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ÏÐÎÃÐÅÑÑ Â ÎÁËÀÑÒÈ ÊÀÒÀËÈÒÈ×ÅÑÊÎÉ ÏÎËÈÌÅÐÈÇÀÖÈÈ È ÑÎÏÎËÈÌÅÐÈÇÀÖÈÈ ÝÒÈËÅÍÀ Èâàí÷åâ Ñ.Ñ. Ñàíêò-Ïåòåðáóðãñêèé ôèëèàë Èíñòèòóòà êàòàëèçà èì. Ã.Ê. Áîðåñêîâà ÑÎ ÐÀÍ, Ñàíêò-Ïåòåðáóðã E-mail: Ivanchev@SM2270.spb.edu Àíàëèçèðóþòñÿ îñíîâíûå ýòàïû è íàó÷íûå îñíîâû òåõíîëîãè÷åñêèõ ðåøåíèé ïðîìûøëåííîé ðåàëèçàöèè ïðîöåññà ïîëèìåðèçàöèè è ñîïîëèìåðèçàöèè ýòèëåíà – íàèáîëåå êðóïíîòîííàæíîãî ïëàñòèêà øèðîêîãî ïðèìåíåíèÿ. Îòìå÷àåòñÿ, ÷òî âñå ýòàïû ñîâåðøåíñòâîâàíèÿ òåõíîëîãèè ïîëèìåðèçàöèè ñâÿçàíû ñ ñîçäàíèåì íîâûõ òèïîâ êàòàëèòè÷åñêèõ ñèñòåì ïîëèìåðèçàöèè è ñîïîëèìåðèçàöèè. Îñîáîå âíèìàíèå óäåëÿåòñÿ ñîâðåìåííûì äîñòèæåíèÿì â îáëàñòè ñîçäàíèÿ íîâûõ êëàññîâ ïîñòìåòàëëîöåíîâûõ êàòàëèçàòîðîâ íà îñíîâå áèñèìèííûõ è áèñ(èìèíî)ïèðèäèíîâûõ êîìïëåêñîâ òÿæåëûõ ìåòàëëîâ, âïåðâûå ïîëó÷åííûõ â ñåðåäèíå 90-õ ãã. ïðîøëîãî ñòîëåòèÿ, à òàêæå ôåíîêñè-èìèííûõ êîìïëåêñîâ ìåòàëëîâ IV ãðóïïû, ðàçðàáîòàííûõ ñðàâíèòåëüíî íåäàâíî. Ðàññìîòðåíû ðåçóëüòàòû èññëåäîâàíèé íîâûõ ïîñòìåòàëëîöåíîâûõ êàòàëèòè÷åñêèõ ñèñòåì, âûïîëíåííûõ â Ñàíêò-Ïåòåðáóðãñêîì ôèëèàëå Èíñòèòóòà êàòàëèçà ÑÎ ÐÀÍ â ïîñëåäíèå ãîäû. 17
Page 1 and 2: Èíñòèòóò êàòàëèçà
Page 3 and 4: Îðãàíèçàòîðû êîíôå
Page 6 and 7: SINGLE SITE CATALYSTS - IDEAL MODEL
Page 8 and 9: ÑÒÀÁÈËÈÇÈÐÎÂÀÍÍÛÅ
Page 10 and 11: ÈÇÓ×ÅÍÈÅ ÌÅÕÀÍÈÇÌÎ
Page 12 and 13: Ñðàâíåíèå äèíàìèêè
Page 14 and 15: ÐÎËÜ ÍÎÑÈÒÅËÅÉ Â ÔÎ
Page 16 and 17: ÒÐÈÈÇÎÁÓÒÈËÀËÞÌÈÍ
Page 20: ÓÑÒÍÛÅ ÄÎÊËÀÄÛ Ñåê
Page 23 and 24: most abundant form of tin is Sn-Pt
Page 25 and 26: whereas a Pd(II)/NO - n catalytic s
Page 27 and 28: Èñïîëüçîâàíèå ïîëó
Page 29 and 30: ÌÅÕÀÍÈÇÌ ÔÎÐÌÈÐÎÂÀ
Page 31 and 32: ÌÎËÅÊÓËßÐÍÛÉ ÄÈÇÀÉ
Page 33 and 34: ñ÷åò ñïåêàíèÿ íàèì
Page 35 and 36: è Ru, íàíåñåííûå íà ó
Page 37 and 38: ÐÀÑÏÐÅÄÅËÅÍÈÅ ÌÅÄÈ
Page 39 and 40: èîíû ëîêàëèçóþòñÿ
Page 41 and 42: ÔÎÐÌÈÐÎÂÀÍÈÅ ÀÊÒÈÂ
Page 43 and 44: ÑÈÍÒÅÇ ÊÀÒÀËÈÇÀÒÎÐ
Page 45 and 46: ÑÈÍÒÅÇ, ÈÑÑËÅÄÎÂÀÍ
Page 47 and 48: ÏÎËÈÌÅÐ-ÎÏÎÑÐÅÄÎÂÀ
Page 49 and 50: Îñíîâíûå ïîäõîäû ê
Page 51 and 52: Ðåãåíåðàöèÿ âîññòà
Page 53 and 54: ïðåäåëüíî äèñïåðñí
Page 55 and 56: ÏÐÎÈÇÂÎÄÑÒÂÎ ÌÎÒÎÐ
Page 57 and 58: Â öåëîì, îòíîñèòåëü
Page 59 and 60: Ñîñòàâ ãàçîâîãî ïð
Page 61 and 62: ïîñëåäóþùèìè ñóøêî
Page 63 and 64: Ïðåâðàùåíèå í-àëêà
Page 65 and 66: ÃÈÄÐÎÈÇÎÌÅÐÈÇÀÖÈß
Page 67 and 68: ÍÅÊÎÒÎÐÛÅ ÀÑÏÅÊÒÛ
Page 69 and 70:
Ïî ñòðóêòóðíûì õàð
Page 71 and 72:
Ïîêàçàíî, ÷òî ïðèðî
Page 73 and 74:
ÂËÈßÍÈÅ ÌÀÒÐÈÖÛ ÍÀ
Page 75 and 76:
ÑÒÎËÁ×ÀÒÛÅ ÃËÈÍÛ Â
Page 77 and 78:
Îáðàçåö Al-ÏÌ Zr-ÏÌ Ïî
Page 79 and 80:
Ãèäðîïðåâðàùåíèå ï
Page 81 and 82:
ÎÊÈÑËÈÒÅËÜÍÛÉ ÀÌÌÎ
Page 83 and 84:
ÍÈÇÊÎÒÅÌÏÅÐÀÒÓÐÍÎ
Page 85 and 86:
ÍÎÂÀß ÒÅÕÍÎËÎÃÈß Ê
Page 87 and 88:
ÏÐÎÌÎÒÈÐÎÂÀÍÍÛÉ ÕË
Page 89 and 90:
ÑÅËÅÊÒÈÂÍÛÉ ÊÀÒÀËÈ
Page 91 and 92:
ÑÎÏÎËÈÌÅÐÈÇÀÖÈß ÏÐ
Page 93 and 94:
ÍÀÏÐÀÂËÅÍÍÎÅ ÐÅÃÓË
Page 95 and 96:
ÍÎÂÛÅ ÐÅÀÊÖÈÈ ÄËß Õ
Page 97 and 98:
Áîëåå ãëóáîêîå êàð
Page 99 and 100:
Êîìïëåêñ (1) â êîìáè
Page 101 and 102:
100
Page 103 and 104:
Öåëüþ íàñòîÿùåé ðà
Page 105 and 106:
ÈÑÑËÅÄÎÂÀÍÈÅ ÏÐÎÖÅ
Page 107 and 108:
ÑÂÎÉÑÒÂÀ ÏÎÂÅÐÕÍÎÑ
Page 109 and 110:
ôîðìèàòà - 3*10 17 êîìï
Page 111 and 112:
ïîíèæåíèþ ïàðàìåòð
Page 113 and 114:
ÃÅÒÅÐÎÃÅÍÍÛÅ ÊÀÒÀË
Page 115 and 116:
Ñêîðîñòü Ðåàëüíûé
Page 117 and 118:
îðãàíè÷åñêèõ ñîëåé
Page 119 and 120:
ÑÈÍÒÅÇ È ÊÀÒÀËÈÒÈ×
Page 121 and 122:
èëè ïîëíîñòüþ îòñó
Page 123 and 124:
àëþìîïàëëàäèåâîãî
Page 125 and 126:
ÔÎÐÌÈÐÎÂÀÍÈÅ MoVTe ÎÊ
Page 127 and 128:
çàâèñèìîñòè îò ïðè
Page 129 and 130:
ÑÐÀÂÍÈÒÅËÜÍÎÅ ÈÇÓ×
Page 131 and 132:
ÍÎÂÛÉ ÏÎÄÕÎÄ Ê ÑÈÍÒ
Page 133 and 134:
ÑÎÏÎÑÒÀÂËÅÍÈÅ ÀÊÒÈ
Page 135 and 136:
Áóòàí. Â îòëè÷èå îò
Page 137 and 138:
Ïîêàçàíî, ÷òî äîáàâ
Page 139 and 140:
öèêëîãåêñàíà äî ñî
Page 141 and 142:
Íà èñõîäíîì îáðàçö
Page 143 and 144:
ÏÎÂÛØÅÍÈÅ ÀÊÒÈÂÍÎÑ
Page 145 and 146:
ÃÈÄÐÎÊÐÅÊÈÍÃ ÌÀÇÓÒ
Page 147 and 148:
ÊÎËÅÁÀÒÅËÜÍÎÅ ßÂËÅ
Page 149 and 150:
Êîíñòàíòà ðàâíîâåñ
Page 151 and 152:
Ðèñ. 2. Çàâèñèìîñòü
Page 153 and 154:
Òåñòèðîâàíèå êàòàë
Page 155 and 156:
Â àíàëîãè÷íûõ óñëî
Page 157 and 158:
Ru/C, Ir/C êàòàëèçàòîðà
Page 159 and 160:
òåìïåðàòóðàìè ïî ì
Page 161 and 162:
ñëîé êàòàëèçàòîðà
Page 163 and 164:
âåëè÷èíû êîíâåðñèè
Page 165 and 166:
ÑÅËÅÊÒÈÂÍÎÅ ÂÎÑÑÒÀ
Page 167 and 168:
ÏÎËÓ×ÅÍÈÅ ÆÈÄÊÎÃÎ
Page 169 and 170:
ÏÀÐÎ-ÓÃËÅÊÈÑËÎÒÍÛÉ
Page 171 and 172:
ÌÅÇÎÏÎÐÈÑÒÛÅ ÊÀÒÀË
Page 173 and 174:
ÂËÈßÍÈÅ ÄÀÂËÅÍÈß Í
Page 175 and 176:
ÀÊÒÈÂÍÎÑÒÜ ÌÎÄÈÔÈÖ
Page 177 and 178:
Ðåçóëüòàòû ïîçâîëÿ
Page 179 and 180:
Îïûòû ïðîâîäèëè íà
Page 181 and 182:
ÏÐÈÐÎÄÍÛÅ ÀËÞÌÎÑÈË
Page 183 and 184:
óãëåâîäîðîäîâ, â òî
Page 185 and 186:
ïèðîôîñôàòû êðåìíè
Page 187 and 188:
à) á) Îáùàÿ ñåðà, % ìà
Page 189 and 190:
íàáëþäàåòñÿ ñíèæåí
Page 191 and 192:
âàêóóìíîãî ãàçîéëÿ
Page 193 and 194:
ÐÀÇÐÀÁÎÒÊÀ ÍÎÂÎÃÎ
Page 195 and 196:
ÍÎÂÛÅ ÊÀÒÀËÈÇÀÒÎÐÛ
Page 197 and 198:
ÓÍÂ, ÏÝÌ, àäñîðáöèè
Page 199 and 200:
Â ëèòåðàòóðå âîïðî
Page 201 and 202:
ÎÊÑÈÃÅÍÈÐÎÂÀÍÈÅ Í-
Page 203 and 204:
ÎÊÈÑËÈÒÅËÜÍÀß ÏÎËÈ
Page 205 and 206:
ÂËÈßÍÈÅ ÏÐÈÐÎÄÛ ÍÎ
Page 207 and 208:
×ÈÑËÎ ÀÊÒÈÂÍÛÕ ÖÅÍ
Page 209 and 210:
ÎÄÍÎ- È ÄÂÓÕÊÎÌÏÎÍÅ
Page 211 and 212:
Br + N H R Pd[PBu t 3] 2 , K 3 PO 4
Page 213 and 214:
è ñòàöèîíàðíóþ àêò
Page 215 and 216:
âðåìÿ ãåòåðîãåíèçè
Page 217 and 218:
ìîëüíîå îòíîøåíèå M
Page 219 and 220:
ÈÊ ñïåêòðîñêîïèÿ ä
Page 221 and 222:
áûëè ïîëó÷åíû êðèñ
Page 223 and 224:
ÈÇÓ×ÅÍÈÅ ÏÐÎÖÅÑÑÎÂ
Page 225 and 226:
ÍÎÂÛÅ ÏÎÄÕÎÄÛ Ê ÏÎË
Page 227 and 228:
Ïðåäâàðèòåëüíàÿ îö
Page 229 and 230:
ÁÅËÀß Ëèëèÿ Àëåêñà
Page 231 and 232:
Å×ÅÂÑÊÈÉ Ãåííàäèé
Page 233 and 234:
ËÅÐÌÎÍÒÎÂ Àíàòîëèé
Page 235 and 236:
ÐÈØÈÍÀ Ëàóðà Àáðàì
Page 237 and 238:
ÙÓÊÈÍÀ Îëüãà Âèêòî
Page 239 and 240:
ÓÄ-I-2 ÓÄ-I-3 ÓÄ-I-4 ÓÄ-I-5
Page 241 and 242:
ÓÄ-II-16 Øèëèíà Ì.È., Á
Page 243 and 244:
CÄ-I-15 CÄ-I-16 CÄ-I-17 Îìàð
Page 245 and 246:
CÄ-II-23 Öåëþòèíà Ì.È.,
Page 247:
Êîíôåðåíöèÿ Ìîëåêó
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