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The impact of urban groundwater upon surface water - eTheses ...

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STUDY SETTING<br />

<strong>water</strong> quality throughout the unconfined aquifer with the exception <strong>of</strong> two boreholes cased to<br />

a depth <strong>of</strong> >135 m. In all surveys the abstraction regime <strong>of</strong> the sampled well was found to be a<br />

major influence on temporal quality variations. Intermittent pumping was found to take high<br />

proportions <strong>of</strong> shallow <strong>water</strong>. Evidence was also found <strong>of</strong> migration <strong>of</strong> contaminants down<br />

the side <strong>of</strong> borehole casing. Rises in <strong>ground<strong>water</strong></strong> have led to a reduction in the unsaturated<br />

zone increasing the vulnerability <strong>of</strong> the <strong>ground<strong>water</strong></strong>. Closure <strong>of</strong> industry and reduction <strong>of</strong><br />

abstraction mean migration <strong>of</strong> contaminant plumes <strong>of</strong>f site is now more likely to occur.<br />

Of the 28 inorganic determinands measured from 70 abstraction wells (Ford et al.,1994) only<br />

nitrate and barium regularly approached the European Community drinking <strong>water</strong> standards.<br />

However, localised areas showing high levels <strong>of</strong> <strong>ground<strong>water</strong></strong> contamination, including heavy<br />

metals, were observed. <strong>The</strong> principal organic contaminants detected in the <strong>ground<strong>water</strong></strong> are<br />

chlorinated solvents (Rivett, 1989) which could be directly related to metal work degreasing<br />

or dry cleaning industries. Little correlation was found between the distributions <strong>of</strong> organic<br />

and inorganic contaminants, probably reflecting differences in physical transport<br />

processes,chemical interactions and histories <strong>of</strong> chemical usage. <strong>The</strong> worst case <strong>of</strong> inorganic<br />

pollution was found in west Birmingham and the worst case <strong>of</strong> organic contamination was<br />

within the Tame Valley. <strong>The</strong> extent <strong>of</strong> microbiological contamination within the Birmingham<br />

Aquifer is unknown but a study <strong>of</strong> shallow <strong>ground<strong>water</strong></strong> in the Triassic Sandstone beneath<br />

Nottingham has revealed the widespread occurrence <strong>of</strong> bacteria and bacteriophage marker<br />

species related to leakage from sewers.<br />

Temporal variations in <strong>ground<strong>water</strong></strong> quality have been investigated by Ford et al., (1994),<br />

Rivett, (1989) and Taylor and Rivett, (1999). Contaminant travel times to the <strong>water</strong> table have<br />

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