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The impact of urban groundwater upon surface water - eTheses ...

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GROUNDWATER FLUX<br />

aquifer is abstracted (13.3 Mld -1 ). <strong>The</strong> mean values for total dissolved mass in the riverbed<br />

piezometer and abstraction well data from the 2001 sampling (Section 7.1, Tables 7.1 and 7.3)<br />

were 1101 mgl -1 and 504 mgl -1 respectively. <strong>The</strong>refore, in terms <strong>of</strong> the total <strong>ground<strong>water</strong></strong><br />

chemical mass flux, 76-91% goes to the river and only 9-24% to the abstraction wells. Of the<br />

total <strong>ground<strong>water</strong></strong> flux, some comprises relatively recent recharge affected by anthropogenic<br />

pollution and the remainder consists <strong>of</strong> older <strong>ground<strong>water</strong></strong> with a composition reflecting<br />

previous recharge history and mineral dissolution. <strong>The</strong> relative contribution to the <strong>surface</strong><br />

<strong>water</strong> flux from the different <strong>water</strong> types is unknown. <strong>The</strong> calculation <strong>of</strong> mass flux through<br />

the aquifer is highly complex but some estimates <strong>of</strong> current mass loading via recharge can be<br />

made for comparison with the estimates <strong>of</strong> <strong>ground<strong>water</strong></strong> flux to <strong>surface</strong> <strong>water</strong>. <strong>The</strong> current<br />

recharge to the aquifer is estimated to comprise 52% rainfall run-<strong>of</strong>f and 48% from other<br />

sources such as mains and sewer leakage (Section 6.4.2.2). A recent survey <strong>of</strong> ro<strong>of</strong> run-<strong>of</strong>f in<br />

a residential area <strong>of</strong> Birmingham (Harris,2002) and from a study on pollutant flux to the<br />

aquifer (Thomas, 2001) provide data on the likely composition <strong>of</strong> recharge <strong>water</strong> (Table 8.2).<br />

<strong>The</strong> residential ro<strong>of</strong> run-<strong>of</strong>f is generally representative <strong>of</strong> atmospheric loading, while the<br />

general <strong>urban</strong> and industrial categories reflect the higher concentrations observed in storm<br />

drains associated with different land uses. Many <strong>of</strong> the concentrations in rainfall from the ro<strong>of</strong><br />

run-<strong>of</strong>f survey are one to two orders <strong>of</strong> magnitude lower than the <strong>ground<strong>water</strong></strong> discharging to<br />

the riverbed, showing the extensive input from natural and anthropogenic sources. However,<br />

the run-<strong>of</strong>f concentrations for the metals Cu, Pb, Zn are similar to, or greater than, the<br />

concentrations in the riverbed. Given the sources in addition to the run-<strong>of</strong>f, this implies<br />

attenuation is occurring within the aquifer.<br />

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