2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
2 ОРГАНИЗАЦИЯ И МЕТОДИКА РАБОТ - Courrier international
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The composition of this line includes plasma-optical camera and monitoring unit off-gas with<br />
an actuating device switch thread. In normal operation of the plant gases through the unit for<br />
monitoring and flow-switching device is discharged into the atmosphere.<br />
When issuing a unit signal for excess levels of incomplete combustion produces a signal to<br />
the actuator to switch the direction of flow and the additional stage of gas purification.<br />
After the normalization process of gas purification in the absence of a signal from the<br />
monitoring unit flue gas by switching the flow to discharge into the atmosphere.<br />
All the techno-economic and environmental performance of the disposal of persistent organic<br />
pollutants were confirmed in a laboratory setting using a full-scale specimens of PCBcontaining<br />
wastes.<br />
11.3.4.2 Stage of PCB-waste sulphonation with further neutraliztion by salt-forming agent.<br />
Select the direction of the third stage of technology, as mentioned above, determined by the<br />
concentration of PCB-containing liquids. When the concentration of active ingredient of PCB<br />
for more than 90% used mobile installation, which uses technology oleum sulfonation<br />
followed by treatment with salt-forming agent (method sovtol patent RU 2341509 C1) [52].<br />
The process involves sulfonation with oleum excess sovtol relatively oleum at a temperature<br />
of 100-180 ° C and subsequent neutralization of the salt-forming agents - triethanolamine.<br />
Sulfonation reaction is carried out at a molar ratio sovtol: oleum of 1: (from 0,55 up to less<br />
than 0,6), after neutralization of the reaction mixture was extracted with a solvent free sovtol -<br />
tolueneom, whose amount is equal to 0,75% of the initial mass sovtol after then extracted with<br />
toluene sovtol regenerate, bottoms - sovtol return to the stage of sulfonation, and toluene on<br />
the stage of extraction.<br />
Block diagram of sulfonation of PCB wastes, followed by neutralization salt-forming agent is<br />
shown in Figure 11.3.7.<br />
FINAL REPORT for Contract No. CS-NPA-Arctic-13/2009 of December 01, 2009 within the framework of pilot project<br />
Development of Technology of clean up of the area of Decommissioned Sites of The Russian Federation Ministry of Defense in<br />
the Arctic by the Example of Alexanra Island of Franz Josef Land Archipelago from Hazardous Waste<br />
195