<br />
The examination of technical and environmental characteristics of Russian methods of disposal<br />
of PCB-containing condensers showed that technology with using explosion, tested on an<br />
industrial scale and technology using PSFG fuel tested on pilot scale for other waste are quite<br />
simple. However, for environmental reasons, they can not be recommended for further<br />
examination, since it does not allow us to guarantee the absence of emissions of both<br />
undecomposed PCB and dioxins. The cost of creating a single unit with explosion of 500 tons of<br />
condensers per year is 2 million dollars and the cost of the elimination of one ton of condensers<br />
is 1350 U.S. dollars. The cost of creating a plant using PSFG fuel is 70000 U.S. dollars and the<br />
cost of processing one ton of condensers is from 4000 to 6000 U.S. dollars.<br />
Tested in industrial conditions on Metallurgical Complex the technology of decontamination of<br />
condensers by their calcination and subsequent disposal of metal also cannot be recommended<br />
for further replication in Russia, because the completeness of the transformation of PCB and<br />
dioxins in waste gases is unknown.<br />
Upon the review of these technologies from a technical, environmental and economic point<br />
of view, the most appropriate technology is that using bubbling melting furnace with<br />
afterburner systems and neutralization of waste gases.<br />
Despite the absence of a full-scale testing, this technology should meet the European<br />
requirements for the degree of PCB conversion - no less than 99.9999% and the content of<br />
dioxins in flue gases - less than 0.1 ng / m 3 , which is provided by the technological conditions of<br />
the process.<br />
The cost of such an installation capacity of 4000 tons of condensers in the year amounted to<br />
1,6 million U.S. and the cost of processing one ton of condensers to be about 1000 U.S.dollars.<br />
8.1.3 Analysis of technologies of PCB and spent oil elimination<br />
Existing in the Russian Federation, methods and technologies of neutralization of PCB and spent<br />
oils, by analogy with the global practice can be divided into three options for their<br />
implementation [52]:<br />
burial of waste in accordance with applicable rules, regulations and security measures to protect<br />
the environment;<br />
FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project Development<br />
of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in the Arctic by the<br />
Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste<br />
147