The impact of urban groundwater upon surface water - eTheses ...

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WATER QUALITY INTERACTIONS Redox conditions are consistent with the oxygen levels. The aquifer is generally oxidising with mean Eh 456 mv (median 463mv) in the deep aquifer, falling slightly to 444 mv (median 441 mv) in the shallow. More reducing conditions (mean 298 mv, median 333 mv) coincide with microbial activity and the drop in oxygen levels across the riverbed. Surface water data show a mean Eh of 317 mv (median 326 mv). Considerable variation in both the oxygen content and the redox potential (Figure 7.3a and b) is observed within the riverbed piezometers along the reach and within the same lateral profile. Previous workers (Conant, 2000) have attributed this to differences in groundwater discharge velocities and residence times within the sediments, low oxygen content corresponding to long residence times. Information from five multilevel piezometer profiles (Figures 7.4 a, b and c) shows the often complex vertical zonation in redox conditions that occurs across the riverbed. The western, eastern and central multilevel piezometers at Profile 8 were sampled on more than one occasion and display considerable temporal variability which will be discussed in more detail in Section 7.6. Mixing with surface water appears to occur across the top 40cm to 20 cm of the riverbed as evidenced in some profiles by increasing levels of pH and dissolved oxygen (D.O.) approaching surface water conditions. However, there is great variability in the data and profile 2 shows a decrease in oxygen content towards the surface, with considerable (microbial) oxygen consumption taking place between 30cm and 70 cm depth. Solid-phase iron and manganese oxides are present throughout the aquifer and the solubilities of both are sensitive to redox conditions. Variations in dissolved concentrations coincide with changing conditions across the aquifer system. Manganese shows increasing mean concentrations from 0.08 mgl -1 in the deep, 1.49 mgl -1 in the shallow to 3.15 mgl -1 in the 248
(a) (b) Eh (mv) DO (mgl -1 ) 600 500 400 300 200 100 10 9 8 7 6 5 4 3 2 1 Eh Data from Surface Water, Riverbed and Riverbank Piezometers Aquifer 0 -5000 -3000 -1000 1000 3000 5000 7000 9000 28/02/01 22/05/01 23/05/01 11/05/01 30/07/01 7/20/00 7/26/00 R.bed 2001 R.bank 2001 R.bed 2000 R.bank 2000 Distance downstream from profile 5 (metres) Dissolved Oxygen Data from Riverbed and Riverbank Piezometers Aquifer 0 -5000 -3000 -1000 1000 3000 5000 7000 9000 Distance downstream from profile 5 (metres) 28/02/01 22/05/01 23/05/01 11/05/01 30/07/01 7/20/00 7/26/00 R.bed 2001 R.bank 2001 R.bed 2000 R.bank 2000 Figure 7.3 Longitudinal profile of surface water and groundwater (a) Eh, (b) D.O.
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THE IMPACT OF URBAN GROUNDWATER UPO
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ABSTRACT A field-based research stu
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ACKNOWLEDGEMENTS I would like to th
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3.4.1 Solid Geology ...............
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5.5.2 Riverbed Sediment Core Data a
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6.10 Investigation of groundwater-s
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LIST OF FIGURES 2.1 Conceptual mode
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6.1 Schematic diagram for the analy
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LIST OF TABLES Table 3.1 Descriptio
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APPENDICES Appendices 1, 11, 19, 20
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1.1 Project outline CHAPTER 1. INTR
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4) to develop suitable monitoring m
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INTRODUCTION European Commission Wa
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REVIEW 2.1) and surface water may o
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REVIEW features of groundwater/surf
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REVIEW provide refuge to benthic in
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Abstraction For drinking water supp
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REVIEW occur such as biodegradation
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2.2.1 Water quality studies REVIEW
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REVIEW investigated groundwater/sur
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REVIEW owing to their widespread de
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REVIEW have been used to determine
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REVIEW and under conditions of non-
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(b) (a) River Tame 10 m topographic
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STUDY SETTING But under the General
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(a) Land Use In The River Tame Corr
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(a) (b) Figure 3.3 (a) Photograph o
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Figure 3.4 Schematic geology of the
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Table 3.1 Description of geological
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Wildmoor Sandstone Formation (middl
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STUDY SETTING Man-made excavations
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STUDY SETTING Tame were effluent to
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(a) (b) (c) Figure 3.9 (a) Postulat
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STUDY SETTING this restricts the le
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Figure 3.10 Schematic cross section
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STUDY SETTING water quality through
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STUDY SETTING (Ford, 1990) from nin
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STUDY SETTING dry cleaning industry
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MONITORING NETWORKS AND METHODS CHA
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2 9 4 0 0 0 2 8 8 0 0 0 4020000 410
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MONITORING NETWORKS AND METHODS The
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Water quality data were collected i
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MONITORING NETWORKS AND METHODS pie
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MONITORING NETWORKS AND METHODS pre
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MONITORING NETWORKS AND METHODS the
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MONITORING NETWORKS AND METHODS (Ga
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MONITORING NETWORKS AND METHODS Acc
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MONITORING NETWORKS AND METHODS bor
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MONITORING NETWORKS AND METHODS tha
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MONITORING NETWORKS AND METHODS des
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4.7.3 Grain size analyses by the Ha
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K = hydraulic conductivity (feet da
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MONITORING NETWORKS AND METHODS A s
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MONITORING NETWORKS AND METHODS Run
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MONITORING NETWORKS AND METHODS nex
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MONITORING NETWORKS AND METHODS Dif
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4.9.3 Radial Flow Analytical Soluti
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q = - k dh dx River Riverbed q = th
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Determinands Method of analyses Ana
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MONITORING NETWORKS AND METHODS dif
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5.2 Groundwater in the Tame Valley
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Total Monthly Volume Abstracted (m
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4020000 4100000 Bescot GS 91, 182 1
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5.3.2 Baseflow Analyses GROUNDWATER
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GROUNDWATER FLOW TO THE RIVER TAME
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Temperature C o 20 19.5 19 18.5 18
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5 cm Figure 5.16 (a) Riverbed core
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Frequency 9 8 7 6 5 4 3 2 1 0 10 20
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Summary of Darcy Specific Discharge
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Location Specific Discharge (md -1
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5.8 The Hydrogeological Setting of
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Level ( m.a.o.d ) Level ( m.a.o.d )
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5.9 Concluding Discussion GROUNDWAT
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CHAPTER 6. THE MODELLING OF GROUNDW
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6.2.1 Analytical Model, Steady Stat
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GROUNDWATER FLOW MODELLING The rive
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GROUNDWATER FLOW MODELLING 6.3.1 Re
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39 57 Figure 6.2 Regional Setting f
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GROUNDWATER FLOW MODELLING increase
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GROUNDWATER FLOW MODELLING general,
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Groundwater head contours (1m) 93.0
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GROUNDWATER FLOW MODELLING 6.4.3 Gr
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11 12 13 # # # # # # 96 97 98 Colum
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GROUNDWATER FLOW MODELLING unsatura
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River level data GROUNDWATER FLOW M
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GROUNDWATER FLOW MODELLING of geolo
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GROUNDWATER FLOW MODELLING The FAT3
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GROUNDWATER FLOW MODELLING and grav
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Elevation of cell centre (m.a.o.d)
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GROUNDWATER FLOW MODELLING transmis
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GROUNDWATER FLOW MODELLING on each
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GROUNDWATER FLOW MODELLING The FAT3
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GROUNDWATER FLOW MODELLING of 0.5md
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Analytical solution for the saturat
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GROUNDWATER FLOW MODELLING presence
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GROUNDWATER FLOW MODELLING in secti
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Page 225 and 226: 95 95 95 95 39 MODFLOW Particle Tra
Page 227 and 228: GROUNDWATER FLOW MODELLING Historic
Page 229 and 230: Discharge to the river m 3 d -1 % v
Page 231 and 232: GROUNDWATER FLOW MODELLING 6.10.2 A
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Page 235 and 236: GROUNDWATER FLOW MODELLING across t
Page 237 and 238: GROUNDWATER FLOW MODELLING by the F
Page 239 and 240: Specific discharge to the river fro
Page 241 and 242: GROUNDWATER FLOW MODELLING in time
Page 243 and 244: GROUNDWATER FLOW MODELLING unsatura
Page 245 and 246: GROUNDWATER FLOW MODELLING amplitud
Page 247 and 248: Depth (cm) -80 -100 -120 -140 -160
Page 249 and 250: Depth (cm) -40 -60 -80 -100 -120 -1
Page 251 and 252: GROUNDWATER FLOW MODELLING cycles o
Page 253 and 254: 6.12 Conclusions GROUNDWATER FLOW M
Page 255 and 256: GROUNDWATER FLOW MODELLING consider
Page 257 and 258: WATER QUALITY INTERACTIONS CHAPTER
Page 259 and 260: Water Quality Data From Sutton Park
Page 261 and 262: WATER QUALITY INTERACTIONS 7.1 Indi
Page 263 and 264: WATER QUALITY INTERACTIONS (the fur
Page 265 and 266: WATER QUALITY INTERACTIONS Underlyi
Page 267: WATER QUALITY INTERACTIONS Oxygen l
Page 271 and 272: WATER QUALITY INTERACTIONS riverbed
Page 273 and 274: WATER QUALITY INTERACTIONS samples
Page 275 and 276: WATER QUALITY INTERACTIONS errors i
Page 277 and 278: WATER QUALITY INTERACTIONS industri
Page 279 and 280: (a) (b) (c) Depth below river bed (
Page 281 and 282: WATER QUALITY INTERACTIONS within 5
Page 283 and 284: WATER QUALITY INTERACTIONS The grea
Page 285 and 286: Cation Content (mgl -1 ) 300 250 20
Page 287 and 288: (a) (b) (c) Calcium Concentration m
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Page 291 and 292: 7.5 Toxic Metals WATER QUALITY INTE
Page 293 and 294: WATER QUALITY INTERACTIONS parkland
Page 295 and 296: 95 94 93 92 OD (meters) 91 90 89 88
Page 297 and 298: (a) (b) (c) Chloride (meql -1 ) Nit
Page 299 and 300: (a) (b) Depth below river bed (cm)
Page 301 and 302: (a) (c) (e) Depth below river bed (
Page 303 and 304: WATER QUALITY INTERACTIONS depth. T
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Page 307 and 308: Number of samples greater than dete
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Page 313 and 314: WATER QUALITY INTERACTIONS The surf
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WATER QUALITY INTERACTIONS The grou
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WATER QUALITY INTERACTIONS value of
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Depth below river bed (cm) 0 20 40
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WATER QUALITY INTERACTIONS There is
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WATER QUALITY INTERACTIONS Standard
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WATER QUALITY INTERACTIONS general
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WATER QUALITY INTERACTIONS attenuat
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WATER QUALITY INTERACTIONS these fa
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GROUNDWATER FLUX CHAPTER 8. ESTIMAT
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GROUNDWATER FLUX solution then the
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GROUNDWATER FLUX the riverbed piezo
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HCO3 - Determinant Mean Groundwater
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Residential roof run-off *1 General
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GROUNDWATER FLUX availability of sa
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Discharge MLd -1 350 330 310 290 27
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(a) Dissolved Mass gs -1 Dissolved
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GROUNDWATER FLUX exception of Si, C
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Location Distance from Bescot GS (k
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GROUNDWATER FLUX groundwater is a s
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Maximum concentration in the plume
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GROUNDWATER FLUX 150 m was used, to
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Estimate of mass flux from the plum
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GROUNDWATER FLUX an urban setting.
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GROUNDWATER FLUX improvement of sur
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CONCLUSIONS CHAPTER 9. CONCLUSIONS
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CONCLUSIONS surface-water quality b
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CONCLUSIONS 1945) which caused sign
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CONCLUSIONS Objective 4. To develop
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CONCLUSIONS On a catchment scale, g
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CONCLUSIONS other compounds of inte
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CONCLUSIONS groundwater and surface
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REFERENCES REFERENCES Allen, D.J.,
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REFERENCES Bredehoeft, J.D., & Papa
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REFERENCES De Marsily, G., 1986. Qu
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REFERENCES Ford, M., Tellam, J.H.,
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REFERENCES Hooda, P.S., Moynagh, M.
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REFERENCES Kuwabara, J., Berelson,
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REFERENCES Modica, E., 1993. Hydrau
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REFERENCES Rivett, M.O., Feenstra,
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REFERENCES Stagg, K.A., 2000. An in
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REFERENCES Younger, P.L., 1989. Str
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