Èíñòèòóò êàòàëèçà èì. Ã.Ê. Áîðåñêîâà ÑÎ ÐÀÍ Èíñòèòóò ïðîáëåì ïåðåðàáîòêè óãëåâîäîðîäîâ ÑÎ ÐÀÍ Íàó÷íûé ñîâåò ïî êàòàëèçó ÎÕÍÌ ÐÀÍ Êîíôåðåíöèÿ ÌÎËÅÊÓËßÐÍÛÉ ÄÈÇÀÉÍ ÊÀÒÀËÈÇÀÒÎÐÎÂ È ÊÀÒÀËÈÇ Â ÏÐÎÖÅÑÑÀÕ ÏÅÐÅÐÀÁÎÒÊÈ ÓÃËÅÂÎÄÎÐÎÄÎÂ È ÏÎËÈÌÅÐÈÇÀÖÈÈ ê 70-ëåòèþ ñî äíÿ ðîæäåíèÿ ïðîôåññîðà Þðèÿ Èâàíîâè÷à Åðìàêîâà 15 - 17 èþíÿ 2005 ã. ã. Îìñê ÒÅÇÈÑÛ ÄÎÊËÀÄΠÍîâîñèáèðñê-2005 1
Îðãàíèçàòîðû êîíôåðåíöèè • Èíñòèòóò êàòàëèçà èì. Ã.Ê. Áîðåñêîâà ÑÎ ÐÀÍ, Íîâîñèáèðñê • Èíñòèòóò ïðîáëåì ïåðåðàáîòêè óãëåâîäîðîäîâ ÑÎ ÐÀÍ, Îìñê • Îìñêèé íàó÷íûé öåíòð ÑÎ ÐÀÍ, Îìñê • Íàó÷íûé ñîâåò ïî êàòàëèçó ÎÕÍÌ ÐÀÍ, Ìîñêâà • Ôåäåðàëüíîå àãåíòñòâî ïî íàóêå è èííîâàöèÿì ÐÔ, Ìîñêâà • Ðîññèéñêèé ôîíä ôóíäàìåíòàëüíûõ èññëåäîâàíèé, Ìîñêâà Îðãêîìèòåò âûðàæàåò áëàãîäàðíîñòü Îìñêîé ãîñóäàðñòâåííîé îáëàñòíîé íàó÷íîé áèáëèîòåêå èì. À.Ñ. Ïóøêèíà çà ñîäåéñòâèå â ïðîâåäåíèè êîíôåðåíöèè Îðãàíèçàöèîííûé êîìèòåò Â.À. Ëèõîëîáîâ (ïðåäñåäàòåëü, ÈÏÏÓ ÑÎ ÐÀÍ, ã. Îìñê), Â.À. Çàõàðîâ (çàì. ïðåäñåäàòåëÿ, ÈÊ ÑÎ ÐÀÍ, ã. Íîâîñèáèðñê), À.Ì. Àëàäûøåâ (ÈÕÔ ÐÀÍ, Ìîñêâà), Ñ.Ï. Ãóáèí (ÈÎÍÕ ÐÀÍ, ã. Ìîñêâà), Â.Ê. Äóïëÿêèí (ÈÏÏÓ ÑÎ ÐÀÍ, ã. Îìñê), Á.Í. Êóçíåöîâ (ÈÕÕÒ ÑÎ ÐÀÍ, ã. Êðàñíîÿðñê), À.Ë. Ëàïèäóñ (ÈÎÕ ÐÀÍ, ã. Ìîñêâà), Ã.Â. Ëèñè÷êèí (ÌÃÓ, ã. Ìîñêâà), Î.Ï. Ïàðåíàãî (ÈÍÕÑ ÐÀÍ, ã. Ìîñêâà), Ã.Â. Ïëàêñèí (ÈÏÏÓ ÑÎ ÐÀÍ, ã. Îìñê), À.Í. Ñòàðöåâ (ÈÊ ÑÎ ÐÀÍ, ã. Íîâîñèáèðñê), Â.Á. Øóð (ÈÍÝÎÑ ÐÀÍ, ã. Ìîñêâà), Ð.Õ. Êàðûìîâà (ñåêðåòàðü, ÈÏÏÓ ÑÎ ÐÀÍ, ã. Îìñê), Ë.ß. Ñòàðöåâà (ñåêðåòàðü, ÈÊ ÑÎ ÐÀÍ, ã. Íîâîñèáèðñê) ©Èíñòèòóò êàòàëèçà èì. Ã.Ê. Áîðåñêîâà ÑÎ ÐÀÍ, 2005 2
- Page 1: Èíñòèòóò êàòàëèçà
- Page 6 and 7: SINGLE SITE CATALYSTS - IDEAL MODEL
- Page 8 and 9: ÑÒÀÁÈËÈÇÈÐÎÂÀÍÍÛÅ
- Page 10 and 11: ÈÇÓ×ÅÍÈÅ ÌÅÕÀÍÈÇÌÎ
- Page 12 and 13: Ñðàâíåíèå äèíàìèêè
- Page 14 and 15: ÐÎËÜ ÍÎÑÈÒÅËÅÉ Â ÔÎ
- Page 16 and 17: ÒÐÈÈÇÎÁÓÒÈËÀËÞÌÈÍ
- Page 18: ÏÐÎÃÐÅÑÑ Â ÎÁËÀÑÒÈ
- Page 22 and 23: MOLECULAR DESIGN OF NEW TYPE OF CAT
- Page 24 and 25: PALLADIUM AND COBALT CATALYZED OXID
- Page 26 and 27: ÍÎÂÛÉ ÏÎÄÕÎÄ Ê ÔÎÐÌ
- Page 28 and 29: Èîííûé îáìåí Al 2O 3 2+
- Page 30 and 31: êîòîðûõ èììîáèëèçî
- Page 32 and 33: ïðèâåäøàÿ ê ñîçäàí
- Page 34 and 35: ÐÀÇÐÀÁÎÒÊÀ ÊÀÒÀËÈÇ
- Page 36 and 37: ðàñïðåäåëåíèÿ ÷àñò
- Page 38 and 39: ÷òî äåôåêòû ýòîãî â
- Page 40 and 41: ÈÇÓ×ÅÍÈÅ ÔÎÐÌÈÐÎÂÀ
- Page 42 and 43: Ñîäåðæàíèå äèîêñèä
- Page 44 and 45: Òàáë. 1. Äàííûå õåìî
- Page 46 and 47: ñëàáîñâÿçàííîì ñîñ
- Page 48 and 49: ãèäðîãåíèçàöèè, âå
- Page 50 and 51: ÑÅËÅÊÒÈÂÍÀß ÎÊÈÑËÈ
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ÌÎÄÈÔÈÖÈÐÎÂÀÍÈÅ ÀË
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ãèäðîîêèñüþ àëþìèí
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ïðîìûñëîâûõ ìèíè-Í
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ÏÎËÓ×ÅÍÈÅ ÆÈÄÊÈÕ Ó
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ÈÇÎÌÅÐÈÇÀÖÈß ÓÃËÅÂ
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ÊÀÒÀËÈÒÈ×ÅÑÊÈÅ ÏÐÅ
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îáðàçîâàíèÿ öèêëîï
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ïðåèìóùåñòâåííîå ï
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ÈÍÒÅÐÊÀËÈÐÎÂÀÍÍÛÅ
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ÊÐÅÊÈÍÃ Ñ 10 -Ñ 15 - ÀË
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 ÈÊ- ñïåêòðàõ àäñî
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Ïî âëèÿíèþ íà êàòàë
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Ïðåîáëàäàþùèìè ïðè
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ÃÈÄÐÎÏÅÐÅÐÀÁÎÒÊÀ Í
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Ïîñëå ãèäðîïåðåðàá
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óñëîâèé ïðîöåññà î
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åå ðåàêöèè. Èìåííî
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í-C 4 H 8 + Pd II + Í 2 Î ⎯⎯
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ïðîäóêòîâ. Íàïðèìå
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×ÈÑËÎ È ÐÅÀÊÖÈÎÍÍÀ
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Äëÿ âñåõ ñèñòåì îïð
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ñèíäèîòàêòè÷åñêèé
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ñâÿçåé è ýêâèâàëåí
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ÝËÅÊÒÐÎÕÈÌÈ×ÅÑÊÈÉ
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ÑÒÅÍÄÎÂÛÅ ÄÎÊËÀÄÛ
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ÈÇÓ×ÅÍÈÅ ÌÅÕÀÍÈÇÌÀ
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Ðèñóíîê 2. Äèôôåðåí
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âòîðîé ïî èíòåíñèâ
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êîëåáàíèÿ â ìîñòèê
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ÑÒÐÓÊÒÓÐÍÎ-ÎÐÃÀÍÈÇ
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Òàáëèöà 2. Ðàñïðåäå
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50 Rate/10 -8 mol g -1 s -1 40 30 2
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ÐÀÇÐÀÁÎÒÊÀ È ÈÑÑËÅ
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êèñëîðîäó øïèíåëè C
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èçîìåðèçàöèè í-ãåê
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ÃÅÍÅÇÈÑ ÔÀÇÎÂÎÃÎ Ñ
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óïëîòíåíèÿ çàïîëíÿ
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Ïðèðîäà èñõîäíûõ ñ
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ÏÎËÈÌÅÐÍÛÅ ÐÎÄÈÉÑÎ
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ïðîìîòîðîâ. Â ðàáîò
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ôîðìàëüäåãèä, äè- è
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Äàëüíåéøàÿ äåãèäðî
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ÌÅÒÎÄÛ ÐÅÃÓËÈÐÎÂÀÍ
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ÑÈÍÒÅÇ È ÈÑÑËÅÄÎÂÀ
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ÂËÈßÍÈÅ ÎÁÐÀÁÎÒÎÊ
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Íàðÿäó ñ óâåëè÷åíè
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îáîðîòîâ êàòàëèçàò
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Íàìè ðàçðàáîòàí ïð
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äî 0,5 ÌÏà. Ôîðìû çàâ
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Î ÏÐÎÖÅÑÑÀÕ ÏÐÅÄÎÒ
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ÐÀÇÐÀÁÎÒÊÀ ÊÀÒÀËÈÒ
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ÏÐÅÂÐÀÙÅÍÈß ÑÒÈÐÎË
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ÆÈÄÊÎÔÀÇÍÀß ÈÇÎÌÅÐ
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ÍÅÏÎËÍÎÅ ÎÊÈÑËÅÍÈÅ
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ÍÀÍÎÑÒÐÓÊÒÓÐÍÛÅ ÊÀ
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ÃÈÄÐÎÊÎÍÂÅÐÑÈß Í-Ã
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ðàñòåò ñ ïîâûøåíèå
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Èíäèâèäóàëüíàÿ àäñ
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â ÑÍÃ ñíèæàåò òåìïå
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Ïðîöåññ áèôîðìèíãà
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ÈÑÏÎËÜÇÎÂÀÍÈÅ ÊÀÒÀ
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Ïîâûøåíèå äàâëåíèÿ
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Èç ïðèðîäíîãî öåîë
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ÄÅÃÈÄÐÈÐÎÂÀÍÈÅ ËÅÃ
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ðîäèåâûå è ðóòåíèå
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Òàáëèöà 1. Âëèÿíèå ï
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ÈÑÑËÅÄÎÂÀÍÈÅ ÏÐÎÖÅ
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ÏÅÐÅÐÀÁÎÒÊÀ ÄÈÑÒÈË
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ÃÈÄÐÎÏÅÐÅÐÀÁÎÒÊÀ í
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ÊÐÅÊÈÍà ÒßÆÅËÎÃÎ Í
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óãëåðîäà â äèîêñèä
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ïîäà÷è ñûðüÿ 1,0-1,5 ÷
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ëîêàëèçîâàííûå íà
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CÓËÜÔÎÊÀÒÈÎÍÈÒÛ ÍÀ
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Ïðè íàëè÷èè â ñèñòå
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ãåêñàäåêàíîë-2 (ïðè
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óñëîâèÿ îêèñëåíèÿ
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ãàçîâ òåðìîäåñîðáö
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ïîëèìåðèçàöèè ýòèë
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ÊÀÒÀËÈÇÈÐÓÅÌÎÅ ÏÀË
- Page 212 and 213:
ÈÑÑËÅÄÎÂÀÍÈÅ ÂËÈßÍ
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ÄÈÌÅÐÈÇÀÖÈß ÝÒÈËÅÍ
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ÈÇÓ×ÅÍÈÅ ÏÐÎÖÅÑÑÎÂ
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ÐÀÑÏÐÅÄÅËÅÍÈÅ ÂÍÓÒ
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ÃÎÌÎ - È ÑÎÏÎËÈÌÅÐÈ
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ÏÎËÈÌÅÐÈÇÀÖÈß ÝÒÈË
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Ñ ïðèìåíåíèåì ìåòî
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àìîðôíûìè è êðèñòà
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ÑÏÈÑÎÊ ÀÄÐÅÑΠÓ×À
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ÃÐÈÃÎÐÜÅÂÀ Íåëëè Ã
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ÊÀÐÛÌÎÂÀ Ðàøèäà Õà
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ÌÓÍØÈÅÂÀ Ìèíà Êåðè
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ÓÑÌÀÍÎÂÀ Ìàíçóðà Ì
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ÑÎÄÅÐÆÀÍÈÅ ÊËÞ×ÅÂÛ
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Ñåêöèÿ II Êàòàëèç â
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CÄ-I-3 CÄ-I-4 CÄ-I-5 CÄ-I-6 CÄ
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CÄ-II-10 Çàêèðîâà À.Ã.,
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CÄ-III-4 Ìèêåíàñ T.Á., Å
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